Articles | Volume 16, issue 3
https://doi.org/10.5194/acp-16-1693-2016
© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/acp-16-1693-2016
© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Aqueous phase oxidation of sulphur dioxide by ozone in cloud droplets
Laboratory of Atmospheric Chemistry, Paul Scherrer Institute, Villigen, Switzerland
WSL Institute for Snow and Avalanche Research SLF Davos, Switzerland
C. Fuchs
Laboratory of Atmospheric Chemistry, Paul Scherrer Institute, Villigen, Switzerland
E. Järvinen
Karlsruhe Institute of Technology, Institute for Meteorology and Climate Research, P.O. Box 3640, 76021 Karlsruhe, Germany
H. Saathoff
Karlsruhe Institute of Technology, Institute for Meteorology and Climate Research, P.O. Box 3640, 76021 Karlsruhe, Germany
A. Dias
CERN, 1211 Geneva, Switzerland
I. El Haddad
Laboratory of Atmospheric Chemistry, Paul Scherrer Institute, Villigen, Switzerland
Laboratory of Atmospheric Chemistry, Paul Scherrer Institute, Villigen, Switzerland
S. C. Coburn
Department of Chemistry and Biochemistry & CIRES, University of Colorado, Boulder, CO, USA
J. Tröstl
Laboratory of Atmospheric Chemistry, Paul Scherrer Institute, Villigen, Switzerland
A.-K. Bernhammer
University of Innsbruck, Institute for Ion Physics and Applied Physics, Technikerstrasse 25, 6020 Innsbruck, Austria
Ionicon Analytik GmbH, Eduard-Bodem-Gasse 3, 6020 Innsbruck, Austria
F. Bianchi
Laboratory of Atmospheric Chemistry, Paul Scherrer Institute, Villigen, Switzerland
M. Breitenlechner
University of Innsbruck, Institute for Ion Physics and Applied Physics, Technikerstrasse 25, 6020 Innsbruck, Austria
J. C. Corbin
Laboratory of Atmospheric Chemistry, Paul Scherrer Institute, Villigen, Switzerland
J. Craven
California Institute of Technology, Department of Chemical Engineering, Pasadena, CA 91125, USA
now at: Portland Technology Development Division of Intel, Hillsboro, OR, USA
N. M. Donahue
Carnegie Mellon University Center for Atmospheric Particle Studies, 5000 Forbes Ave, Pittsburgh, PA 15213, USA
J. Duplissy
Division of Atmospheric Sciences, Department of Physics, P.O. Box 64, 00014, University of Helsinki, Helsinki, Finland
S. Ehrhart
CERN, 1211 Geneva, Switzerland
Laboratory of Atmospheric Chemistry, Paul Scherrer Institute, Villigen, Switzerland
H. Gordon
CERN, 1211 Geneva, Switzerland
N. Höppel
Karlsruhe Institute of Technology, Institute for Meteorology and Climate Research, P.O. Box 3640, 76021 Karlsruhe, Germany
M. Heinritzi
Goethe University of Frankfurt, Institute for Atmospheric and Environmental Sciences, 60438 Frankfurt am Main, Germany
T. B. Kristensen
Leibniz Institute for Tropospheric Research, Permoserstrasse 15, 04318 Leipzig, Germany
U. Molteni
Laboratory of Atmospheric Chemistry, Paul Scherrer Institute, Villigen, Switzerland
L. Nichman
School of Earth, Atmospheric and Environmental Sciences, University of Manchester, Manchester, M13 9PL, UK
T. Pinterich
University of Vienna, Faculty of Physics, Aerosol and Environmental Physics, Boltzmanngasse 5, 1090 Vienna, Austria
A. S. H. Prévôt
Laboratory of Atmospheric Chemistry, Paul Scherrer Institute, Villigen, Switzerland
Goethe University of Frankfurt, Institute for Atmospheric and Environmental Sciences, 60438 Frankfurt am Main, Germany
J. G. Slowik
Laboratory of Atmospheric Chemistry, Paul Scherrer Institute, Villigen, Switzerland
G. Steiner
Division of Atmospheric Sciences, Department of Physics, P.O. Box 64, 00014, University of Helsinki, Helsinki, Finland
University of Innsbruck, Institute for Ion Physics and Applied Physics, Technikerstrasse 25, 6020 Innsbruck, Austria
University of Vienna, Faculty of Physics, Aerosol and Environmental Physics, Boltzmanngasse 5, 1090 Vienna, Austria
CENTRA-SIM, University of Lisbon and University of Beira Interior, 1749-016 Lisbon, Portugal
