Articles | Volume 17, issue 18
https://doi.org/10.5194/acp-17-11261-2017
© Author(s) 2017. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/acp-17-11261-2017
© Author(s) 2017. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Research article
| 
25 Sep 2017
Research article |
| 25 Sep 2017
Liquid–liquid phase separation in particles containing secondary organic material free of inorganic salts
Mijung Song
Department of Earth and Environmental Sciences, Chonbuk
National University, Jeollabuk-do, Republic of Korea
Department of Chemistry, University of British Columbia,
Vancouver, BC, V6T 1Z1, Canada
Pengfei Liu
John A. Paulson School of Engineering and Applied
Sciences, Harvard University, Cambridge, Massachusetts 02138,
USA
Scot T. Martin
John A. Paulson School of Engineering and Applied
Sciences, Harvard University, Cambridge, Massachusetts 02138,
USA
Department of Earth and Planetary Sciences, Harvard
University, Cambridge, Massachusetts 02138, USA
Department of Chemistry, University of British Columbia,
Vancouver, BC, V6T 1Z1, Canada
Viewed
Total article views: 3,841 (including HTML, PDF, and XML)
Cumulative views and downloads
(calculated since 11 May 2017)
| HTML | XML | Total | Supplement | BibTeX | EndNote | |
|---|---|---|---|---|---|---|
| 2,335 | 1,386 | 120 | 3,841 | 267 | 85 | 165 |
- HTML: 2,335
- PDF: 1,386
- XML: 120
- Total: 3,841
- Supplement: 267
- BibTeX: 85
- EndNote: 165
Total article views: 3,087 (including HTML, PDF, and XML)
Cumulative views and downloads
(calculated since 25 Sep 2017)
| HTML | XML | Total | Supplement | BibTeX | EndNote | |
|---|---|---|---|---|---|---|
| 1,906 | 1,094 | 87 | 3,087 | 150 | 74 | 133 |
- HTML: 1,906
- PDF: 1,094
- XML: 87
- Total: 3,087
- Supplement: 150
- BibTeX: 74
- EndNote: 133
Total article views: 754 (including HTML, PDF, and XML)
Cumulative views and downloads
(calculated since 11 May 2017)
| HTML | XML | Total | Supplement | BibTeX | EndNote | |
|---|---|---|---|---|---|---|
| 429 | 292 | 33 | 754 | 117 | 11 | 32 |
- HTML: 429
- PDF: 292
- XML: 33
- Total: 754
- Supplement: 117
- BibTeX: 11
- EndNote: 32
Viewed (geographical distribution)
Total article views: 3,841 (including HTML, PDF, and XML)
Thereof 3,793 with geography defined
and 48 with unknown origin.
Total article views: 3,087 (including HTML, PDF, and XML)
Thereof 3,053 with geography defined
and 34 with unknown origin.
Total article views: 754 (including HTML, PDF, and XML)
Thereof 740 with geography defined
and 14 with unknown origin.
| Country | # | Views | % |
|---|
| Country | # | Views | % |
|---|
| Country | # | Views | % |
|---|
| Total: | 0 |
| HTML: | 0 |
| PDF: | 0 |
| XML: | 0 |
- 1
1
| Total: | 0 |
| HTML: | 0 |
| PDF: | 0 |
| XML: | 0 |
- 1
1
| Total: | 0 |
| HTML: | 0 |
| PDF: | 0 |
| XML: | 0 |
- 1
1
Cited
46 citations as recorded by crossref.
