Articles | Volume 15, issue 16
https://doi.org/10.5194/acp-15-9521-2015
© Author(s) 2015. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/acp-15-9521-2015
© Author(s) 2015. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Atmospheric isoprene ozonolysis: impacts of stabilised Criegee intermediate reactions with SO2, H2O and dimethyl sulfide
M. J. Newland
University of Birmingham, School of Geography, Earth and Environmental Sciences, Birmingham, UK
now at: University of East Anglia, School of Environmental Sciences, Norwich, UK
National Centre for Atmospheric Science (NCAS), University of York, York, UK
Wolfson Atmospheric Chemistry Laboratories, Department of Chemistry, University of York, York, UK
L. Vereecken
Max Planck Institute for Chemistry, Atmospheric Sciences, J.-J.-Becher-Weg 27, Mainz, Germany
Instituto Universitario CEAM-UMH, EUPHORE Laboratories, Avda/Charles R. Darwin, Parque Tecnologico, Valencia, Spain
M. Ródenas
Instituto Universitario CEAM-UMH, EUPHORE Laboratories, Avda/Charles R. Darwin, Parque Tecnologico, Valencia, Spain
University of Birmingham, School of Geography, Earth and Environmental Sciences, Birmingham, UK
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Cited
58 citations as recorded by crossref.
- Electronic Absorption Spectroscopy and Photochemistry of Criegee Intermediates T. Karsili et al. 10.1111/php.13665
- The reaction of OH radical with the Criegee intermediate propanone oxide: Theoretical investigations V. Saheb & A. Nazari 10.1016/j.comptc.2020.112726
- Low molecular weight dicarboxylic acids, oxocarboxylic acids and α-dicarbonyls as ozonolysis products of isoprene: Implication for the gaseous-phase formation of secondary organic aerosols S. Bikkina et al. 10.1016/j.scitotenv.2020.144472
- Temperature‐Dependence of the Rates of Reaction of Trifluoroacetic Acid with Criegee Intermediates R. Chhantyal‐Pun et al. 10.1002/anie.201703700
- The atmospheric impacts of monoterpene ozonolysis on global stabilised Criegee intermediate budgets and SO<sub>2</sub> oxidation: experiment, theory and modelling M. Newland et al. 10.5194/acp-18-6095-2018
- How does substitution affect the unimolecular reaction rates of Criegee intermediates? C. Yin & K. Takahashi 10.1039/C7CP01091E
- Theoretical kinetics studies on the temperature and pressure dependence of the reaction of ammonia with the Criegee intermediate CH2OO A. Nazari & V. Saheb 10.1007/s00214-022-02930-5
- Atmospheric Kinetics: Bimolecular Reactions of Carbonyl Oxide by a Triple-Level Strategy B. Long et al. 10.1021/jacs.1c02029
- Toward Building a Physical Proxy for Gas-Phase Sulfuric Acid Concentration Based on Its Budget Analysis in Polluted Yangtze River Delta, East China L. Yang et al. 10.1021/acs.est.1c00738
- An Estimation of the Levels of Stabilized Criegee Intermediates in the UK Urban and Rural Atmosphere Using the Steady-State Approximation and the Potential Effects of These Intermediates on Tropospheric Oxidation Cycles M. H. Khan et al. 10.1002/kin.21101
- Gas-phase broadband spectroscopy using active sources: progress, status, and applications [Invited] K. Cossel et al. 10.1364/JOSAB.34.000104
- Surprisingly long lifetime of methacrolein oxide, an isoprene derived Criegee intermediate, under humid conditions Y. Lin et al. 10.1038/s42004-021-00451-z
- Direct kinetic measurements and theoretical predictions of an isoprene-derived Criegee intermediate R. Caravan et al. 10.1073/pnas.1916711117
- Competition between H2O and (H2O)2 reactions with CH2OO/CH3CHOO L. Lin et al. 10.1039/C5CP06446E
- Low-pressure and nascent yields of stabilized Criegee intermediates CH2OO and CH3CHOO in ozonolysis of propene L. Yang et al. 10.1039/D3CP02590J
