Articles | Volume 16, issue 20
https://doi.org/10.5194/acp-16-13035-2016
© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/acp-16-13035-2016
© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Research article
| 
21 Oct 2016
Research article |
| 21 Oct 2016
The effect of viscosity and diffusion on the HO2 uptake by sucrose and secondary organic aerosol particles
Pascale S. J. Lakey
School of Chemistry, University of Leeds, Woodhouse Lane, Leeds, LS2 9JT, UK
Multiphase Chemistry Department, Max Planck Institute for Chemistry, Hahn-Meitner-Weg 1, 55128 Mainz, Germany
Thomas Berkemeier
Multiphase Chemistry Department, Max Planck Institute for Chemistry, Hahn-Meitner-Weg 1, 55128 Mainz, Germany
Manuel Krapf
Paul Scherrer Institute, Villigen, Switzerland
Josef Dommen
Paul Scherrer Institute, Villigen, Switzerland
Sarah S. Steimer
Paul Scherrer Institute, Villigen, Switzerland
Lisa K. Whalley
School of Chemistry, University of Leeds, Woodhouse Lane, Leeds, LS2 9JT, UK
National Centre for Atmospheric Chemistry, University of Leeds, Woodhouse Lane, Leeds, LS2 9JT, UK
Trevor Ingham
School of Chemistry, University of Leeds, Woodhouse Lane, Leeds, LS2 9JT, UK
National Centre for Atmospheric Chemistry, University of Leeds, Woodhouse Lane, Leeds, LS2 9JT, UK
Maria T. Baeza-Romero
Escuela de Ingeniería Industrial de Toledo, Universidad de Castilla la Mancha, Avenida Carlos III s/n Real Fábrica de Armas, 45071 Toledo, Spain
Ulrich Pöschl
Multiphase Chemistry Department, Max Planck Institute for Chemistry, Hahn-Meitner-Weg 1, 55128 Mainz, Germany
Manabu Shiraiwa
Multiphase Chemistry Department, Max Planck Institute for Chemistry, Hahn-Meitner-Weg 1, 55128 Mainz, Germany
Department of Chemistry, University of California, Irvine, CA 92617, USA
Markus Ammann
Paul Scherrer Institute, Villigen, Switzerland
School of Chemistry, University of Leeds, Woodhouse Lane, Leeds, LS2 9JT, UK
National Centre for Atmospheric Chemistry, University of Leeds, Woodhouse Lane, Leeds, LS2 9JT, UK
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Cited
30 citations as recorded by crossref.
- Kinetics and impacting factors of HO2 uptake onto submicron atmospheric aerosols during the 2019 Air QUAlity Study (AQUAS) in Yokohama, Japan J. Zhou et al. 10.5194/acp-21-12243-2021
- Influence of Particle Physical State on the Uptake of Medium-Sized Organic Molecules Z. Gong et al. 10.1021/acs.est.8b02119
- Reduced Aerosol Uptake of Hydroperoxyl Radical May Increase the Sensitivity of Ozone Production to Volatile Organic Compounds H. Song et al. 10.1021/acs.estlett.1c00893
- Effects of Phase State and Phase Separation on Dimethylamine Uptake of Ammonium Sulfate and Ammonium Sulfate–Sucrose Mixed Particles W. DeRieux et al. 10.1021/acsearthspacechem.9b00142
- Classical Molecular Dynamics Study of Small-Chain Carboxylic Acid Aerosol Particles A. Roose et al. 10.1021/acsearthspacechem.8b00172
- Influence of aerosol copper on HO2 uptake: a novel parameterized equation H. Song et al. 10.5194/acp-20-15835-2020
- Towards a better understanding of the HO2uptake coefficient to aerosol particles measured during laboratory experiments P. Lakey et al. 10.1039/D4EA00025K
- Effective mass accommodation for partitioning of organic compounds into surface films with different viscosities P. Lakey et al. 10.1039/D3EM00213F
- Multiple Impacts of Aerosols on O3 Production Are Largely Compensated: A Case Study Shenzhen, China Z. Tan et al. 10.1021/acs.est.2c06217
