Articles | Volume 16, issue 19
https://doi.org/10.5194/acp-16-12513-2016
© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/acp-16-12513-2016
© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Research article
| 
07 Oct 2016
Research article |
| 07 Oct 2016
Chemical ionization of clusters formed from sulfuric acid and dimethylamine or diamines
Department of Mechanical Engineering, University of Minnesota, Twin
Cities, 111 Church St. SE, Minneapolis, MN 55455, USA
now at: Department of Environmental Science, Policy, and Management,
University of California, Berkeley, Hilgard Hall, Berkeley, CA 94720, USA
Department of Mechanical Engineering, University of Minnesota, Twin
Cities, 111 Church St. SE, Minneapolis, MN 55455, USA
now at: Institute of Earth Climate and Environment System, Sun Yat-sen
University, 135 West Xingang Road, 510275 Guangzhou, China
Peter H. McMurry
Department of Mechanical Engineering, University of Minnesota, Twin
Cities, 111 Church St. SE, Minneapolis, MN 55455, USA
David R. Hanson
Department of Chemistry, Augsburg College, 2211 Riverside Ave.,
Minneapolis, MN 55454, USA
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Cited
28 citations as recorded by crossref.
- Temperature effects on sulfuric acid aerosol nucleation and growth: initial results from the TANGENT study L. Tiszenkel et al. 10.5194/acp-19-8915-2019
- The missing base molecules in atmospheric acid–base nucleation R. Cai et al. 10.1093/nsr/nwac137
- New Particle Formation in the Atmosphere: From Molecular Clusters to Global Climate S. Lee et al. 10.1029/2018JD029356
- Limited Role of Malonic Acid in Sulfuric Acid–Dimethylamine New Particle Formation S. Fomete et al. 10.1021/acsomega.3c01643
- Observation of new particle formation and measurement of sulfuric acid, ammonia, amines and highly oxidized organic molecules at a rural site in central Germany A. Kürten et al. 10.5194/acp-16-12793-2016
- What Is Required for Highly Oxidized Molecules To Form Clusters with Sulfuric Acid? J. Elm et al. 10.1021/acs.jpca.7b03759
- The potential role of organics in new particle formation and initial growth in the remote tropical upper troposphere A. Kupc et al. 10.5194/acp-20-15037-2020
- Size-Resolved Chemical Composition of Sub-20 nm Particles from Methanesulfonic Acid Reactions with Methylamine and Ammonia V. Perraud et al. 10.1021/acsearthspacechem.0c00120
- Formation of atmospheric molecular clusters consisting of methanesulfonic acid and sulfuric acid: Insights from flow tube experiments and cluster dynamics simulations H. Wen et al. 10.1016/j.atmosenv.2018.11.043
- New particle formation from sulfuric acid and ammonia: nucleation and growth model based on thermodynamics derived from CLOUD measurements for a wide range of conditions A. Kürten 10.5194/acp-19-5033-2019
- Exploring the potential of nano-Köhler theory to describe the growth of atmospheric molecular clusters by organic vapors using cluster kinetics simulations J. Kontkanen et al. 10.5194/acp-18-13733-2018
- Understanding vapor nucleation on the molecular level: A review C. Li & R. Signorell 10.1016/j.jaerosci.2020.105676
- Synergistic effect of glutaric acid and ammonia/amine/amide on their hydrates in the clustering: A theoretical study S. Ni et al. 10.1016/j.chemosphere.2021.130063
- Computational Fluid Dynamics Studies of a Flow Reactor: Free Energies of Clusters of Sulfuric Acid with NH3 or Dimethyl Amine D. Hanson et al. 10.1021/acs.jpca.7b00252
- Ion–Molecule Rate Constants for Reactions of Sulfuric Acid with Acetate and Nitrate Ions S. Fomete et al. 10.1021/acs.jpca.2c02072
- Interaction of Glutamic Acid/Protonated Glutamic Acid with Amide and Water Molecules: A Theoretical Study J. Liu et al. 10.1021/acs.jpca.2c05135
- Experimental and Theoretical Study on the Enhancement of Alkanolamines on Sulfuric Acid Nucleation S. Fomete et al. 10.1021/acs.jpca.2c01672
- Quantitation of 11 alkylamines in atmospheric samples: separating structural isomers by ion chromatography B. Place et al. 10.5194/amt-10-1061-2017
- The Synergistic Role of Sulfuric Acid, Bases, and Oxidized Organics Governing New‐Particle Formation in Beijing C. Yan et al. 10.1029/2020GL091944
- A tutorial guide on new particle formation experiments using a laminar flow reactor S. Fomete et al. 10.1016/j.jaerosci.2021.105808
- Investigation of several proxies to estimate sulfuric acid concentration under volcanic plume conditions C. Rose et al. 10.5194/acp-21-4541-2021
- Surface modulated dissociation of organic aerosol acids and bases in different atmospheric environments G. Sengupta & N. Prisle 10.1080/02786826.2024.2323641
- Sulfuric Acid Nucleation Potential Model Applied to Complex Reacting Systems in the Atmosphere J. Johnson & C. Jen 10.1029/2023JD039344
- Molecular insights into new particle formation in Barcelona, Spain J. Brean et al. 10.5194/acp-20-10029-2020
- New particle formation in the sulfuric acid–dimethylamine–water system: reevaluation of CLOUD chamber measurements and comparison to an aerosol nucleation and growth model A. Kürten et al. 10.5194/acp-18-845-2018
- An Atmospheric Cluster Database Consisting of Sulfuric Acid, Bases, Organics, and Water J. Elm 10.1021/acsomega.9b00860
- Role of Methanesulfonic Acid in Sulfuric Acid–Amine and Ammonia New Particle Formation J. Johnson & C. Jen 10.1021/acsearthspacechem.3c00017
- Modeling the formation and growth of atmospheric molecular clusters: A review J. Elm et al. 10.1016/j.jaerosci.2020.105621
28 citations as recorded by crossref.