- Effects of Organic Matrices on Nucleophilic Aqueous Aerosol Chemistry: Yields and Mechanistic Insight for Brown Carbon Formation from Glyoxal and Ammonia G. Drozd et al. 10.1021/acsearthspacechem.2c00068
- Hygroscopic behavior and aerosol chemistry of atmospheric particles containing organic acids and inorganic salts F. Tan et al. 10.1038/s41612-024-00752-9
- Photolytic Mass Loss of Secondary Organic Aerosol Derived from Photooxidation of Biomass Burning Furan Precursors N. Shin et al. 10.1021/acsestair.4c00230
- Hygroscopic growth and CCN activity of secondary organic aerosol produced from dark ozonolysis of γ-terpinene H. Bouzidi et al. 10.1016/j.scitotenv.2022.153010
- Direct observation for relative-humidity-dependent mixing states of submicron particles containing organic surfactants and inorganic salts C. Xiong et al. 10.5194/acp-23-8979-2023
- Challenges and Opportunities in Molecular-Level Indoor Surface Chemistry and Physics Y. Liu et al. 10.1016/j.xcrp.2020.100256
- Influence of Ions on the Size Dependent Morphology of Aerosol Particles E. Ott & M. Freedman 10.1021/acsearthspacechem.1c00210
- Liquid–liquid phase separation and morphologies in organic particles consisting of α-pinene and β-caryophyllene ozonolysis products and mixtures with commercially available organic compounds Y. Song et al. 10.5194/acp-20-11263-2020
- Ratiometric Optical Sensing of Aerosol Phase State with Excited-State Intramolecular Proton Transfer Probes A. Gibbons & P. Ohno 10.1021/acs.analchem.5c00717
- Role of pH in Aerosol Processes and Measurement Challenges M. Freedman et al. 10.1021/acs.jpca.8b10676
- The Role of Organic Aerosol in Atmospheric Ice Nucleation: A Review D. Knopf et al. 10.1021/acsearthspacechem.7b00120
- Resolving the mechanisms of hygroscopic growth and cloud condensation nuclei activity for organic particulate matter P. Liu et al. 10.1038/s41467-018-06622-2
- Effects of Phase State and Phase Separation on Dimethylamine Uptake of Ammonium Sulfate and Ammonium Sulfate–Sucrose Mixed Particles W. DeRieux et al. 10.1021/acsearthspacechem.9b00142
- Liquid–liquid phase separation and viscosity within secondary organic aerosol generated from diesel fuel vapors M. Song et al. 10.5194/acp-19-12515-2019
- Exploring controls on perfluorocarboxylic acid (PFCA) gas–particle partitioning using a model with observational constraints Y. Tao et al. 10.1039/D2EM00261B
- A review of experimental techniques for aerosol hygroscopicity studies M. Tang et al. 10.5194/acp-19-12631-2019
- Effect of Particle Morphology on Cloud Condensation Nuclei Activity M. Altaf et al. 10.1021/acsearthspacechem.7b00146
- Phase Behavior of Hydrocarbon-like Primary Organic Aerosol and Secondary Organic Aerosol Proxies Based on Their Elemental Oxygen-to-Carbon Ratio F. Mahrt et al. 10.1021/acs.est.1c02697
- Molecular-scale description of interfacial mass transfer in phase-separated aqueous secondary organic aerosol M. Lbadaoui-Darvas et al. 10.5194/acp-21-17687-2021
- Does liquid–liquid phase separation impact ice nucleation in mixed polyethylene glycol and ammonium sulfate droplets? Y. Yao et al. 10.1039/D2CP04407B
- Geometric Analysis of Free and Accessible Volume in Atmospheric Nanoparticles P. Mermigkis et al. 10.1021/acsomega.3c03293
- Probing Liquid–Liquid Phase Separation in Secondary Organic Aerosol Mimicking Solutions Using Articulated Straws E. Longnecker et al. 10.1021/acsomega.1c04014
- Effects of liquid–liquid phase separation and relative humidity on the heterogeneous OH oxidation of inorganic–organic aerosols: insights from methylglutaric acid and ammonium sulfate particles H. Lam et al. 10.5194/acp-21-2053-2021
