Articles | Volume 16, issue 7
https://doi.org/10.5194/acp-16-4707-2016
© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/acp-16-4707-2016
© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Research article
| 
15 Apr 2016
Research article |
| 15 Apr 2016
Interferences in photolytic NO2 measurements: explanation for an apparent missing oxidant?
Wolfson Atmospheric Chemistry Laboratories, Department of Chemistry, University of York, Heslington, York YO10 5DD, UK
Mathew J. Evans
Wolfson Atmospheric Chemistry Laboratories, Department of Chemistry, University of York, Heslington, York YO10 5DD, UK
National Centre for Atmospheric Science (NCAS), University of York, Heslington, York YO10 5DD, UK
Piero Di Carlo
Centre of Excellence CEMTEPs, Universita' degli studi di L'Aquila, Via Vetoio, 67010 Coppito, L'Aquila, Italy
Dipartmento di Scienze Fisiche e Chimiche, Universita' degli studi di L'Aquila, Via Vetoio, 67010 Coppito, L'Aquila, Italy
James D. Lee
Wolfson Atmospheric Chemistry Laboratories, Department of Chemistry, University of York, Heslington, York YO10 5DD, UK
National Centre for Atmospheric Science (NCAS), University of York, Heslington, York YO10 5DD, UK
Lucy J. Carpenter
Wolfson Atmospheric Chemistry Laboratories, Department of Chemistry, University of York, Heslington, York YO10 5DD, UK
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Cited
58 citations as recorded by crossref.
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- Measurement report: Assessment of Asian emissions of ethane and propane with a chemistry transport model based on observations from the island of Hateruma A. Adedeji et al. 10.5194/acp-23-9229-2023
- Interference from alkenes in chemiluminescent NO<sub><i>x</i></sub> measurements M. Alam et al. 10.5194/amt-13-5977-2020
- What controls ozone sensitivity in the upper tropical troposphere? C. Nussbaumer et al. 10.5194/acp-23-12651-2023
- Nitrogen oxides in the global upper troposphere: interpreting cloud-sliced NO<sub>2</sub> observations from the OMI satellite instrument E. Marais et al. 10.5194/acp-18-17017-2018
- Secondary organic aerosol formation from smoldering and flaming combustion of biomass: a box model parametrization based on volatility basis set G. Stefenelli et al. 10.5194/acp-19-11461-2019
- Future Adoption of Direct Measurement Techniques for Regulatory Measurements of Nitrogen Dioxide: Drivers and Challenges D. Worton 10.1021/acs.est.0c04709
- Long-term trends in air quality in major cities in the UK and India: a view from space K. Vohra et al. 10.5194/acp-21-6275-2021
- Evidence for renoxification in the tropical marine boundary layer C. Reed et al. 10.5194/acp-17-4081-2017
- Using satellite observations of tropospheric NO<sub>2</sub> columns to infer long-term trends in US NO<sub><i>x</i></sub> emissions: the importance of accounting for the free tropospheric NO<sub>2</sub> background R. Silvern et al. 10.5194/acp-19-8863-2019
- Comprehensive evaluations of diurnal NO<sub>2</sub> measurements during DISCOVER-AQ 2011: effects of resolution-dependent representation of NO<sub><i>x</i></sub> emissions J. Li et al. 10.5194/acp-21-11133-2021
- Investigation of nonadiabatic dynamics in the photolysis of methyl nitrate (CH3ONO2) by on-the-fly surface hopping simulation J. Zhang et al. 10.1039/D1CP03226G
- Nitrogen Oxides (NOx) in the Arctic Troposphere at Ny-Ålesund (Svalbard Islands): Effects of Anthropogenic Pollution Sources A. Ianniello et al. 10.3390/atmos12070901
- Interannual and seasonal variability of NOx observed at the Mt. Cimone GAW/WMO global station (2165 m a.s.l., Italy) P. Cristofanelli et al. 10.1016/j.atmosenv.2021.118245
- Seasonal variations in the NO 2 artifact from chemiluminescence measurements with a molybdenum converter at a suburban site in Korea (downwind of the Asian continental outflow) during 2015–2016 J. Jung et al. 10.1016/j.atmosenv.2017.07.010
- Fundamental oxidation processes in the remote marine atmosphere investigated using the NO–NO2–O3 photostationary state S. Andersen et al. 10.5194/acp-22-15747-2022
