Articles | Volume 16, issue 3
Atmos. Chem. Phys., 16, 1693–1712, 2016
https://doi.org/10.5194/acp-16-1693-2016
© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Special issue: BACCHUS – Impact of Biogenic versus Anthropogenic emissions...
Special issue: The CERN CLOUD experiment (ACP/AMT inter-journal SI)
Atmos. Chem. Phys., 16, 1693–1712, 2016
https://doi.org/10.5194/acp-16-1693-2016
© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Research article 12 Feb 2016
Research article | 12 Feb 2016
Aqueous phase oxidation of sulphur dioxide by ozone in cloud droplets
C. R. Hoyle et al.
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23 citations as recorded by crossref.
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- Sulfur dioxide from the atmospheric chemistry experiment (ACE) satellite W. Cameron et al. 10.1016/j.jqsrt.2020.107341
- Cloud Processing of Secondary Organic Aerosol from Isoprene and Methacrolein Photooxidation C. Giorio et al. 10.1021/acs.jpca.7b05933
- Temperature uniformity in the CERN CLOUD chamber A. Dias et al. 10.5194/amt-10-5075-2017
- Marine versus Continental Sources of Iodine and Selenium in Rainfall at Two European High-Altitude Locations E. Suess et al. 10.1021/acs.est.8b05533
- The unintended consequence of SO<sub>2</sub> and NO<sub>2</sub> regulations over China: increase of ammonia levels and impact on PM<sub>2.5</sub> concentrations M. Lachatre et al. 10.5194/acp-19-6701-2019
- Unraveling a New Chemical Mechanism of Missing Sulfate Formation in Aerosol Haze: Gaseous NO2 with Aqueous HSO3–/SO32– J. Yang et al. 10.1021/jacs.9b08503
- SO 2 Observations and Sources in the Western Pacific Tropical Tropopause Region A. Rollins et al. 10.1029/2018JD029635
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- Theoretical study of the oxidation reactions of sulfurous acid/sulfite with ozone to produce sulfuric acid/sulfate with atmospheric implications F. Sheng et al. 10.1039/C8RA00411K
- The adsorption and oxidation of SO2on MgO surface: experimental and DFT calculation studies H. Wang et al. 10.1039/C9EN01474H
- Phase transition observations and discrimination of small cloud particles by light polarization in expansion chamber experiments L. Nichman et al. 10.5194/acp-16-3651-2016
- Effect of NOx and SO2 on the photooxidation of methylglyoxal: Implications in secondary aerosol formation S. Wang et al. 10.1016/j.jes.2020.02.011
- Trends in heterogeneous aqueous reaction in continuous haze episodes in suburban Shanghai: An in-depth case study L. Kong et al. 10.1016/j.scitotenv.2018.04.086
- Discrimination of water, ice and aerosols by light polarisation in the CLOUD experiment L. Nichman et al. 10.5194/acpd-15-31433-2015
22 citations as recorded by crossref.
- Observation of viscosity transition in <i>α</i>-pinene secondary organic aerosol E. Järvinen et al. 10.5194/acp-16-4423-2016
- Heterogeneous ice nucleation of viscous secondary organic aerosol produced from ozonolysis of <i>α</i>-pinene K. Ignatius et al. 10.5194/acp-16-6495-2016
- A potential source of atmospheric sulfate from O<sub>2</sub><sup>−</sup>-induced SO<sub>2</sub> oxidation by ozone N. Tsona & L. Du 10.5194/acp-19-649-2019
- Influence of temperature on the molecular composition of ions and charged clusters during pure biogenic nucleation C. Frege et al. 10.5194/acp-18-65-2018
- Modeling atmospheric mineral aerosol chemistry to predict heterogeneous photooxidation of SO<sub>2</sub> Z. Yu et al. 10.5194/acp-17-10001-2017
- Decadal Trends in Wet Sulfur Deposition in China Estimated From OMI SO 2 Columns X. Zhang et al. 10.1029/2018JD028770
- Molecular and physical characteristics of aerosol at a remote free troposphere site: implications for atmospheric aging S. Schum et al. 10.5194/acp-18-14017-2018
- Formation of aqueous-phase sulfate during the haze period in China: Kinetics and atmospheric implications H. Zhang et al. 10.1016/j.atmosenv.2018.01.017
- Sulfur dioxide from the atmospheric chemistry experiment (ACE) satellite W. Cameron et al. 10.1016/j.jqsrt.2020.107341
- Cloud Processing of Secondary Organic Aerosol from Isoprene and Methacrolein Photooxidation C. Giorio et al. 10.1021/acs.jpca.7b05933
- Temperature uniformity in the CERN CLOUD chamber A. Dias et al. 10.5194/amt-10-5075-2017
- Marine versus Continental Sources of Iodine and Selenium in Rainfall at Two European High-Altitude Locations E. Suess et al. 10.1021/acs.est.8b05533
- The unintended consequence of SO<sub>2</sub> and NO<sub>2</sub> regulations over China: increase of ammonia levels and impact on PM<sub>2.5</sub> concentrations M. Lachatre et al. 10.5194/acp-19-6701-2019
- Unraveling a New Chemical Mechanism of Missing Sulfate Formation in Aerosol Haze: Gaseous NO2 with Aqueous HSO3–/SO32– J. Yang et al. 10.1021/jacs.9b08503
- SO 2 Observations and Sources in the Western Pacific Tropical Tropopause Region A. Rollins et al. 10.1029/2018JD029635
- Unexpectedly acidic nanoparticles formed in dimethylamine–ammonia–sulfuric-acid nucleation experiments at CLOUD M. Lawler et al. 10.5194/acp-16-13601-2016
- Recent advances in understanding secondary organic aerosol: Implications for global climate forcing M. Shrivastava et al. 10.1002/2016RG000540
- Theoretical study of the oxidation reactions of sulfurous acid/sulfite with ozone to produce sulfuric acid/sulfate with atmospheric implications F. Sheng et al. 10.1039/C8RA00411K
- The adsorption and oxidation of SO2on MgO surface: experimental and DFT calculation studies H. Wang et al. 10.1039/C9EN01474H
- Phase transition observations and discrimination of small cloud particles by light polarization in expansion chamber experiments L. Nichman et al. 10.5194/acp-16-3651-2016
- Effect of NOx and SO2 on the photooxidation of methylglyoxal: Implications in secondary aerosol formation S. Wang et al. 10.1016/j.jes.2020.02.011
- Trends in heterogeneous aqueous reaction in continuous haze episodes in suburban Shanghai: An in-depth case study L. Kong et al. 10.1016/j.scitotenv.2018.04.086
1 citations as recorded by crossref.
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Latest update: 01 Mar 2021
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Short summary
A significant portion of sulphate, an important constituent of atmospheric aerosols, is formed via the aqueous phase oxidation of sulphur dioxide by ozone. The rate of this reaction has previously only been measured over a relatively small temperature range. Here, we use the state of the art CLOUD chamber at CERN to perform the first measurements of this reaction rate in super-cooled droplets, confirming that the existing extrapolation of the reaction rate to sub-zero temperatures is accurate.
A significant portion of sulphate, an important constituent of atmospheric aerosols, is formed...
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