Articles | Volume 17, issue 22
https://doi.org/10.5194/acp-17-13491-2017
© Author(s) 2017. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/acp-17-13491-2017
© Author(s) 2017. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Secondary organic aerosol from chlorine-initiated oxidation of isoprene
Dongyu S. Wang
McKetta Department of Chemical Engineering, The University of Texas at
Austin, Austin, Texas, USA
McKetta Department of Chemical Engineering, The University of Texas at
Austin, Austin, Texas, USA
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- Atmospheric Chemistry of Allylic Radicals from Isoprene: A Successive Cyclization-Driven Autoxidation Mechanism F. Ma et al. 10.1021/acs.est.0c07925
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- Photodissociation of particulate nitrate as a source of daytime tropospheric Cl2 X. Peng et al. 10.1038/s41467-022-28383-9
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- Secondary organic aerosols from oxidation of 1-methylnaphthalene: Yield, composition, and volatility W. Xiang et al. 10.1016/j.scitotenv.2024.170379
61 citations as recorded by crossref.
- Size‐dependent Molecular Characteristics and Possible Sources of Organic Aerosols at a Coastal New Particle Formation Hotspot of East China Y. Wan et al. 10.1029/2021JD034610
- Effects of Relative Humidity and Photoaging on the Formation, Composition, and Aging of Ethylbenzene SOA: Insights from Chamber Experiments on Chlorine Radical-Initiated Oxidation of Ethylbenzene L. Jahn et al. 10.1021/acsearthspacechem.3c00279
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- Heterogeneous production of Cl2 from particulate chloride: Effects of composition and relative humidity C. Faxon et al. 10.1002/aic.16204
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- Atmospheric oxidation mechanism and kinetics of isoprene initiated by chlorine radicals: A computational study X. Guo et al. 10.1016/j.scitotenv.2019.136330
- Halogens Enhance Haze Pollution in China Q. Li et al. 10.1021/acs.est.1c01949
- Isoprene Emission in Darkness by a Facultative Heterotrophic Green Alga K. Dani et al. 10.3389/fpls.2020.598786
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- Anthropogenic emissions of atomic chlorine precursors in the Yangtze River Delta region, China X. Yi et al. 10.1016/j.scitotenv.2020.144644
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- Simultaneous formation of sulfate and nitrate via co-uptake of SO2 and NO2 by aqueous NaCl droplets: combined effect of nitrate photolysis and chlorine chemistry R. Zhang & C. Chan 10.5194/acp-23-6113-2023
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- The Role of Hydrates, Competing Chemical Constituents, and Surface Composition on ClNO2 Formation H. Royer et al. 10.1021/acs.est.0c06067
- New insights into the influences of firework combustion on molecular composition and formation of sulfur- and halogen-containing organic compounds C. Yan et al. 10.1016/j.scitotenv.2024.172929
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- Observations of organic and inorganic chlorinated compounds and their contribution to chlorine radical concentrations in an urban environment in northern Europe during the wintertime M. Priestley et al. 10.5194/acp-18-13481-2018
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- Formation of highly oxygenated organic molecules from chlorine-atom-initiated oxidation of alpha-pinene Y. Wang et al. 10.5194/acp-20-5145-2020
- Enhanced Sulfate Formation through Synergistic Effects of Chlorine Chemistry and Photosensitization in Atmospheric Particles R. Zhang & C. Chan 10.1021/acsestair.3c00030
- Impact of Molecular Chlorine Production from Aerosol Iron Photochemistry on Atmospheric Oxidative Capacity in North China Q. Chen et al. 10.1021/acs.est.4c02534
- Photocatalytic ethylbenzene degradation associated with ozone (TiO2/UV/O3) under different percentages of catalytic coating area: Evaluation of process parameters L. Saldanha et al. 10.1016/j.seppur.2021.118344
- Measurement report: Effects of anthropogenic emissions and environmental factors on the formation of biogenic secondary organic aerosol (BSOA) in a coastal city of southeastern China Y. Hong et al. 10.5194/acp-22-7827-2022
- Evaluating the response of the Aerodyne aerosol mass spectrometer to monoterpene- and isoprene-derived organic nitrate standards M. Takeuchi et al. 10.1080/02786826.2024.2389183
- Photodissociation of particulate nitrate as a source of daytime tropospheric Cl2 X. Peng et al. 10.1038/s41467-022-28383-9
- New mechanistic understanding for atmospheric oxidation of isoprene initiated by atomic chlorine Z. Ding et al. 10.1016/j.scitotenv.2021.149768
- Secondary organic aerosols from oxidation of 1-methylnaphthalene: Yield, composition, and volatility W. Xiang et al. 10.1016/j.scitotenv.2024.170379
Latest update: 06 Nov 2024
Short summary
We investigated the formation of atmospheric pollutants from chlorine-initiated oxidation of isoprene. Our study is the first to report formation of airborne particles from these reactions. We analyzed the chemical composition of both gas- and particle-phase products and propose methods to better detect particle-phase pollutants. Overall, our study demonstrates that reactions between isoprene and chlorine can have important implications for atmospheric composition and therefore human health.
We investigated the formation of atmospheric pollutants from chlorine-initiated oxidation of...
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