Kinetic isotope effects of 12CH3D  + OH and 13CH3D  + OH from 278 to 313 K

Joelsson, L. M. T.; Schmidt, J. A.; Nilsson, E. J. K.; Blunier, T.; Griffith, D. W. T.; Ono, S.; Johnson, M. S.

doi:10.5194/acp-16-4439-2016

Articles | Volume 16, issue 7

https://doi.org/10.5194/acp-16-4439-2016

© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.

https://doi.org/10.5194/acp-16-4439-2016

© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.

Articles | Volume 16, issue 7

Research article

| Highlight paper

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11 Apr 2016

Research article | Highlight paper |

| 11 Apr 2016

Kinetic isotope effects of ¹²CH₃D  + OH and ¹³CH₃D  + OH from 278 to 313 K

L. M. T. Joelsson, J. A. Schmidt, E. J. K. Nilsson, T. Blunier, D. W. T. Griffith, S. Ono, and M. S. Johnson

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Total article views: 6,335 (including HTML, PDF, and XML)

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HTML: 4,774
PDF: 1,361
XML: 200
Total: 6,335
Supplement: 415
BibTeX: 201
EndNote: 208

Views and downloads (calculated since 15 Oct 2015)

Month	HTML	PDF	XML	Total
Oct 2015	65	71	17	153
Nov 2015	27	23	11	61
Dec 2015	24	27	8	59
Jan 2016	96	12	2	110
Feb 2016	106	6	2	114
Mar 2016	10	5	0	15
Apr 2016	216	91	2	309
May 2016	71	24	1	96
Jun 2016	44	13	1	58
Jul 2016	33	12	2	47
Aug 2016	27	8	0	35
Sep 2016	20	8	2	30
Oct 2016	16	4	2	22
Nov 2016	13	6	0	19
Dec 2016	11	4	0	15
Jan 2017	22	6	1	29
Feb 2017	19	6	2	27
Mar 2017	41	9	4	54
Apr 2017	68	16	5	89
May 2017	63	14	4	81
Jun 2017	46	7	3	56
Jul 2017	31	4	0	35
Aug 2017	16	6	0	22
Sep 2017	26	12	0	38
Oct 2017	12	8	0	20
Nov 2017	11	6	0	17
Dec 2017	9	8	0	17
Jan 2018	19	13	0	32
Feb 2018	31	5	0	36
Mar 2018	15	12	1	28
Apr 2018	7	12	1	20
May 2018	17	11	1	29
Jun 2018	16	10	0	26
Jul 2018	13	5	0	18
Aug 2018	20	6	0	26
Sep 2018	12	8	1	21
Oct 2018	24	9	4	37
Nov 2018	11	7	1	19
Dec 2018	8	4	1	13
Jan 2019	9	4	1	14
Feb 2019	5	3	1	9
Mar 2019	20	9	0	29
Apr 2019	38	5	0	43
May 2019	34	9	1	44
Jun 2019	28	7	3	38
Jul 2019	28	7	1	36
Aug 2019	32	9	0	41
Sep 2019	31	3	0	34
Oct 2019	26	6	1	33
Nov 2019	34	10	1	45
Dec 2019	37	11	0	48
Jan 2020	22	5	1	28
Feb 2020	27	6	2	35
Mar 2020	34	3	0	37
Apr 2020	51	3	0	54
May 2020	66	4	2	72
Jun 2020	46	4	0	50
Jul 2020	80	10	9	99
Aug 2020	51	7	4	62
Sep 2020	53	7	2	62
Oct 2020	26	7	1	34
Nov 2020	25	5	0	30
Dec 2020	46	6	0	52
Jan 2021	57	10	0	67
Feb 2021	44	8	0	52
Mar 2021	46	12	0	58
Apr 2021	54	5	0	59
May 2021	63	9	2	74
Jun 2021	52	7	0	59
Jul 2021	65	11	0	76
Aug 2021	47	13	1	61
Sep 2021	44	19	0	63
Oct 2021	33	32	0	65
Nov 2021	42	17	4	63
Dec 2021	45	11	0	56
Jan 2022	46	6	3	55
Feb 2022	37	2	2	41
Mar 2022	42	4	1	47
Apr 2022	35	4	1	40
May 2022	33	6	0	39
Jun 2022	33	3	1	37
Jul 2022	39	7	0	46
Aug 2022	46	5	0	51
Sep 2022	35	1	0	36
Oct 2022	35	5	0	40
Nov 2022	33	3	0	36
Dec 2022	40	4	0	44
Jan 2023	38	11	0	49
Feb 2023	36	7	0	43
Mar 2023	45	6	0	51
Apr 2023	37	8	0	45
May 2023	62	9	1	72
Jun 2023	73	5	1	79
Jul 2023	70	6	1	77
Aug 2023	67	10	3	80
Sep 2023	75	12	2	89
Oct 2023	75	8	2	85
Nov 2023	36	1	0	37
Dec 2023	50	9	2	61
Jan 2024	39	10	2	51
Feb 2024	39	7	0	46
Mar 2024	43	14	0	57
Apr 2024	43	10	4	57
May 2024	16	11	2	29
Jun 2024	9	4	2	15
Jul 2024	14	12	4	30
Aug 2024	19	5	9	33
Sep 2024	14	7	5	26
Oct 2024	11	10	0	21
Nov 2024	7	5	2	14
Dec 2024	18	7	0	25
Jan 2025	25	10	6	41
Feb 2025	37	12	4	53
Mar 2025	17	13	2	32
Apr 2025	15	38	0	53
May 2025	46	13	1	60
Jun 2025	91	6	2	99
Jul 2025	79	16	2	97
Aug 2025	48	13	0	61
Sep 2025	79	19	2	100
Oct 2025	29	24	2	55
Nov 2025	40	37	4	81
Dec 2025	64	49	4	117
Jan 2026	37	45	5	87