- Emission characteristics of 99 NMVOCs in different seasonal days and the relationship with air quality parameters in Beijing, China Y. Gu et al. 10.1016/j.ecoenv.2018.11.091
- Quantification of Gas-to-Particle Conversion Rates of Sulfur in the Terrestrial Atmosphere Using High-Sensitivity Measurements of Cosmogenic 35S M. Lin et al. 10.1021/acsearthspacechem.7b00047
- Molecular response of poplar to single and combined ozone and drought J. Zhang et al. 10.1016/j.scitotenv.2018.11.195
- Increased primary and secondary H<sub>2</sub>SO<sub>4</sub> showing the opposing roles in secondary organic aerosol formation from ethyl methacrylate ozonolysis P. Zhang et al. 10.5194/acp-21-7099-2021
- Oligomerization reactions for precursors to secondary organic aerosol: Comparison between two formation mechanisms for the oligomeric hydroxyalkyl hydroperoxides Q. Zhao et al. 10.1016/j.atmosenv.2017.07.008
- Investigation of potential interferences in the detection of atmospheric RO<sub><i>x</i></sub> radicals by laser-induced fluorescence under dark conditions H. Fuchs et al. 10.5194/amt-9-1431-2016
- Formation of secondary organic aerosols from the ozonolysis of dihydrofurans Y. Diaz-de-Mera et al. 10.5194/acp-17-2347-2017
- Criegee intermediates and their impacts on the troposphere M. Khan et al. 10.1039/C7EM00585G
- Formation of nighttime sulfuric acid from the ozonolysis of alkenes in Beijing Y. Guo et al. 10.5194/acp-21-5499-2021
- Water vapour effects on secondary organic aerosol formation in isoprene ozonolysis Y. Sakamoto et al. 10.1039/C6CP04521A
- Unimolecular decomposition rates of a methyl-substituted Criegee intermediate syn-CH3CHOO Y. Li et al. 10.1039/D0RA01406K
- The favorable routes for the hydrolysis of CH2OO with (H2O)n (n = 1–4) investigated by global minimum searching combined with quantum chemical methods R. Wang et al. 10.1039/D0CP00028K
- Identification of the Criegee intermediate reaction network in ethylene ozonolysis: impact on energy conversion strategies and atmospheric chemistry A. Rousso et al. 10.1039/C9CP00473D
- Formation of secondary organic aerosols from the ozonolysis of Cis-3-hexenyl acetate: The effect of acidic seed particles and SO2 D. Shi et al. 10.1016/j.atmosenv.2023.119907
- Kinetics of dimethyl sulfide (DMS) reactions with isoprene-derived Criegee intermediates studied with direct UV absorption M. Kuo et al. 10.5194/acp-20-12983-2020
- Trends in stabilisation of Criegee intermediates from alkene ozonolysis M. Newland et al. 10.1039/D0CP00897D
- Reaction Kinetics of Criegee Intermediates with Nitric Acid J. Yang et al. 10.1021/acs.jpca.2c04596
- Impacts of Mixed Gaseous and Particulate Pollutants on Secondary Particle Formation during Ozonolysis of Butyl Vinyl Ether P. Zhang et al. 10.1021/acs.est.9b07650
- Temperature‐Dependence of the Rates of Reaction of Trifluoroacetic Acid with Criegee Intermediates R. Chhantyal‐Pun et al. 10.1002/ange.201703700
- Estimating the atmospheric concentration of Criegee intermediates and their possible interference in a FAGE-LIF instrument A. Novelli et al. 10.5194/acp-17-7807-2017
- Low-Pressure and Nascent Yields of Thermalized Criegee Intermediate in Ozonolysis of Ethene L. Yang et al. 10.1021/acs.jpclett.2c02940
- Heterogeneous interactions between SO<sub>2</sub> and organic peroxides in submicron aerosol S. Wang et al. 10.5194/acp-21-6647-2021
- The reaction of Criegee intermediates with formamide and its implication to atmospheric aerosols Y. Wei et al. 10.1016/j.chemosphere.2022.133717
- Processes governing the surface ozone over a tropical hill station in the Western Ghats R. Ajayakumar et al. 10.1016/j.atmosenv.2023.120286
