Articles | Volume 16, issue 20
https://doi.org/10.5194/acp-16-13231-2016
© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/acp-16-13231-2016
© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Research article
| 
27 Oct 2016
Research article |
| 27 Oct 2016
Estimating N2O5 uptake coefficients using ambient measurements of NO3, N2O5, ClNO2 and particle-phase nitrate
Gavin J. Phillips
Department of Atmospheric Chemistry, Max Planck Institute for
Chemistry, Mainz, Germany
Jim Thieser
Department of Atmospheric Chemistry, Max Planck Institute for
Chemistry, Mainz, Germany
Mingjin Tang
Department of Atmospheric Chemistry, Max Planck Institute for
Chemistry, Mainz, Germany
Nicolas Sobanski
Department of Atmospheric Chemistry, Max Planck Institute for
Chemistry, Mainz, Germany
Gerhard Schuster
Department of Atmospheric Chemistry, Max Planck Institute for
Chemistry, Mainz, Germany
Johannes Fachinger
Particle Chemistry Department, Max Planck Institute for Chemistry,
Mainz, Germany
Frank Drewnick
Particle Chemistry Department, Max Planck Institute for Chemistry,
Mainz, Germany
Stephan Borrmann
Particle Chemistry Department, Max Planck Institute for Chemistry,
Mainz, Germany
Heinz Bingemer
Institute for Atmospheric and Environmental Sciences, Goethe
University, Frankfurt, Germany
Jos Lelieveld
Department of Atmospheric Chemistry, Max Planck Institute for
Chemistry, Mainz, Germany
Department of Atmospheric Chemistry, Max Planck Institute for
Chemistry, Mainz, Germany
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Latest update: 29 Mar 2025
Short summary
We use trace gas measurements (N2O5, ClNO2, NO3) and particle properties (surface area, nitrate content etc.) to derive uptake coefficients (the probability of removal from the gas-phase on a per-collision basis) for the interaction of N2O5 with ambient aerosol and also the efficiency of formation of ClNO2. The uptake coefficients show high variability but are reasonably well captured by parameterisations based on laboratory measurements.
We use trace gas measurements (N2O5, ClNO2, NO3) and particle properties (surface area, nitrate...
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