Cumulative views and downloads (calculated since 15 Oct 2015)

Month	HTML	PDF	XML	Total
Oct 2015	65	71	17	153
Nov 2015	27	23	11	61
Dec 2015	24	27	8	59
Jan 2016	96	12	2	110
Feb 2016	106	6	2	114
Mar 2016	10	5	0	15
Apr 2016	216	91	2	309
May 2016	71	24	1	96
Jun 2016	44	13	1	58
Jul 2016	33	12	2	47
Aug 2016	27	8	0	35
Sep 2016	20	8	2	30
Oct 2016	16	4	2	22
Nov 2016	13	6	0	19
Dec 2016	11	4	0	15
Jan 2017	22	6	1	29
Feb 2017	19	6	2	27
Mar 2017	41	9	4	54
Apr 2017	68	16	5	89
May 2017	63	14	4	81
Jun 2017	46	7	3	56
Jul 2017	31	4	0	35
Aug 2017	16	6	0	22
Sep 2017	26	12	0	38
Oct 2017	12	8	0	20
Nov 2017	11	6	0	17
Dec 2017	9	8	0	17
Jan 2018	19	13	0	32
Feb 2018	31	5	0	36
Mar 2018	15	12	1	28
Apr 2018	7	12	1	20
May 2018	17	11	1	29
Jun 2018	16	10	0	26
Jul 2018	13	5	0	18
Aug 2018	20	6	0	26
Sep 2018	12	8	1	21
Oct 2018	24	9	4	37
Nov 2018	11	7	1	19
Dec 2018	8	4	1	13
Jan 2019	9	4	1	14
Feb 2019	5	3	1	9
Mar 2019	20	9	0	29
Apr 2019	38	5	0	43
May 2019	34	9	1	44
Jun 2019	28	7	3	38
Jul 2019	28	7	1	36
Aug 2019	32	9	0	41
Sep 2019	31	3	0	34
Oct 2019	26	6	1	33
Nov 2019	34	10	1	45
Dec 2019	37	11	0	48
Jan 2020	22	5	1	28
Feb 2020	27	6	2	35
Mar 2020	34	3	0	37
Apr 2020	51	3	0	54
May 2020	66	4	2	72
Jun 2020	46	4	0	50
Jul 2020	80	10	9	99
Aug 2020	51	7	4	62
Sep 2020	53	7	2	62
Oct 2020	26	7	1	34
Nov 2020	25	5	0	30
Dec 2020	46	6	0	52
Jan 2021	57	10	0	67
Feb 2021	44	8	0	52
Mar 2021	46	12	0	58
Apr 2021	54	5	0	59
May 2021	63	9	2	74
Jun 2021	52	7	0	59
Jul 2021	65	11	0	76
Aug 2021	47	13	1	61
Sep 2021	44	19	0	63
Oct 2021	33	32	0	65
Nov 2021	42	17	4	63
Dec 2021	45	11	0	56
Jan 2022	46	6	3	55
Feb 2022	37	2	2	41
Mar 2022	42	4	1	47
Apr 2022	35	4	1	40
May 2022	33	6	0	39
Jun 2022	33	3	1	37
Jul 2022	39	7	0	46
Aug 2022	46	5	0	51
Sep 2022	35	1	0	36
Oct 2022	35	5	0	40
Nov 2022	33	3	0	36
Dec 2022	40	4	0	44
Jan 2023	38	11	0	49
Feb 2023	36	7	0	43
Mar 2023	45	6	0	51
Apr 2023	37	8	0	45
May 2023	62	9	1	72
Jun 2023	73	5	1	79
Jul 2023	70	6	1	77
Aug 2023	67	10	3	80
Sep 2023	75	12	2	89
Oct 2023	75	8	2	85
Nov 2023	36	1	0	37
Dec 2023	50	9	2	61
Jan 2024	39	10	2	51
Feb 2024	39	7	0	46
Mar 2024	43	14	0	57
Apr 2024	43	10	4	57
May 2024	16	11	2	29
Jun 2024	9	4	2	15
Jul 2024	14	12	4	30
Aug 2024	19	5	9	33
Sep 2024	14	7	5	26
Oct 2024	11	10	0	21
Nov 2024	7	5	2	14
Dec 2024	18	7	0	25
Jan 2025	25	10	6	41
Feb 2025	37	12	4	53
Mar 2025	17	13	2	32
Apr 2025	15	38	0	53
May 2025	46	13	1	60
Jun 2025	91	6	2	99
Jul 2025	79	16	2	97
Aug 2025	48	13	0	61
Sep 2025	79	19	2	100
Oct 2025	29	24	2	55
Nov 2025	40	37	4	81
Dec 2025	64	49	4	117
Jan 2026	37	45	5	87

Latest update: 28 Jan 2026

Short summary

We present experimental kinetic isotope effects (KIE) for the OH oxidation of CH₃D and ¹³CH₃D and their temperature dependence. Our determination of the ¹³CH₃D + OH KIE is novel and we find no "clumped" isotope effect within the experimental uncertainty.

Kinetic isotope effects of 12CH3D + OH and 13CH3D + OH from 278 to 313 K

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Kinetic isotope effects of ¹²CH₃D  + OH and ¹³CH₃D  + OH from 278 to 313 K