- Tropospheric NO2 vertical profiles over South Korea and their relation to oxidant chemistry: implications for geostationary satellite retrievals and the observation of NO2 diurnal variation from space L. Yang et al. 10.5194/acp-23-2465-2023
- Modification of a conventional photolytic converter for improving aircraft measurements of NO<sub>2</sub> via chemiluminescence C. Nussbaumer et al. 10.5194/amt-14-6759-2021
- Long-term NO<sub><i>x</i></sub> measurements in the remote marine tropical troposphere S. Andersen et al. 10.5194/amt-14-3071-2021
- Central role of nitric oxide in ozone production in the upper tropical troposphere over the Atlantic Ocean and western Africa I. Tadic et al. 10.5194/acp-21-8195-2021
- Effects of halogens on European air-quality T. Sherwen et al. 10.1039/C7FD00026J
- A mini broadband cavity enhanced absorption spectrometer for nitrogen dioxide measurement on the unmanned aerial vehicle platform Z. Zheng et al. 10.1016/j.atmosenv.2024.120361
- Detection and quantification of nitric oxide–derived oxidants in biological systems M. Möller et al. 10.1074/jbc.REV119.006136
- Development of a Rapid Measurement Method for Analysis of the NOx Conversion Process Based on Quantum Cascade Laser Absorption Spectroscopy X. Yang et al. 10.3390/s23083885
- Assessing the bias of molybdenum catalytic conversion in the measurement of NO2 in rural air quality networks N. Cowan et al. 10.1016/j.atmosenv.2024.120375
- Photochemical production of ozone and emissions of NO<sub><i>x</i></sub> and CH<sub>4</sub> in the San Joaquin Valley J. Trousdell et al. 10.5194/acp-19-10697-2019
- Influence of Oil and Gas End-Use on Summertime Particulate Matter and Ozone Pollution in the Eastern US K. Vohra et al. 10.1021/acs.est.4c10032
- Why do models overestimate surface ozone in the Southeast United States? K. Travis et al. 10.5194/acp-16-13561-2016
- Laser absorption spectroscopy applied to monitoring of short-lived climate pollutants (SLCPs) G. Wang et al. 10.1016/j.jms.2018.03.015
- Dual quantum cascade laser-based sensor for simultaneous NO and NO2 detection using a wavelength modulation-division multiplexing technique Y. Yu et al. 10.1007/s00340-017-6742-7
- Mid-IR spectrometer for mobile, real-time urban NO<sub>2</sub> measurements P. Hundt et al. 10.5194/amt-11-2669-2018
- On the use of data from commercial NOx analyzers for air pollution studies R. Dickerson et al. 10.1016/j.atmosenv.2019.116873
- Evaluation of Novel Routes for NOx Formation in Remote Regions C. Ye et al. 10.1021/acs.est.6b06441
- New observations of NO<sub>2</sub> in the upper troposphere from TROPOMI E. Marais et al. 10.5194/amt-14-2389-2021
- Observed NO/NO2 Ratios in the Upper Troposphere Imply Errors in NO‐NO2‐O3 Cycling Kinetics or an Unaccounted NOx Reservoir R. Silvern et al. 10.1029/2018GL077728
- The IAGOS NO<sub><i>x</i></sub> instrument – design, operation and first results from deployment aboard passenger aircraft F. Berkes et al. 10.5194/amt-11-3737-2018
- Measurement of NO<sub><i>x</i></sub> and NO<sub><i>y</i></sub> with a thermal dissociation cavity ring-down spectrometer (TD-CRDS): instrument characterisation and first deployment N. Friedrich et al. 10.5194/amt-13-5739-2020
- Advances in High-Precision NO2 Measurement by Quantum Cascade Laser Absorption Spectroscopy N. Sobanski et al. 10.3390/app11031222
- Global impact of nitrate photolysis in sea-salt aerosol on NO<sub><i>x</i></sub>, OH, and O<sub>3</sub> in the marine boundary layer P. Kasibhatla et al. 10.5194/acp-18-11185-2018
- Seasonal and geographical variability of nitryl chloride and its precursors in Northern Europe R. Sommariva et al. 10.1002/asl.844
- Impact of the COVID-19 outbreak on air pollution levels in East Asia M. Ghahremanloo et al. 10.1016/j.scitotenv.2020.142226
- Vertical profiles of global tropospheric nitrogen dioxide (NO2) obtained by cloud slicing the TROPOspheric Monitoring Instrument (TROPOMI) R. Horner et al. 10.5194/acp-24-13047-2024
- Analysis of the distributions of hourly NO<sub>2</sub> concentrations contributing to annual average NO<sub>2</sub> concentrations across the European monitoring network between 2000 and 2014 C. Malley et al. 10.5194/acp-18-3563-2018
