Articles | Volume 16, issue 19
https://doi.org/10.5194/acp-16-12631-2016
© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/acp-16-12631-2016
© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Research article
| 
11 Oct 2016
Research article |
| 11 Oct 2016
Photochemical organonitrate formation in wet aerosols
Center for Environment, Health and Welfare Research, Korea Institute
of Science and Technology, Seoul 02792, Republic of Korea
Department of Environmental Sciences, Rutgers University, New
Brunswick, New Jersey 08901, USA
Hwajin Kim
Center for Environment, Health and Welfare Research, Korea Institute
of Science and Technology, Seoul 02792, Republic of Korea
Department of Energy and Environmental Engineering, University of
Science and Technology, Daejeon 34113, Republic of Korea
Jin Young Kim
CORRESPONDING AUTHOR
Center for Environment, Health and Welfare Research, Korea Institute
of Science and Technology, Seoul 02792, Republic of Korea
Department of Energy and Environmental Engineering, University of
Science and Technology, Daejeon 34113, Republic of Korea
Barbara J. Turpin
Department of Environmental Science and Engineering, University of
North Carolina, Chapel Hill, North Carolina 27599, USA
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Cited
22 citations as recorded by crossref.
- Precursors and Pathways Leading to Enhanced Secondary Organic Aerosol Formation during Severe Haze Episodes Y. Zheng et al. 10.1021/acs.est.1c04255
- On the multiday haze in the Asian continental outflow: the important role of synoptic conditions combined with regional and local sources J. Seo et al. 10.5194/acp-17-9311-2017
- Abundance of organosulfates derived from biogenic volatile organic compounds: Seasonal and spatial contrasts at four sites in China Y. Wang et al. 10.1016/j.scitotenv.2021.151275
- Photochemistry of glyoxylate embedded in sodium chloride clusters, a laboratory model for tropospheric sea-salt aerosols N. Bersenkowitsch et al. 10.1039/C8CP00399H
- Secondary organic aerosol formed by Euro 5 gasoline vehicle emissions: chemical composition and gas-to-particle phase partitioning E. Kostenidou et al. 10.5194/acp-24-2705-2024
- New measurements reveal a large contribution of nitrogenous molecules to ambient organic aerosol X. Yu et al. 10.1038/s41612-024-00620-6
- Analysis of reduced and oxidized nitrogen-containing organic compounds at a coastal site in summer and winter J. Ditto et al. 10.5194/acp-22-3045-2022
- Water Soluble Organic Nitrogen (WSON) in Ambient Fine Particles Over a Megacity in South China: Spatiotemporal Variations and Source Apportionment X. Yu et al. 10.1002/2017JD027327
- Interfacial Ozone Oxidation Chemistry at a Riverine Surface Microlayer as a Source of Nitrogen Organic Compounds Y. Wang et al. 10.1021/acs.estlett.2c00130
- Evolution of nucleophilic high molecular-weight organic compounds in ambient aerosols: a case study C. He et al. 10.5194/acp-24-1627-2024
- Hydrazine and its Derivatives: Role on Nitrogen Dioxide Hydrolysis and Ensuing Nucleation in the Atmosphere S. Ni et al. 10.1002/slct.202304403
- Process analysis of elevated concentrations of organic acids at Whiteface Mountain, New York C. Lawrence et al. 10.5194/acp-24-13693-2024
- Photochemical Degradation of Organic Matter in the Atmosphere W. Hu et al. 10.1002/adsu.202100027
- More water-soluble brown carbon after the residential “coal-to-gas” conversion measure in urban Beijing W. Yuan et al. 10.1038/s41612-023-00355-w
- Aging of atmospheric aerosols and the role of iron in catalyzing brown carbon formation H. Al-Abadleh 10.1039/D1EA00038A
- Mass Spectrometry Analysis in Atmospheric Chemistry J. Laskin et al. 10.1021/acs.analchem.7b04249
- Enhanced Wet Deposition of Water‐Soluble Organic Nitrogen During the Harvest Season: Influence of Biomass Burning and In‐Cloud Scavenging X. Yu et al. 10.1029/2020JD032699
- Reversible and irreversible gas–particle partitioning of dicarbonyl compounds observed in the real atmosphere J. Hu et al. 10.5194/acp-22-6971-2022
- Synthesis and Hydrolysis of Atmospherically Relevant Monoterpene-Derived Organic Nitrates Y. Wang et al. 10.1021/acs.est.1c05310
- Assessment of PM2.5-bound nitrogen-containing organic compounds (NOCs) during winter at urban sites in China and Korea K. Jang et al. 10.1016/j.envpol.2020.114870
- Field observational constraints on the controllers in glyoxal (CHOCHO) reactive uptake to aerosol D. Kim et al. 10.5194/acp-22-805-2022
- A perspective on iron (Fe) in the atmosphere: air quality, climate, and the ocean H. Al-Abadleh et al. 10.1039/D2EM00176D
22 citations as recorded by crossref.