A. L. Vogel
CERN, 1211 Geneva, Switzerland
R. Volkamer
Department of Chemistry and Biochemistry & CIRES, University of Colorado, Boulder, CO, USA
A. C. Wagner
Goethe University of Frankfurt, Institute for Atmospheric and Environmental Sciences, 60438 Frankfurt am Main, Germany
R. Wagner
Division of Atmospheric Sciences, Department of Physics, P.O. Box 64, 00014, University of Helsinki, Helsinki, Finland
A. S. Wexler
Departments of Mechanical and Aeronautical Engineering, Civil and Environmental Engineering, and Land, Air, and Water Resources, University of California, Davis, CA, USA
C. Williamson
Goethe University of Frankfurt, Institute for Atmospheric and Environmental Sciences, 60438 Frankfurt am Main, Germany
now at: Chemical Sciences Division NOAA Earth System Research Laboratory 325 Broadway R/CSD2 Boulder, CO, USA
now at: Cooperative Institute for Research in Environmental Sciences, University of Colorado Boulder, Boulder, CO, USA
P. M. Winkler
University of Vienna, Faculty of Physics, Aerosol and Environmental Physics, Boltzmanngasse 5, 1090 Vienna, Austria
Division of Atmospheric Sciences, Department of Physics, P.O. Box 64, 00014, University of Helsinki, Helsinki, Finland
A. Amorim
CENTRA-SIM, University of Lisbon and University of Beira Interior, 1749-016 Lisbon, Portugal
J. Dommen
Laboratory of Atmospheric Chemistry, Paul Scherrer Institute, Villigen, Switzerland
J. Curtius
Goethe University of Frankfurt, Institute for Atmospheric and Environmental Sciences, 60438 Frankfurt am Main, Germany
M. W. Gallagher
School of Earth, Atmospheric and Environmental Sciences, University of Manchester, Manchester, M13 9PL, UK
NERC Instrument PI, National Centre for Atmospheric Science (NCAS), Leeds, UK
R. C. Flagan
California Institute of Technology, Department of Chemical Engineering, Pasadena, CA 91125, USA
A. Hansel
University of Innsbruck, Institute for Ion Physics and Applied Physics, Technikerstrasse 25, 6020 Innsbruck, Austria
Ionicon Analytik GmbH, Eduard-Bodem-Gasse 3, 6020 Innsbruck, Austria
J. Kirkby
CERN, 1211 Geneva, Switzerland
Goethe University of Frankfurt, Institute for Atmospheric and Environmental Sciences, 60438 Frankfurt am Main, Germany
M. Kulmala
Division of Atmospheric Sciences, Department of Physics, P.O. Box 64, 00014, University of Helsinki, Helsinki, Finland
O. Möhler
Karlsruhe Institute of Technology, Institute for Meteorology and Climate Research, P.O. Box 3640, 76021 Karlsruhe, Germany
F. Stratmann
Leibniz Institute for Tropospheric Research, Permoserstrasse 15, 04318 Leipzig, Germany
D. R. Worsnop
Division of Atmospheric Sciences, Department of Physics, P.O. Box 64, 00014, University of Helsinki, Helsinki, Finland
Aerodyne Research Inc., Billerica, MA 01821, USA
U. Baltensperger
Laboratory of Atmospheric Chemistry, Paul Scherrer Institute, Villigen, Switzerland
Viewed
Total article views: 5,605 (including HTML, PDF, and XML)
Cumulative views and downloads
(calculated since 01 Dec 2015)
HTML | XML | Total | BibTeX | EndNote | |
---|---|---|---|---|---|
3,232 | 2,196 | 177 | 5,605 | 115 | 159 |
- HTML: 3,232
- PDF: 2,196
- XML: 177
- Total: 5,605
- BibTeX: 115
- EndNote: 159
Total article views: 4,587 (including HTML, PDF, and XML)
Cumulative views and downloads
(calculated since 12 Feb 2016)
HTML | XML | Total | BibTeX | EndNote | |
---|---|---|---|---|---|
2,695 | 1,737 | 155 | 4,587 | 97 | 135 |
- HTML: 2,695
- PDF: 1,737
- XML: 155
- Total: 4,587
- BibTeX: 97
- EndNote: 135
Total article views: 1,018 (including HTML, PDF, and XML)
Cumulative views and downloads
(calculated since 01 Dec 2015)
HTML | XML | Total | BibTeX | EndNote | |
---|---|---|---|---|---|
537 | 459 | 22 | 1,018 | 18 | 24 |
- HTML: 537
- PDF: 459
- XML: 22
- Total: 1,018
- BibTeX: 18
- EndNote: 24
Cited
37 citations as recorded by crossref.