- Heterogeneous Nitrate Production Mechanisms in Intense Haze Events in the North China Plain Y. Chan et al. 10.1029/2021JD034688
- Potential interferences in photolytic nitrogen dioxide converters for ambient air monitoring: Evaluation of a prototype N. Jordan et al. 10.1080/10962247.2020.1769770
- Simultaneous Measurement of Multiparameter of Diesel Engine Exhaust Based on Mid-Infrared Laser Absorption Spectroscopy Y. Li et al. 10.1109/TIM.2023.3268450
- Summer variability of the atmospheric NO2 : NO ratio at Dome C on the East Antarctic Plateau A. Barbero et al. 10.5194/acp-22-12025-2022
- Measurements of NO and NO<sub>2</sub> exchange between the atmosphere and <i>Quercus agrifolia</i> E. Delaria et al. 10.5194/acp-18-14161-2018
- Future air quality and premature mortality in Korea Y. Oak et al. 10.1016/j.scitotenv.2022.161134
- Laser-induced fluorescence-based detection of atmospheric nitrogen dioxide and comparison of different techniques during the PARADE 2011 field campaign U. Javed et al. 10.5194/amt-12-1461-2019
- Net ozone production and its relationship to nitrogen oxides and volatile organic compounds in the marine boundary layer around the Arabian Peninsula I. Tadic et al. 10.5194/acp-20-6769-2020
- US COVID‐19 Shutdown Demonstrates Importance of Background NO2 in Inferring NOx Emissions From Satellite NO2 Observations Z. Qu et al. 10.1029/2021GL092783
- Nitrogen oxides in the free troposphere: implications for tropospheric oxidants and the interpretation of satellite NO2 measurements V. Shah et al. 10.5194/acp-23-1227-2023
- Trends of inorganic and organic aerosols and precursor gases in Europe: insights from the EURODELTA multi-model experiment over the 1990–2010 period G. Ciarelli et al. 10.5194/gmd-12-4923-2019
- Development and application of a nitrogen oxides analyzer based on the cavity attenuated phase shift technique J. Zhou et al. 10.1016/j.jes.2023.11.017
- Extensive field evidence for the release of HONO from the photolysis of nitrate aerosols S. Andersen et al. 10.1126/sciadv.add6266
- Spatially and temporally resolved measurements of NO<sub><i>x</i></sub> fluxes by airborne eddy covariance over Greater London A. Vaughan et al. 10.5194/acp-21-15283-2021
58 citations as recorded by crossref.
- Isoprene nitrates drive new particle formation in Amazon’s upper troposphere J. Curtius et al. 10.1038/s41586-024-08192-4
- HONO measurement by differential photolysis C. Reed et al. 10.5194/amt-9-2483-2016
- Measurement report: Assessment of Asian emissions of ethane and propane with a chemistry transport model based on observations from the island of Hateruma A. Adedeji et al. 10.5194/acp-23-9229-2023
- Interference from alkenes in chemiluminescent NO<sub><i>x</i></sub> measurements M. Alam et al. 10.5194/amt-13-5977-2020
- What controls ozone sensitivity in the upper tropical troposphere? C. Nussbaumer et al. 10.5194/acp-23-12651-2023
- Nitrogen oxides in the global upper troposphere: interpreting cloud-sliced NO<sub>2</sub> observations from the OMI satellite instrument E. Marais et al. 10.5194/acp-18-17017-2018
- Secondary organic aerosol formation from smoldering and flaming combustion of biomass: a box model parametrization based on volatility basis set G. Stefenelli et al. 10.5194/acp-19-11461-2019
- Future Adoption of Direct Measurement Techniques for Regulatory Measurements of Nitrogen Dioxide: Drivers and Challenges D. Worton 10.1021/acs.est.0c04709
- Long-term trends in air quality in major cities in the UK and India: a view from space K. Vohra et al. 10.5194/acp-21-6275-2021
- Evidence for renoxification in the tropical marine boundary layer C. Reed et al. 10.5194/acp-17-4081-2017
- Using satellite observations of tropospheric NO<sub>2</sub> columns to infer long-term trends in US NO<sub><i>x</i></sub> emissions: the importance of accounting for the free tropospheric NO<sub>2</sub> background R. Silvern et al. 10.5194/acp-19-8863-2019