- Modelling the gas–particle partitioning and water uptake of isoprene-derived secondary organic aerosol at high and low relative humidity D. Amaladhasan et al. 10.5194/acp-22-215-2022
- Viscosity and liquid–liquid phase separation in healthy and stressed plant SOA N. Smith et al. 10.1039/D0EA00020E
- Impact of phase state and non-ideal mixing on equilibration timescales of secondary organic aerosol partitioning M. Schervish & M. Shiraiwa 10.5194/acp-23-221-2023
- Multiphase reactivity of polycyclic aromatic hydrocarbons is driven by phase separation and diffusion limitations S. Zhou et al. 10.1073/pnas.1902517116
- Phase Transitions in Organic and Organic/Inorganic Aerosol Particles M. Freedman et al. 10.1146/annurev-physchem-083122-115909
- A Significant Portion of Water-Soluble Organic Matter in Fresh Biomass Burning Particles Does Not Contribute to Hygroscopic Growth: An Application of Polarity Segregation by 1-Octanol–Water Partitioning Method J. Chen et al. 10.1021/acs.est.9b01696
- Reactive Uptake of Isoprene Epoxydiols Increases the Viscosity of the Core of Phase-Separated Aerosol Particles N. Olson et al. 10.1021/acsearthspacechem.9b00138
- Mass accommodation and gas–particle partitioning in secondary organic aerosols: dependence on diffusivity, volatility, particle-phase reactions, and penetration depth M. Shiraiwa & U. Pöschl 10.5194/acp-21-1565-2021
- Water uptake of subpollen aerosol particles: hygroscopic growth, cloud condensation nuclei activation, and liquid–liquid phase separation E. Mikhailov et al. 10.5194/acp-21-6999-2021
- Microscopic observation of a liquid-liquid-(semi)solid phase in polluted PM2.5 S. Gaikwad et al. 10.3389/fenvs.2022.947924
- Surface-Active β-Caryophyllene Oxidation Products at the Air/Aqueous Interface A. Bé et al. 10.1021/acsearthspacechem.9b00185
- Optical trapping and light scattering in atmospheric aerosol science A. Rafferty et al. 10.1039/D2CP05301B
- Liquid-liquid phase separation in internally mixed magnesium sulfate/glutaric acid particles F. Wu et al. 10.1016/j.atmosenv.2018.02.012
- Confined Water Molecules in Binary Mixtures of Water and 2,6-Lutidine Near Lower Solution Critical Temperature A. Korotkevich & H. Bakker 10.1021/acs.jpcb.0c09363
- Respiratory aerosols and droplets in the transmission of infectious diseases M. Pöhlker et al. 10.1103/RevModPhys.95.045001
- Liquid–liquid phase separation in secondary organic aerosol particles produced from α-pinene ozonolysis and α-pinene photooxidation with/without ammonia S. Ham et al. 10.5194/acp-19-9321-2019
- Liquid–Liquid Phase Separation in Supermicrometer and Submicrometer Aerosol Particles M. Freedman 10.1021/acs.accounts.0c00093
- Effects of Sucrose on Phase Transitions of Organic/Inorganic Aerosols E. Ott et al. 10.1021/acsearthspacechem.0c00006
- Liquid–liquid phase separation in organic particles containing one and two organic species: importance of the average O : C M. Song et al. 10.5194/acp-18-12075-2018
- Observations on hygroscopic growth and phase transitions of mixed 1, 2, 6-hexanetriol ∕ (NH4)2SO4 particles: investigation of the liquid–liquid phase separation (LLPS) dynamic process and mechanism and secondary LLPS during the dehumidification S. Ma et al. 10.5194/acp-21-9705-2021
- Chemical Imaging of Atmospheric Particles A. Laskin et al. 10.1021/acs.accounts.9b00396
- Phase separation in organic aerosol M. Freedman 10.1039/C6CS00783J
- Effects of High Acidity on Phase Transitions of an Organic Aerosol D. Losey et al. 10.1021/acs.jpca.8b00399
45 citations as recorded by crossref.
