Articles | Volume 17, issue 18
https://doi.org/10.5194/acp-17-11273-2017
© Author(s) 2017. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/acp-17-11273-2017
© Author(s) 2017. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Higher measured than modeled ozone production at increased NOx levels in the Colorado Front Range
Bianca C. Baier
CORRESPONDING AUTHOR
Department of Meteorology and Atmospheric Science, The Pennsylvania State University, University Park, PA, USA
now at: Cooperative Institute for Research in Environmental Sciences, University of Colorado Boulder, Boulder, CO, USA
now at: Global Monitoring Division, NOAA Earth System Research Laboratory, Boulder, CO, USA
William H. Brune
Department of Meteorology and Atmospheric Science, The Pennsylvania State University, University Park, PA, USA
David O. Miller
Department of Meteorology and Atmospheric Science, The Pennsylvania State University, University Park, PA, USA
Donald Blake
School of Physical Sciences, University of California, Irvine, CA, USA
Russell Long
US EPA National Exposure Research Lab, Research Triangle Park, NC, USA
Armin Wisthaler
Institute of Ion Physics and Applied Physics, University of Innsbruck, Innsbruck, Austria
Department of Chemistry, University of Oslo, Oslo, Norway
Christopher Cantrell
Department of Atmospheric and Oceanic Sciences, University of Colorado Boulder, Boulder, CO, USA
Alan Fried
INSTAAR, University of Colorado Boulder, Boulder, CO, USA
Brian Heikes
Graduate School of Oceanography, University of Rhode Island, Kingston, RI, USA
Steven Brown
Chemical Sciences Division, NOAA Earth System Research Laboratory, Boulder, CO, USA
Department of Chemistry and Biochemistry, University of Colorado Boulder, Boulder, CO, USA
Erin McDuffie
Chemical Sciences Division, NOAA Earth System Research Laboratory, Boulder, CO, USA
Department of Chemistry and Biochemistry, University of Colorado Boulder, Boulder, CO, USA
Cooperative Institute for Research in Environmental Sciences, University of Colorado Boulder, Boulder, CO, USA
Frank Flocke
Atmospheric Chemistry Observations and Modeling Laboratory, National Center for Atmospheric Research, Boulder, CO, USA
Eric Apel
Atmospheric Chemistry Observations and Modeling Laboratory, National Center for Atmospheric Research, Boulder, CO, USA
Lisa Kaser
Atmospheric Chemistry Observations and Modeling Laboratory, National Center for Atmospheric Research, Boulder, CO, USA
Andrew Weinheimer
Atmospheric Chemistry Observations and Modeling Laboratory, National Center for Atmospheric Research, Boulder, CO, USA
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Latest update: 06 Nov 2025
Short summary
Ozone production rates were measured using the Measurement of Ozone Production Sensor (MOPS). Measurements are compared to modeled ozone production rates using two different chemical mechanisms. At high nitric oxide levels, observed rates are higher than those modeled, prompting the need to revisit current model photochemistry. These direct measurements can add to our understanding of the ozone chemistry within air quality models and can be used to guide government regulatory strategies.
Ozone production rates were measured using the Measurement of Ozone Production Sensor (MOPS)....
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