- Multiphase processes in the EC-Earth model and their relevance to the atmospheric oxalate, sulfate, and iron cycles S. Myriokefalitakis et al. 10.5194/gmd-15-3079-2022
- Observation of viscosity transition in <i>α</i>-pinene secondary organic aerosol E. Järvinen et al. 10.5194/acp-16-4423-2016
- Heterogeneous ice nucleation of viscous secondary organic aerosol produced from ozonolysis of <i>α</i>-pinene K. Ignatius et al. 10.5194/acp-16-6495-2016
- Relative Humidity Changes the Role of SO2 in Biogenic Secondary Organic Aerosol Formation L. Xu et al. 10.1021/acs.jpclett.1c01550
- A potential source of atmospheric sulfate from O<sub>2</sub><sup>−</sup>-induced SO<sub>2</sub> oxidation by ozone N. Tsona & L. Du 10.5194/acp-19-649-2019
- Influence of temperature on the molecular composition of ions and charged clusters during pure biogenic nucleation C. Frege et al. 10.5194/acp-18-65-2018
- Calculation of electron interaction models in N2 and O2 F. Nicolanti et al. 10.1016/j.ejmp.2023.102661
- Modeling atmospheric mineral aerosol chemistry to predict heterogeneous photooxidation of SO<sub>2</sub> Z. Yu et al. 10.5194/acp-17-10001-2017
- Particles liquid water and acidity determine formation of secondary inorganic ions in Urumqi, NW China H. Liu et al. 10.1016/j.atmosres.2021.105622
- Decadal Trends in Wet Sulfur Deposition in China Estimated From OMI SO2 Columns X. Zhang et al. 10.1029/2018JD028770
- On the importance of non-ideal sulphate processing of multi-component aerosol haze over urban areas S. Gumber et al. 10.1007/s00703-022-00877-7
- Molecular and physical characteristics of aerosol at a remote free troposphere site: implications for atmospheric aging S. Schum et al. 10.5194/acp-18-14017-2018
- Contribution of expanded marine sulfur chemistry to the seasonal variability of dimethyl sulfide oxidation products and size-resolved sulfate aerosol L. Tashmim et al. 10.5194/acp-24-3379-2024
- Formation of aqueous-phase sulfate during the haze period in China: Kinetics and atmospheric implications H. Zhang et al. 10.1016/j.atmosenv.2018.01.017
- Pre‐Industrial, Present and Future Atmospheric Soluble Iron Deposition and the Role of Aerosol Acidity and Oxalate Under CMIP6 Emissions E. Bergas‐Massó et al. 10.1029/2022EF003353
- Sulfur dioxide from the atmospheric chemistry experiment (ACE) satellite W. Cameron et al. 10.1016/j.jqsrt.2020.107341
- Cloud Processing of Secondary Organic Aerosol from Isoprene and Methacrolein Photooxidation C. Giorio et al. 10.1021/acs.jpca.7b05933
- Temperature uniformity in the CERN CLOUD chamber A. Dias et al. 10.5194/amt-10-5075-2017
- An oxidation flow reactor for simulating and accelerating secondary aerosol formation in aerosol liquid water and cloud droplets N. Xu et al. 10.5194/amt-17-4227-2024
- Marine versus Continental Sources of Iodine and Selenium in Rainfall at Two European High-Altitude Locations E. Suess et al. 10.1021/acs.est.8b05533
- The unintended consequence of SO<sub>2</sub> and NO<sub>2</sub> regulations over China: increase of ammonia levels and impact on PM<sub>2.5</sub> concentrations M. Lachatre et al. 10.5194/acp-19-6701-2019
- Unraveling a New Chemical Mechanism of Missing Sulfate Formation in Aerosol Haze: Gaseous NO2 with Aqueous HSO3–/SO32– J. Yang et al. 10.1021/jacs.9b08503
- Aging of atmospheric aerosols and the role of iron in catalyzing brown carbon formation H. Al-Abadleh 10.1039/D1EA00038A
- Reaction between a NO2 Dimer and Dissolved SO2: A New Mechanism for ONSO3– Formation and its Fate in Aerosol B. Tang & Z. Li 10.1021/acs.jpca.1c06215
- SO2 Observations and Sources in the Western Pacific Tropical Tropopause Region A. Rollins et al. 10.1029/2018JD029635
- Catalytic role of formaldehyde in particulate matter formation E. Dovrou et al. 10.1073/pnas.2113265119
- Unexpectedly acidic nanoparticles formed in dimethylamine–ammonia–sulfuric-acid nucleation experiments at CLOUD M. Lawler et al. 10.5194/acp-16-13601-2016