- Precursors and Pathways Leading to Enhanced Secondary Organic Aerosol Formation during Severe Haze Episodes Y. Zheng et al. 10.1021/acs.est.1c04255
- On the multiday haze in the Asian continental outflow: the important role of synoptic conditions combined with regional and local sources J. Seo et al. 10.5194/acp-17-9311-2017
- Abundance of organosulfates derived from biogenic volatile organic compounds: Seasonal and spatial contrasts at four sites in China Y. Wang et al. 10.1016/j.scitotenv.2021.151275
- Photochemistry of glyoxylate embedded in sodium chloride clusters, a laboratory model for tropospheric sea-salt aerosols N. Bersenkowitsch et al. 10.1039/C8CP00399H
- Secondary organic aerosol formed by Euro 5 gasoline vehicle emissions: chemical composition and gas-to-particle phase partitioning E. Kostenidou et al. 10.5194/acp-24-2705-2024
- New measurements reveal a large contribution of nitrogenous molecules to ambient organic aerosol X. Yu et al. 10.1038/s41612-024-00620-6
- Analysis of reduced and oxidized nitrogen-containing organic compounds at a coastal site in summer and winter J. Ditto et al. 10.5194/acp-22-3045-2022
- Water Soluble Organic Nitrogen (WSON) in Ambient Fine Particles Over a Megacity in South China: Spatiotemporal Variations and Source Apportionment X. Yu et al. 10.1002/2017JD027327
- Interfacial Ozone Oxidation Chemistry at a Riverine Surface Microlayer as a Source of Nitrogen Organic Compounds Y. Wang et al. 10.1021/acs.estlett.2c00130
- Evolution of nucleophilic high molecular-weight organic compounds in ambient aerosols: a case study C. He et al. 10.5194/acp-24-1627-2024
- Hydrazine and its Derivatives: Role on Nitrogen Dioxide Hydrolysis and Ensuing Nucleation in the Atmosphere S. Ni et al. 10.1002/slct.202304403
- Process analysis of elevated concentrations of organic acids at Whiteface Mountain, New York C. Lawrence et al. 10.5194/acp-24-13693-2024
- Photochemical Degradation of Organic Matter in the Atmosphere W. Hu et al. 10.1002/adsu.202100027
- More water-soluble brown carbon after the residential “coal-to-gas” conversion measure in urban Beijing W. Yuan et al. 10.1038/s41612-023-00355-w
- Aging of atmospheric aerosols and the role of iron in catalyzing brown carbon formation H. Al-Abadleh 10.1039/D1EA00038A
- Mass Spectrometry Analysis in Atmospheric Chemistry J. Laskin et al. 10.1021/acs.analchem.7b04249
- Enhanced Wet Deposition of Water‐Soluble Organic Nitrogen During the Harvest Season: Influence of Biomass Burning and In‐Cloud Scavenging X. Yu et al. 10.1029/2020JD032699
- Reversible and irreversible gas–particle partitioning of dicarbonyl compounds observed in the real atmosphere J. Hu et al. 10.5194/acp-22-6971-2022
- Synthesis and Hydrolysis of Atmospherically Relevant Monoterpene-Derived Organic Nitrates Y. Wang et al. 10.1021/acs.est.1c05310
- Assessment of PM2.5-bound nitrogen-containing organic compounds (NOCs) during winter at urban sites in China and Korea K. Jang et al. 10.1016/j.envpol.2020.114870
- Field observational constraints on the controllers in glyoxal (CHOCHO) reactive uptake to aerosol D. Kim et al. 10.5194/acp-22-805-2022
- A perspective on iron (Fe) in the atmosphere: air quality, climate, and the ocean H. Al-Abadleh et al. 10.1039/D2EM00176D
Saved (preprint)
Latest update: 22 Feb 2025
Short summary
We report that organonitrates were photochemically formed in wet aerosols via aqueous chemistry in the NOx–O3 chamber at high humidity. Organonitrates are considered to form in the gas phase (peroxy radical–NO during the daytime or VOC–NO3 during the nighttime); however, our chamber study results suggest daytime organonitrate formation in polluted and humid areas. Besides organonitrates, organonitrogens, organosulfates, and organonitrogen sulfates were also dominant photooxidation products.
We report that organonitrates were photochemically formed in wet aerosols via aqueous chemistry...
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