Articles | Volume 17, issue 19
https://doi.org/10.5194/acp-17-11991-2017
https://doi.org/10.5194/acp-17-11991-2017
Research article
 | 
10 Oct 2017
Research article |  | 10 Oct 2017

Modeling of the chemistry in oxidation flow reactors with high initial NO

Zhe Peng and Jose L. Jimenez

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Latest update: 06 Oct 2025
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Short summary
Oxidation flow reactors (OFRs) have been increasingly used to study atmospheric chemistry at high NO. We show that it is very difficult to obtain high-NO chemistry (in terms of RO2 fate) in OFRs by initial NO injection. Past OFR studies with combustion sources generally had too-high precursor and NOx concentrations that caused several types of experimental artifacts. A strong dilution (× 100 or larger) may be needed for such experiments to avoid undesired chemistry.
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