- Recent advances in understanding secondary organic aerosol: Implications for global climate forcing M. Shrivastava et al. 10.1002/2016RG000540
- Variability of sulfur and oxygen isotope values within wet precipitation and its correlation with diminished anthropogenic sulfur dioxide (SO2) emission M. Zheng et al. 10.1016/j.atmosenv.2023.120185
- Theoretical study of the oxidation reactions of sulfurous acid/sulfite with ozone to produce sulfuric acid/sulfate with atmospheric implications F. Sheng et al. 10.1039/C8RA00411K
- The adsorption and oxidation of SO2on MgO surface: experimental and DFT calculation studies H. Wang et al. 10.1039/C9EN01474H
- Phase transition observations and discrimination of small cloud particles by light polarization in expansion chamber experiments L. Nichman et al. 10.5194/acp-16-3651-2016
- Effect of NOx and SO2 on the photooxidation of methylglyoxal: Implications in secondary aerosol formation S. Wang et al. 10.1016/j.jes.2020.02.011
- Competitive formation of HSO4- and HSO5- from ion-induced SO2 oxidation: Implication in atmospheric aerosol formation N. Tsona et al. 10.1016/j.atmosenv.2021.118362
- Trends in heterogeneous aqueous reaction in continuous haze episodes in suburban Shanghai: An in-depth case study L. Kong et al. 10.1016/j.scitotenv.2018.04.086
- Elucidating the Mechanism on the Transition-Metal Ion-Synergetic-Catalyzed Oxidation of SO2 with Implications for Sulfate Formation in Beijing Haze S. Zhang et al. 10.1021/acs.est.3c08411
- Discrimination of water, ice and aerosols by light polarisation in the CLOUD experiment L. Nichman et al. 10.5194/acpd-15-31433-2015
36 citations as recorded by crossref.
- Multiphase processes in the EC-Earth model and their relevance to the atmospheric oxalate, sulfate, and iron cycles S. Myriokefalitakis et al. 10.5194/gmd-15-3079-2022
- Observation of viscosity transition in <i>α</i>-pinene secondary organic aerosol E. Järvinen et al. 10.5194/acp-16-4423-2016
- Heterogeneous ice nucleation of viscous secondary organic aerosol produced from ozonolysis of <i>α</i>-pinene K. Ignatius et al. 10.5194/acp-16-6495-2016
- Relative Humidity Changes the Role of SO2 in Biogenic Secondary Organic Aerosol Formation L. Xu et al. 10.1021/acs.jpclett.1c01550
- A potential source of atmospheric sulfate from O<sub>2</sub><sup>−</sup>-induced SO<sub>2</sub> oxidation by ozone N. Tsona & L. Du 10.5194/acp-19-649-2019
- Influence of temperature on the molecular composition of ions and charged clusters during pure biogenic nucleation C. Frege et al. 10.5194/acp-18-65-2018
- Calculation of electron interaction models in N2 and O2 F. Nicolanti et al. 10.1016/j.ejmp.2023.102661
- Modeling atmospheric mineral aerosol chemistry to predict heterogeneous photooxidation of SO<sub>2</sub> Z. Yu et al. 10.5194/acp-17-10001-2017
- Particles liquid water and acidity determine formation of secondary inorganic ions in Urumqi, NW China H. Liu et al. 10.1016/j.atmosres.2021.105622
- Decadal Trends in Wet Sulfur Deposition in China Estimated From OMI SO2 Columns X. Zhang et al. 10.1029/2018JD028770
- On the importance of non-ideal sulphate processing of multi-component aerosol haze over urban areas S. Gumber et al. 10.1007/s00703-022-00877-7
- Molecular and physical characteristics of aerosol at a remote free troposphere site: implications for atmospheric aging S. Schum et al. 10.5194/acp-18-14017-2018
- Contribution of expanded marine sulfur chemistry to the seasonal variability of dimethyl sulfide oxidation products and size-resolved sulfate aerosol L. Tashmim et al. 10.5194/acp-24-3379-2024
- Formation of aqueous-phase sulfate during the haze period in China: Kinetics and atmospheric implications H. Zhang et al. 10.1016/j.atmosenv.2018.01.017
- Pre‐Industrial, Present and Future Atmospheric Soluble Iron Deposition and the Role of Aerosol Acidity and Oxalate Under CMIP6 Emissions E. Bergas‐Massó et al. 10.1029/2022EF003353