- Effects of Organic Matrices on Nucleophilic Aqueous Aerosol Chemistry: Yields and Mechanistic Insight for Brown Carbon Formation from Glyoxal and Ammonia G. Drozd et al. 10.1021/acsearthspacechem.2c00068
- Hygroscopic behavior and aerosol chemistry of atmospheric particles containing organic acids and inorganic salts F. Tan et al. 10.1038/s41612-024-00752-9
- Photolytic Mass Loss of Secondary Organic Aerosol Derived from Photooxidation of Biomass Burning Furan Precursors N. Shin et al. 10.1021/acsestair.4c00230
- Hygroscopic growth and CCN activity of secondary organic aerosol produced from dark ozonolysis of γ-terpinene H. Bouzidi et al. 10.1016/j.scitotenv.2022.153010
- Direct observation for relative-humidity-dependent mixing states of submicron particles containing organic surfactants and inorganic salts C. Xiong et al. 10.5194/acp-23-8979-2023
- Challenges and Opportunities in Molecular-Level Indoor Surface Chemistry and Physics Y. Liu et al. 10.1016/j.xcrp.2020.100256
- Influence of Ions on the Size Dependent Morphology of Aerosol Particles E. Ott & M. Freedman 10.1021/acsearthspacechem.1c00210
- Liquid–liquid phase separation and morphologies in organic particles consisting of α-pinene and β-caryophyllene ozonolysis products and mixtures with commercially available organic compounds Y. Song et al. 10.5194/acp-20-11263-2020
- Ratiometric Optical Sensing of Aerosol Phase State with Excited-State Intramolecular Proton Transfer Probes A. Gibbons & P. Ohno 10.1021/acs.analchem.5c00717
- Role of pH in Aerosol Processes and Measurement Challenges M. Freedman et al. 10.1021/acs.jpca.8b10676
- The Role of Organic Aerosol in Atmospheric Ice Nucleation: A Review D. Knopf et al. 10.1021/acsearthspacechem.7b00120
- Resolving the mechanisms of hygroscopic growth and cloud condensation nuclei activity for organic particulate matter P. Liu et al. 10.1038/s41467-018-06622-2
- Effects of Phase State and Phase Separation on Dimethylamine Uptake of Ammonium Sulfate and Ammonium Sulfate–Sucrose Mixed Particles W. DeRieux et al. 10.1021/acsearthspacechem.9b00142
- Liquid–liquid phase separation and viscosity within secondary organic aerosol generated from diesel fuel vapors M. Song et al. 10.5194/acp-19-12515-2019
- Exploring controls on perfluorocarboxylic acid (PFCA) gas–particle partitioning using a model with observational constraints Y. Tao et al. 10.1039/D2EM00261B
- A review of experimental techniques for aerosol hygroscopicity studies M. Tang et al. 10.5194/acp-19-12631-2019
- Effect of Particle Morphology on Cloud Condensation Nuclei Activity M. Altaf et al. 10.1021/acsearthspacechem.7b00146
- Phase Behavior of Hydrocarbon-like Primary Organic Aerosol and Secondary Organic Aerosol Proxies Based on Their Elemental Oxygen-to-Carbon Ratio F. Mahrt et al. 10.1021/acs.est.1c02697
- Molecular-scale description of interfacial mass transfer in phase-separated aqueous secondary organic aerosol M. Lbadaoui-Darvas et al. 10.5194/acp-21-17687-2021
- Does liquid–liquid phase separation impact ice nucleation in mixed polyethylene glycol and ammonium sulfate droplets? Y. Yao et al. 10.1039/D2CP04407B
- Geometric Analysis of Free and Accessible Volume in Atmospheric Nanoparticles P. Mermigkis et al. 10.1021/acsomega.3c03293
- Probing Liquid–Liquid Phase Separation in Secondary Organic Aerosol Mimicking Solutions Using Articulated Straws E. Longnecker et al. 10.1021/acsomega.1c04014
- Effects of liquid–liquid phase separation and relative humidity on the heterogeneous OH oxidation of inorganic–organic aerosols: insights from methylglutaric acid and ammonium sulfate particles H. Lam et al. 10.5194/acp-21-2053-2021