- Comprehensive evaluations of diurnal NO<sub>2</sub> measurements during DISCOVER-AQ 2011: effects of resolution-dependent representation of NO<sub><i>x</i></sub> emissions J. Li et al. 10.5194/acp-21-11133-2021
- Investigation of nonadiabatic dynamics in the photolysis of methyl nitrate (CH3ONO2) by on-the-fly surface hopping simulation J. Zhang et al. 10.1039/D1CP03226G
- Nitrogen Oxides (NOx) in the Arctic Troposphere at Ny-Ålesund (Svalbard Islands): Effects of Anthropogenic Pollution Sources A. Ianniello et al. 10.3390/atmos12070901
- Interannual and seasonal variability of NOx observed at the Mt. Cimone GAW/WMO global station (2165 m a.s.l., Italy) P. Cristofanelli et al. 10.1016/j.atmosenv.2021.118245
- Seasonal variations in the NO 2 artifact from chemiluminescence measurements with a molybdenum converter at a suburban site in Korea (downwind of the Asian continental outflow) during 2015–2016 J. Jung et al. 10.1016/j.atmosenv.2017.07.010
- Fundamental oxidation processes in the remote marine atmosphere investigated using the NO–NO2–O3 photostationary state S. Andersen et al. 10.5194/acp-22-15747-2022
- Tropospheric NO2 vertical profiles over South Korea and their relation to oxidant chemistry: implications for geostationary satellite retrievals and the observation of NO2 diurnal variation from space L. Yang et al. 10.5194/acp-23-2465-2023
- Modification of a conventional photolytic converter for improving aircraft measurements of NO<sub>2</sub> via chemiluminescence C. Nussbaumer et al. 10.5194/amt-14-6759-2021
- Long-term NO<sub><i>x</i></sub> measurements in the remote marine tropical troposphere S. Andersen et al. 10.5194/amt-14-3071-2021
- Central role of nitric oxide in ozone production in the upper tropical troposphere over the Atlantic Ocean and western Africa I. Tadic et al. 10.5194/acp-21-8195-2021
- Effects of halogens on European air-quality T. Sherwen et al. 10.1039/C7FD00026J
- A mini broadband cavity enhanced absorption spectrometer for nitrogen dioxide measurement on the unmanned aerial vehicle platform Z. Zheng et al. 10.1016/j.atmosenv.2024.120361
- Detection and quantification of nitric oxide–derived oxidants in biological systems M. Möller et al. 10.1074/jbc.REV119.006136
- Development of a Rapid Measurement Method for Analysis of the NOx Conversion Process Based on Quantum Cascade Laser Absorption Spectroscopy X. Yang et al. 10.3390/s23083885
- Assessing the bias of molybdenum catalytic conversion in the measurement of NO2 in rural air quality networks N. Cowan et al. 10.1016/j.atmosenv.2024.120375
- Photochemical production of ozone and emissions of NO<sub><i>x</i></sub> and CH<sub>4</sub> in the San Joaquin Valley J. Trousdell et al. 10.5194/acp-19-10697-2019
- Influence of Oil and Gas End-Use on Summertime Particulate Matter and Ozone Pollution in the Eastern US K. Vohra et al. 10.1021/acs.est.4c10032
- Why do models overestimate surface ozone in the Southeast United States? K. Travis et al. 10.5194/acp-16-13561-2016
- Laser absorption spectroscopy applied to monitoring of short-lived climate pollutants (SLCPs) G. Wang et al. 10.1016/j.jms.2018.03.015
- Dual quantum cascade laser-based sensor for simultaneous NO and NO2 detection using a wavelength modulation-division multiplexing technique Y. Yu et al. 10.1007/s00340-017-6742-7
- Mid-IR spectrometer for mobile, real-time urban NO<sub>2</sub> measurements P. Hundt et al. 10.5194/amt-11-2669-2018
- On the use of data from commercial NOx analyzers for air pollution studies R. Dickerson et al. 10.1016/j.atmosenv.2019.116873
- Evaluation of Novel Routes for NOx Formation in Remote Regions C. Ye et al. 10.1021/acs.est.6b06441
- New observations of NO<sub>2</sub> in the upper troposphere from TROPOMI E. Marais et al. 10.5194/amt-14-2389-2021
- Observed NO/NO2 Ratios in the Upper Troposphere Imply Errors in NO‐NO2‐O3 Cycling Kinetics or an Unaccounted NOx Reservoir R. Silvern et al. 10.1029/2018GL077728
- The IAGOS NO<sub><i>x</i></sub> instrument – design, operation and first results from deployment aboard passenger aircraft F. Berkes et al. 10.5194/amt-11-3737-2018
