Articles | Volume 16, issue 7
https://doi.org/10.5194/acp-16-4439-2016
https://doi.org/10.5194/acp-16-4439-2016
Research article
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11 Apr 2016
Research article | Highlight paper |  | 11 Apr 2016

Kinetic isotope effects of 12CH3D  + OH and 13CH3D  + OH from 278 to 313 K

L. M. T. Joelsson, J. A. Schmidt, E. J. K. Nilsson, T. Blunier, D. W. T. Griffith, S. Ono, and M. S. Johnson

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A compilation of kinetics data on gas-phase reactions National Institute of Standards and Technology Chemical Kinetics Database http://kinetics.nist.gov

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Short summary
We present experimental kinetic isotope effects (KIE) for the OH oxidation of CH3D and 13CH3D and their temperature dependence. Our determination of the 13CH3D + OH KIE is novel and we find no "clumped" isotope effect within the experimental uncertainty.
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