- Modelling the gas–particle partitioning and water uptake of isoprene-derived secondary organic aerosol at high and low relative humidity D. Amaladhasan et al. 10.5194/acp-22-215-2022
- Viscosity and liquid–liquid phase separation in healthy and stressed plant SOA N. Smith et al. 10.1039/D0EA00020E
- Impact of phase state and non-ideal mixing on equilibration timescales of secondary organic aerosol partitioning M. Schervish & M. Shiraiwa 10.5194/acp-23-221-2023
- Multiphase reactivity of polycyclic aromatic hydrocarbons is driven by phase separation and diffusion limitations S. Zhou et al. 10.1073/pnas.1902517116
- Phase Transitions in Organic and Organic/Inorganic Aerosol Particles M. Freedman et al. 10.1146/annurev-physchem-083122-115909
- A Significant Portion of Water-Soluble Organic Matter in Fresh Biomass Burning Particles Does Not Contribute to Hygroscopic Growth: An Application of Polarity Segregation by 1-Octanol–Water Partitioning Method J. Chen et al. 10.1021/acs.est.9b01696
- Reactive Uptake of Isoprene Epoxydiols Increases the Viscosity of the Core of Phase-Separated Aerosol Particles N. Olson et al. 10.1021/acsearthspacechem.9b00138
- Mass accommodation and gas–particle partitioning in secondary organic aerosols: dependence on diffusivity, volatility, particle-phase reactions, and penetration depth M. Shiraiwa & U. Pöschl 10.5194/acp-21-1565-2021
- Water uptake of subpollen aerosol particles: hygroscopic growth, cloud condensation nuclei activation, and liquid–liquid phase separation E. Mikhailov et al. 10.5194/acp-21-6999-2021
- Microscopic observation of a liquid-liquid-(semi)solid phase in polluted PM2.5 S. Gaikwad et al. 10.3389/fenvs.2022.947924
- Surface-Active β-Caryophyllene Oxidation Products at the Air/Aqueous Interface A. Bé et al. 10.1021/acsearthspacechem.9b00185
- Optical trapping and light scattering in atmospheric aerosol science A. Rafferty et al. 10.1039/D2CP05301B
- Liquid-liquid phase separation in internally mixed magnesium sulfate/glutaric acid particles F. Wu et al. 10.1016/j.atmosenv.2018.02.012
- Confined Water Molecules in Binary Mixtures of Water and 2,6-Lutidine Near Lower Solution Critical Temperature A. Korotkevich & H. Bakker 10.1021/acs.jpcb.0c09363
- Respiratory aerosols and droplets in the transmission of infectious diseases M. Pöhlker et al. 10.1103/RevModPhys.95.045001
- Liquid–liquid phase separation in secondary organic aerosol particles produced from α-pinene ozonolysis and α-pinene photooxidation with/without ammonia S. Ham et al. 10.5194/acp-19-9321-2019
- Liquid–Liquid Phase Separation in Supermicrometer and Submicrometer Aerosol Particles M. Freedman 10.1021/acs.accounts.0c00093
- Effects of Sucrose on Phase Transitions of Organic/Inorganic Aerosols E. Ott et al. 10.1021/acsearthspacechem.0c00006
- Liquid–liquid phase separation in organic particles containing one and two organic species: importance of the average O : C M. Song et al. 10.5194/acp-18-12075-2018
- Observations on hygroscopic growth and phase transitions of mixed 1, 2, 6-hexanetriol ∕ (NH4)2SO4 particles: investigation of the liquid–liquid phase separation (LLPS) dynamic process and mechanism and secondary LLPS during the dehumidification S. Ma et al. 10.5194/acp-21-9705-2021
- Chemical Imaging of Atmospheric Particles A. Laskin et al. 10.1021/acs.accounts.9b00396
- Phase separation in organic aerosol M. Freedman 10.1039/C6CS00783J
1 citations as recorded by crossref.
Latest update: 28 Oct 2025
Altmetrics
Final-revised paper
Preprint