Articles | Volume 17, issue 19
https://doi.org/10.5194/acp-17-11819-2017
© Author(s) 2017. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/acp-17-11819-2017
© Author(s) 2017. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Light-induced protein nitration and degradation with HONO emission
Max Planck Institute for Chemistry, Multiphase Chemistry Department, Mainz, Germany
Yasin Elshorbany
NASA Goddard Space Flight Center, Greenbelt, Maryland, USA
Earth System Science Interdisciplinary Center, University of Maryland, College Park, Maryland, USA
Uwe Kuhn
Max Planck Institute for Chemistry, Multiphase Chemistry Department, Mainz, Germany
Thorsten Bartels-Rausch
Paul Scherrer Institute, Villigen, Switzerland
Kathrin Reinmuth-Selzle
Max Planck Institute for Chemistry, Multiphase Chemistry Department, Mainz, Germany
Christopher J. Kampf
Johannes Gutenberg University of Mainz, Institute for Organic Chemistry, Mainz, Germany
Guo Li
Max Planck Institute for Chemistry, Multiphase Chemistry Department, Mainz, Germany
Xiaoxiang Wang
Max Planck Institute for Chemistry, Multiphase Chemistry Department, Mainz, Germany
Jos Lelieveld
Max Planck Institute for Chemistry, Atmospheric Chemistry Department, Mainz, Germany
Ulrich Pöschl
Max Planck Institute for Chemistry, Multiphase Chemistry Department, Mainz, Germany
Thorsten Hoffmann
Johannes Gutenberg University of Mainz, Institute for Inorganic and Analytical Chemistry, Mainz, Germany
Institute for Environmental and Climate Research, Jinan University, Guangzhou, China
Max Planck Institute for Chemistry, Multiphase Chemistry Department, Mainz, Germany
Markus Ammann
Paul Scherrer Institute, Villigen, Switzerland
Yafang Cheng
Max Planck Institute for Chemistry, Multiphase Chemistry Department, Mainz, Germany
Institute for Environmental and Climate Research, Jinan University, Guangzhou, China
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Latest update: 21 Nov 2025
Short summary
In this study we investigated protein nitration and decomposition by light in the presence of NO2 via flow tube measurements. Nitrated proteins have an enhanced allergenic potential but so far nitration was only studied in dark conditions. Under irradiated conditions we found that proteins predominantly decompose while forming nitrous acid (HONO) an important precursor of the OH radical. Unlike other studies on heterogeneous NO2 conversion we found a stable HONO formation over a long period.
In this study we investigated protein nitration and decomposition by light in the presence of...
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