- Sulfur dioxide from the atmospheric chemistry experiment (ACE) satellite W. Cameron et al. 10.1016/j.jqsrt.2020.107341
- Cloud Processing of Secondary Organic Aerosol from Isoprene and Methacrolein Photooxidation C. Giorio et al. 10.1021/acs.jpca.7b05933
- Temperature uniformity in the CERN CLOUD chamber A. Dias et al. 10.5194/amt-10-5075-2017
- An oxidation flow reactor for simulating and accelerating secondary aerosol formation in aerosol liquid water and cloud droplets N. Xu et al. 10.5194/amt-17-4227-2024
- Marine versus Continental Sources of Iodine and Selenium in Rainfall at Two European High-Altitude Locations E. Suess et al. 10.1021/acs.est.8b05533
- The unintended consequence of SO<sub>2</sub> and NO<sub>2</sub> regulations over China: increase of ammonia levels and impact on PM<sub>2.5</sub> concentrations M. Lachatre et al. 10.5194/acp-19-6701-2019
- Unraveling a New Chemical Mechanism of Missing Sulfate Formation in Aerosol Haze: Gaseous NO2 with Aqueous HSO3–/SO32– J. Yang et al. 10.1021/jacs.9b08503
- Aging of atmospheric aerosols and the role of iron in catalyzing brown carbon formation H. Al-Abadleh 10.1039/D1EA00038A
- Reaction between a NO2 Dimer and Dissolved SO2: A New Mechanism for ONSO3– Formation and its Fate in Aerosol B. Tang & Z. Li 10.1021/acs.jpca.1c06215
- SO2 Observations and Sources in the Western Pacific Tropical Tropopause Region A. Rollins et al. 10.1029/2018JD029635
- Catalytic role of formaldehyde in particulate matter formation E. Dovrou et al. 10.1073/pnas.2113265119
- Unexpectedly acidic nanoparticles formed in dimethylamine–ammonia–sulfuric-acid nucleation experiments at CLOUD M. Lawler et al. 10.5194/acp-16-13601-2016
- Recent advances in understanding secondary organic aerosol: Implications for global climate forcing M. Shrivastava et al. 10.1002/2016RG000540
- Variability of sulfur and oxygen isotope values within wet precipitation and its correlation with diminished anthropogenic sulfur dioxide (SO2) emission M. Zheng et al. 10.1016/j.atmosenv.2023.120185
- Theoretical study of the oxidation reactions of sulfurous acid/sulfite with ozone to produce sulfuric acid/sulfate with atmospheric implications F. Sheng et al. 10.1039/C8RA00411K
- The adsorption and oxidation of SO2on MgO surface: experimental and DFT calculation studies H. Wang et al. 10.1039/C9EN01474H
- Phase transition observations and discrimination of small cloud particles by light polarization in expansion chamber experiments L. Nichman et al. 10.5194/acp-16-3651-2016
- Effect of NOx and SO2 on the photooxidation of methylglyoxal: Implications in secondary aerosol formation S. Wang et al. 10.1016/j.jes.2020.02.011
- Competitive formation of HSO4- and HSO5- from ion-induced SO2 oxidation: Implication in atmospheric aerosol formation N. Tsona et al. 10.1016/j.atmosenv.2021.118362
- Trends in heterogeneous aqueous reaction in continuous haze episodes in suburban Shanghai: An in-depth case study L. Kong et al. 10.1016/j.scitotenv.2018.04.086
- Elucidating the Mechanism on the Transition-Metal Ion-Synergetic-Catalyzed Oxidation of SO2 with Implications for Sulfate Formation in Beijing Haze S. Zhang et al. 10.1021/acs.est.3c08411
1 citations as recorded by crossref.
Saved (preprint)
Latest update: 14 Dec 2024
Short summary
A significant portion of sulphate, an important constituent of atmospheric aerosols, is formed via the aqueous phase oxidation of sulphur dioxide by ozone. The rate of this reaction has previously only been measured over a relatively small temperature range. Here, we use the state of the art CLOUD chamber at CERN to perform the first measurements of this reaction rate in super-cooled droplets, confirming that the existing extrapolation of the reaction rate to sub-zero temperatures is accurate.
A significant portion of sulphate, an important constituent of atmospheric aerosols, is formed...
Special issue
Altmetrics
Final-revised paper
Preprint