- Temperature effects on sulfuric acid aerosol nucleation and growth: initial results from the TANGENT study L. Tiszenkel et al. 10.5194/acp-19-8915-2019
- The missing base molecules in atmospheric acid–base nucleation R. Cai et al. 10.1093/nsr/nwac137
- New Particle Formation in the Atmosphere: From Molecular Clusters to Global Climate S. Lee et al. 10.1029/2018JD029356
- Limited Role of Malonic Acid in Sulfuric Acid–Dimethylamine New Particle Formation S. Fomete et al. 10.1021/acsomega.3c01643
- Observation of new particle formation and measurement of sulfuric acid, ammonia, amines and highly oxidized organic molecules at a rural site in central Germany A. Kürten et al. 10.5194/acp-16-12793-2016
- What Is Required for Highly Oxidized Molecules To Form Clusters with Sulfuric Acid? J. Elm et al. 10.1021/acs.jpca.7b03759
- The potential role of organics in new particle formation and initial growth in the remote tropical upper troposphere A. Kupc et al. 10.5194/acp-20-15037-2020
- Size-Resolved Chemical Composition of Sub-20 nm Particles from Methanesulfonic Acid Reactions with Methylamine and Ammonia V. Perraud et al. 10.1021/acsearthspacechem.0c00120
- Formation of atmospheric molecular clusters consisting of methanesulfonic acid and sulfuric acid: Insights from flow tube experiments and cluster dynamics simulations H. Wen et al. 10.1016/j.atmosenv.2018.11.043
- New particle formation from sulfuric acid and ammonia: nucleation and growth model based on thermodynamics derived from CLOUD measurements for a wide range of conditions A. Kürten 10.5194/acp-19-5033-2019
- Exploring the potential of nano-Köhler theory to describe the growth of atmospheric molecular clusters by organic vapors using cluster kinetics simulations J. Kontkanen et al. 10.5194/acp-18-13733-2018
- Understanding vapor nucleation on the molecular level: A review C. Li & R. Signorell 10.1016/j.jaerosci.2020.105676
- Synergistic effect of glutaric acid and ammonia/amine/amide on their hydrates in the clustering: A theoretical study S. Ni et al. 10.1016/j.chemosphere.2021.130063
- Computational Fluid Dynamics Studies of a Flow Reactor: Free Energies of Clusters of Sulfuric Acid with NH3 or Dimethyl Amine D. Hanson et al. 10.1021/acs.jpca.7b00252
- Ion–Molecule Rate Constants for Reactions of Sulfuric Acid with Acetate and Nitrate Ions S. Fomete et al. 10.1021/acs.jpca.2c02072
- Interaction of Glutamic Acid/Protonated Glutamic Acid with Amide and Water Molecules: A Theoretical Study J. Liu et al. 10.1021/acs.jpca.2c05135
- Experimental and Theoretical Study on the Enhancement of Alkanolamines on Sulfuric Acid Nucleation S. Fomete et al. 10.1021/acs.jpca.2c01672
- Quantitation of 11 alkylamines in atmospheric samples: separating structural isomers by ion chromatography B. Place et al. 10.5194/amt-10-1061-2017
- The Synergistic Role of Sulfuric Acid, Bases, and Oxidized Organics Governing New‐Particle Formation in Beijing C. Yan et al. 10.1029/2020GL091944
- A tutorial guide on new particle formation experiments using a laminar flow reactor S. Fomete et al. 10.1016/j.jaerosci.2021.105808
- Investigation of several proxies to estimate sulfuric acid concentration under volcanic plume conditions C. Rose et al. 10.5194/acp-21-4541-2021
- Surface modulated dissociation of organic aerosol acids and bases in different atmospheric environments G. Sengupta & N. Prisle 10.1080/02786826.2024.2323641
- Sulfuric Acid Nucleation Potential Model Applied to Complex Reacting Systems in the Atmosphere J. Johnson & C. Jen 10.1029/2023JD039344
- Molecular insights into new particle formation in Barcelona, Spain J. Brean et al. 10.5194/acp-20-10029-2020
- New particle formation in the sulfuric acid–dimethylamine–water system: reevaluation of CLOUD chamber measurements and comparison to an aerosol nucleation and growth model A. Kürten et al. 10.5194/acp-18-845-2018
- An Atmospheric Cluster Database Consisting of Sulfuric Acid, Bases, Organics, and Water J. Elm 10.1021/acsomega.9b00860
- Role of Methanesulfonic Acid in Sulfuric Acid–Amine and Ammonia New Particle Formation J. Johnson & C. Jen 10.1021/acsearthspacechem.3c00017
- Modeling the formation and growth of atmospheric molecular clusters: A review J. Elm et al. 10.1016/j.jaerosci.2020.105621
Latest update: 17 Jul 2024
Short summary
Chemical ionization mass spectrometry measurements of clusters formed from sulfuric acid and dimethylamine or various diamines show that these clusters are not as efficiently ionized by nitrate as they are by acetate. These clusters are atmospherically relevant, and our results suggest that traditional methods may under-measure cluster concentrations by up to a factor of 10.
Chemical ionization mass spectrometry measurements of clusters formed from sulfuric acid and...
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