- The number fraction of iron-containing particles affects OH, HO2 and H2O2 budgets in the atmospheric aqueous phase A. Khaled et al. 10.5194/acp-22-1989-2022
- Investigation of HO2 uptake mechanisms onto multiple-component ambient aerosols collected in summer and winter time in Yokohama, Japan J. Zhou et al. 10.1016/j.jes.2023.02.030
- Kinetic multilayer models for surface chemistry in indoor environments P. Lakey & M. Shiraiwa 10.1039/D4EM00549J
- Heterogeneous OH Oxidation, Shielding Effects, and Implications for the Atmospheric Fate of Terbuthylazine and Other Pesticides J. Socorro et al. 10.1021/acs.est.7b04307
- Real-time quantification of the total HO2 reactivity of ambient air and HO2 uptake kinetics onto ambient aerosols in Kyoto (Japan) J. Zhou et al. 10.1016/j.atmosenv.2019.117189
- The phase state and viscosity of organic aerosol and related impacts on atmospheric physicochemical processes: A review Y. Gou et al. 10.1016/j.atmosenv.2024.120985
- Kinetic multi‐layer model of film formation, growth, and chemistry (KM‐FILM): Boundary layer processes, multi‐layer adsorption, bulk diffusion, and heterogeneous reactions P. Lakey et al. 10.1111/ina.12854
- Investigation of HO2uptake onto Cu(ii)- and Fe(ii)-doped aqueous inorganic aerosols and seawater aerosols using laser spectroscopic techniques J. Li et al. 10.1039/D3EA00093A
- Particle-Phase Photosensitized Radical Production and Aerosol Aging P. Corral Arroyo et al. 10.1021/acs.est.8b00329
- Atmospheric oxidation in the presence of clouds during the Deep Convective Clouds and Chemistry (DC3) study W. Brune et al. 10.5194/acp-18-14493-2018
- Understanding interactions of organic nitrates with the surface and bulk of organic films: implications for particle growth in the atmosphere A. Vander Wall et al. 10.1039/C8EM00348C
- Influence of relative humidity on the heterogeneous oxidation of secondary organic aerosol Z. Li et al. 10.5194/acp-18-14585-2018
- Role of Hydroperoxyl Radicals in Heterogeneous Oxidation of Oxygenated Organic Aerosols W. Zhang et al. 10.1021/acs.est.3c09024
- Impacts of missing OH reactivity and aerosol uptake of HO2 radicals on tropospheric O3 production during the AQUAS-Kyoto summer campaign in 2018 N. Kohno et al. 10.1016/j.atmosenv.2022.119130
- Desorption lifetimes and activation energies influencing gas–surface interactions and multiphase chemical kinetics D. Knopf et al. 10.5194/acp-24-3445-2024
- Predictions of diffusion rates of large organic molecules in secondary organic aerosols using the Stokes–Einstein and fractional Stokes–Einstein relations E. Evoy et al. 10.5194/acp-19-10073-2019
- Multiphase Kinetic Multilayer Model Interfaces for Simulating Surface and Bulk Chemistry for Environmental and Atmospheric Chemistry Teaching A. Hua et al. 10.1021/acs.jchemed.1c00931
- The frequency-dependent response of single aerosol particles to vapour phase oscillations and its application in measuring diffusion coefficients T. Preston et al. 10.1039/C6CP07711K
- Real-time monitoring of cellular Ca2+ efflux with renewable graphene field effect transistor biosensor Y. Lei et al. 10.1016/j.carbon.2022.09.037
- Fractal analysis of impact of PM2.5 on surface O3 sensitivity regime based on field observations C. Liu et al. 10.1016/j.scitotenv.2022.160136
- Measurements and Predictions of Binary Component Aerosol Particle Viscosity Y. Song et al. 10.1021/acs.jpca.6b07835
29 citations as recorded by crossref.
