Kinetic isotope effects of 12CH3D  + OH and 13CH3D  + OH from 278 to 313 K

Joelsson, L. M. T.; Schmidt, J. A.; Nilsson, E. J. K.; Blunier, T.; Griffith, D. W. T.; Ono, S.; Johnson, M. S.

doi:https://doi.org/10.5194/acp-16-4439-2016

Articles | Volume 16, issue 7

https://doi.org/10.5194/acp-16-4439-2016

© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.

https://doi.org/10.5194/acp-16-4439-2016

© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.

Articles | Volume 16, issue 7

Research article

| Highlight paper

|

11 Apr 2016

Research article | Highlight paper |

| 11 Apr 2016

Kinetic isotope effects of ¹²CH₃D  + OH and ¹³CH₃D  + OH from 278 to 313 K

L. M. T. Joelsson, J. A. Schmidt, E. J. K. Nilsson, T. Blunier, D. W. T. Griffith, S. Ono, and M. S. Johnson

Supplement

https://doi.org/10.5194/acp-16-4439-2016-supplement

Data sets

A compilation of kinetics data on gas-phase reactions National Institute of Standards and Technology Chemical Kinetics Database http://kinetics.nist.gov

Short summary

We present experimental kinetic isotope effects (KIE) for the OH oxidation of CH₃D and ¹³CH₃D and their temperature dependence. Our determination of the ¹³CH₃D + OH KIE is novel and we find no "clumped" isotope effect within the experimental uncertainty.

Kinetic isotope effects of 12CH3D + OH and 13CH3D + OH from 278 to 313 K

Supplement

Data sets

Kinetic isotope effects of ¹²CH₃D  + OH and ¹³CH₃D  + OH from 278 to 313 K