- Measurement of NO<sub><i>x</i></sub> and NO<sub><i>y</i></sub> with a thermal dissociation cavity ring-down spectrometer (TD-CRDS): instrument characterisation and first deployment N. Friedrich et al. 10.5194/amt-13-5739-2020
- Advances in High-Precision NO2 Measurement by Quantum Cascade Laser Absorption Spectroscopy N. Sobanski et al. 10.3390/app11031222
- Global impact of nitrate photolysis in sea-salt aerosol on NO<sub><i>x</i></sub>, OH, and O<sub>3</sub> in the marine boundary layer P. Kasibhatla et al. 10.5194/acp-18-11185-2018
- Seasonal and geographical variability of nitryl chloride and its precursors in Northern Europe R. Sommariva et al. 10.1002/asl.844
- Impact of the COVID-19 outbreak on air pollution levels in East Asia M. Ghahremanloo et al. 10.1016/j.scitotenv.2020.142226
- Vertical profiles of global tropospheric nitrogen dioxide (NO2) obtained by cloud slicing the TROPOspheric Monitoring Instrument (TROPOMI) R. Horner et al. 10.5194/acp-24-13047-2024
- Analysis of the distributions of hourly NO<sub>2</sub> concentrations contributing to annual average NO<sub>2</sub> concentrations across the European monitoring network between 2000 and 2014 C. Malley et al. 10.5194/acp-18-3563-2018
- Heterogeneous Nitrate Production Mechanisms in Intense Haze Events in the North China Plain Y. Chan et al. 10.1029/2021JD034688
- Potential interferences in photolytic nitrogen dioxide converters for ambient air monitoring: Evaluation of a prototype N. Jordan et al. 10.1080/10962247.2020.1769770
- Simultaneous Measurement of Multiparameter of Diesel Engine Exhaust Based on Mid-Infrared Laser Absorption Spectroscopy Y. Li et al. 10.1109/TIM.2023.3268450
- Summer variability of the atmospheric NO2 : NO ratio at Dome C on the East Antarctic Plateau A. Barbero et al. 10.5194/acp-22-12025-2022
- Measurements of NO and NO<sub>2</sub> exchange between the atmosphere and <i>Quercus agrifolia</i> E. Delaria et al. 10.5194/acp-18-14161-2018
- Future air quality and premature mortality in Korea Y. Oak et al. 10.1016/j.scitotenv.2022.161134
- Laser-induced fluorescence-based detection of atmospheric nitrogen dioxide and comparison of different techniques during the PARADE 2011 field campaign U. Javed et al. 10.5194/amt-12-1461-2019
- Net ozone production and its relationship to nitrogen oxides and volatile organic compounds in the marine boundary layer around the Arabian Peninsula I. Tadic et al. 10.5194/acp-20-6769-2020
- US COVID‐19 Shutdown Demonstrates Importance of Background NO2 in Inferring NOx Emissions From Satellite NO2 Observations Z. Qu et al. 10.1029/2021GL092783
- Nitrogen oxides in the free troposphere: implications for tropospheric oxidants and the interpretation of satellite NO2 measurements V. Shah et al. 10.5194/acp-23-1227-2023
- Trends of inorganic and organic aerosols and precursor gases in Europe: insights from the EURODELTA multi-model experiment over the 1990–2010 period G. Ciarelli et al. 10.5194/gmd-12-4923-2019
- Development and application of a nitrogen oxides analyzer based on the cavity attenuated phase shift technique J. Zhou et al. 10.1016/j.jes.2023.11.017
- Extensive field evidence for the release of HONO from the photolysis of nitrate aerosols S. Andersen et al. 10.1126/sciadv.add6266
- Spatially and temporally resolved measurements of NO<sub><i>x</i></sub> fluxes by airborne eddy covariance over Greater London A. Vaughan et al. 10.5194/acp-21-15283-2021
Saved (preprint)
Latest update: 13 Dec 2024
Short summary
The self-cleaning capacity of the atmosphere in places like Antarctica can be measured by quantifying very low amounts of combustion products that exist in a well-known ratio. When this ratio deviates from 1 it points to the existence of unknown compounds. Several unknown compounds have been theorized to exist but never measured. We have found the method for measuring the ratio of combustion products suffers a bias in remote places, which when taken into account disproves any unknown compounds.
The self-cleaning capacity of the atmosphere in places like Antarctica can be measured by...
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