- Kinetics and impacting factors of HO2 uptake onto submicron atmospheric aerosols during the 2019 Air QUAlity Study (AQUAS) in Yokohama, Japan J. Zhou et al. 10.5194/acp-21-12243-2021
- Influence of Particle Physical State on the Uptake of Medium-Sized Organic Molecules Z. Gong et al. 10.1021/acs.est.8b02119
- Reduced Aerosol Uptake of Hydroperoxyl Radical May Increase the Sensitivity of Ozone Production to Volatile Organic Compounds H. Song et al. 10.1021/acs.estlett.1c00893
- Effects of Phase State and Phase Separation on Dimethylamine Uptake of Ammonium Sulfate and Ammonium Sulfate–Sucrose Mixed Particles W. DeRieux et al. 10.1021/acsearthspacechem.9b00142
- Classical Molecular Dynamics Study of Small-Chain Carboxylic Acid Aerosol Particles A. Roose et al. 10.1021/acsearthspacechem.8b00172
- Influence of aerosol copper on HO2 uptake: a novel parameterized equation H. Song et al. 10.5194/acp-20-15835-2020
- Towards a better understanding of the HO2uptake coefficient to aerosol particles measured during laboratory experiments P. Lakey et al. 10.1039/D4EA00025K
- Effective mass accommodation for partitioning of organic compounds into surface films with different viscosities P. Lakey et al. 10.1039/D3EM00213F
- Multiple Impacts of Aerosols on O3 Production Are Largely Compensated: A Case Study Shenzhen, China Z. Tan et al. 10.1021/acs.est.2c06217
- The number fraction of iron-containing particles affects OH, HO2 and H2O2 budgets in the atmospheric aqueous phase A. Khaled et al. 10.5194/acp-22-1989-2022
- Investigation of HO2 uptake mechanisms onto multiple-component ambient aerosols collected in summer and winter time in Yokohama, Japan J. Zhou et al. 10.1016/j.jes.2023.02.030
- Kinetic multilayer models for surface chemistry in indoor environments P. Lakey & M. Shiraiwa 10.1039/D4EM00549J
- Heterogeneous OH Oxidation, Shielding Effects, and Implications for the Atmospheric Fate of Terbuthylazine and Other Pesticides J. Socorro et al. 10.1021/acs.est.7b04307
- Real-time quantification of the total HO2 reactivity of ambient air and HO2 uptake kinetics onto ambient aerosols in Kyoto (Japan) J. Zhou et al. 10.1016/j.atmosenv.2019.117189
- The phase state and viscosity of organic aerosol and related impacts on atmospheric physicochemical processes: A review Y. Gou et al. 10.1016/j.atmosenv.2024.120985
- Kinetic multi‐layer model of film formation, growth, and chemistry (KM‐FILM): Boundary layer processes, multi‐layer adsorption, bulk diffusion, and heterogeneous reactions P. Lakey et al. 10.1111/ina.12854
- Investigation of HO2uptake onto Cu(ii)- and Fe(ii)-doped aqueous inorganic aerosols and seawater aerosols using laser spectroscopic techniques J. Li et al. 10.1039/D3EA00093A
- Particle-Phase Photosensitized Radical Production and Aerosol Aging P. Corral Arroyo et al. 10.1021/acs.est.8b00329
- Atmospheric oxidation in the presence of clouds during the Deep Convective Clouds and Chemistry (DC3) study W. Brune et al. 10.5194/acp-18-14493-2018
- Understanding interactions of organic nitrates with the surface and bulk of organic films: implications for particle growth in the atmosphere A. Vander Wall et al. 10.1039/C8EM00348C
- Influence of relative humidity on the heterogeneous oxidation of secondary organic aerosol Z. Li et al. 10.5194/acp-18-14585-2018
- Role of Hydroperoxyl Radicals in Heterogeneous Oxidation of Oxygenated Organic Aerosols W. Zhang et al. 10.1021/acs.est.3c09024
- Impacts of missing OH reactivity and aerosol uptake of HO2 radicals on tropospheric O3 production during the AQUAS-Kyoto summer campaign in 2018 N. Kohno et al. 10.1016/j.atmosenv.2022.119130
- Desorption lifetimes and activation energies influencing gas–surface interactions and multiphase chemical kinetics D. Knopf et al. 10.5194/acp-24-3445-2024
- Predictions of diffusion rates of large organic molecules in secondary organic aerosols using the Stokes–Einstein and fractional Stokes–Einstein relations E. Evoy et al. 10.5194/acp-19-10073-2019
- Multiphase Kinetic Multilayer Model Interfaces for Simulating Surface and Bulk Chemistry for Environmental and Atmospheric Chemistry Teaching A. Hua et al. 10.1021/acs.jchemed.1c00931
- The frequency-dependent response of single aerosol particles to vapour phase oscillations and its application in measuring diffusion coefficients T. Preston et al. 10.1039/C6CP07711K
- Real-time monitoring of cellular Ca2+ efflux with renewable graphene field effect transistor biosensor Y. Lei et al. 10.1016/j.carbon.2022.09.037
- Fractal analysis of impact of PM2.5 on surface O3 sensitivity regime based on field observations C. Liu et al. 10.1016/j.scitotenv.2022.160136
1 citations as recorded by crossref.
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Discussed (preprint)
Latest update: 03 Jul 2025
Short summary
Chemical oxidation in the atmosphere removes pollutants and greenhouse gases but generates undesirable products such as secondary organic aerosol. Radicals are key intermediates in oxidation, but how they interact with aerosols is still not well understood. Here we use a laser to measure the loss of radicals onto oxidised aerosols generated in a smog chamber. The loss of radicals was controlled by the thickness or viscosity of the aerosols, confirmed by using sugar aerosols of known thickness.
Chemical oxidation in the atmosphere removes pollutants and greenhouse gases but generates...
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