Articles | Volume 17, issue 20
https://doi.org/10.5194/acp-17-12797-2017
© Author(s) 2017. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/acp-17-12797-2017
© Author(s) 2017. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Research article
| 
27 Oct 2017
Research article |
| 27 Oct 2017
Hygroscopic behavior and chemical composition evolution of internally mixed aerosols composed of oxalic acid and ammonium sulfate
Xiaowei Wang
The Institute of Chemical Physics, School of Chemistry and Chemical Engineering, Beijing Institute of Technology, Beijing 100081, China
School of Chemical Engineering and Pharmaceutics, Henan University of Science and Technology, Luoyang 471023, China
Beijing National Laboratory for Molecular Sciences (BNLMS), State Key
Laboratory for Structural Chemistry of Unstable and Stable Species, CAS
Research/Education Center for Excellence in Molecular Sciences, Institute of
Chemistry, Chinese Academy of Sciences, Beijing 100190, China
Fang Tan
Beijing National Laboratory for Molecular Sciences (BNLMS), State Key
Laboratory for Structural Chemistry of Unstable and Stable Species, CAS
Research/Education Center for Excellence in Molecular Sciences, Institute of
Chemistry, Chinese Academy of Sciences, Beijing 100190, China
University of Chinese Academy of Sciences, Beijing 100049, China
Jiabi Ma
The Institute of Chemical Physics, School of Chemistry and Chemical Engineering, Beijing Institute of Technology, Beijing 100081, China
Yunhong Zhang
CORRESPONDING AUTHOR
The Institute of Chemical Physics, School of Chemistry and Chemical Engineering, Beijing Institute of Technology, Beijing 100081, China
Beijing National Laboratory for Molecular Sciences (BNLMS), State Key
Laboratory for Structural Chemistry of Unstable and Stable Species, CAS
Research/Education Center for Excellence in Molecular Sciences, Institute of
Chemistry, Chinese Academy of Sciences, Beijing 100190, China
University of Chinese Academy of Sciences, Beijing 100049, China
Center for Excellence in Regional Atmospheric Environment, Institute
of Urban Environment, Chinese Academy of Sciences, Xiamen 361021, China
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Latest update: 23 Nov 2024
Short summary
Our results reveal the formation of NH4HC2O4 and NH4HSO4 from the reaction of oxalic acid (OA) with ammonium sulfate within aerosols during the slow dehydration compared to the rapid dehydration process. The hygroscopic growth of mixed particles at high RH upon hydration is substantially lower than that of the corresponding dehydration process due to the significant formation of low hygroscopic NH4HC2O4 and residual OA. These findings have important implications for atmospheric chemistry.
Our results reveal the formation of NH4HC2O4 and NH4HSO4 from the reaction of oxalic acid (OA)...
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