- Unimolecular decay strongly limits the atmospheric impact of Criegee intermediates L. Vereecken et al. 10.1039/C7CP05541B
- Insights into air pollution chemistry and sulphate formation from nitrous acid (HONO) measurements during haze events in Beijing W. Bloss et al. 10.1039/D0FD00100G
- Impact of the water dimer on the atmospheric reactivity of carbonyl oxides J. Anglada & A. Solé 10.1039/C6CP02531E
- Impacts of SO2, Relative Humidity, and Seed Acidity on Secondary Organic Aerosol Formation in the Ozonolysis of Butyl Vinyl Ether P. Zhang et al. 10.1021/acs.est.9b02702
- Evaluated kinetic and photochemical data for atmospheric chemistry: Volume VII – Criegee intermediates R. Cox et al. 10.5194/acp-20-13497-2020
- Reactions between hydroxyl-substituted alkylperoxy radicals and Criegee intermediates: correlations of the electronic characteristics of methyl substituents and the reactivity Q. Zhao et al. 10.1039/C7CP00869D
- Bimolecular sinks of Criegee intermediates derived from hydrofluoroolefins – a computational analysis N. Watson & J. Beames 10.1039/D3EA00102D
- DFT investigations on the mechanisms and kinetics for the DMS + O3 reaction S. Wang et al. 10.1002/poc.4558
- Criegee Intermediate-Mediated Oxidation of Dimethyl Disulfide: Effect of Formic Acid and Its Atmospheric Relevance G. Babu et al. 10.1021/acs.jpca.3c04730
- Ozonolysis of <i>α</i>-phellandrene – Part 2: Compositional analysis of secondary organic aerosol highlights the role of stabilised Criegee intermediates F. Mackenzie-Rae et al. 10.5194/acp-18-4673-2018
- Multiphase Mechanism for the Production of Sulfuric Acid from SO2 by Criegee Intermediates Formed During the Heterogeneous Reaction of Ozone with Squalene N. Heine et al. 10.1021/acs.jpclett.8b01171
- Effect of Carbon Chain Length on Nascent Yields of Stabilized Criegee Intermediates in Ozonolysis of a Series of Terminal Alkenes L. Yang & J. Zhang 10.1021/jacs.4c08051
- Relative Reactivity Measurements of Stabilized CH2OO, Produced by Ethene Ozonolysis, Toward Acetic Acid and Water Vapor Using Chemical Ionization Mass Spectrometry R. Yajima et al. 10.1021/acs.jpca.7b05065
- Unimolecular decomposition kinetics of the stabilised Criegee intermediates CH2OO and CD2OO D. Stone et al. 10.1039/C8CP05332D
- Online Quantification of Criegee Intermediates of α-Pinene Ozonolysis by Stabilization with Spin Traps and Proton-Transfer Reaction Mass Spectrometry Detection C. Giorio et al. 10.1021/jacs.6b10981
- Optical property variations from a precursor (isoprene) to its atmospheric oxidation products Y. Zeng et al. 10.1016/j.atmosenv.2018.09.017
- Implementation of a chemical background method for atmospheric OH measurements by laser-induced fluorescence: characterisation and observations from the UK and China R. Woodward-Massey et al. 10.5194/amt-13-3119-2020
- A novel reaction between ammonia and Criegee intermediates can form amines and suppress oligomers from isoprene X. Li et al. 10.1016/j.scitotenv.2024.177389
- Investigation of the reaction of ozone with isoprene, methacrolein and methyl vinyl ketone using the HELIOS chamber Y. Ren et al. 10.1039/C7FD00014F
57 citations as recorded by crossref.
- Electronic Absorption Spectroscopy and Photochemistry of Criegee Intermediates T. Karsili et al. 10.1111/php.13665
- The reaction of OH radical with the Criegee intermediate propanone oxide: Theoretical investigations V. Saheb & A. Nazari 10.1016/j.comptc.2020.112726
- Low molecular weight dicarboxylic acids, oxocarboxylic acids and α-dicarbonyls as ozonolysis products of isoprene: Implication for the gaseous-phase formation of secondary organic aerosols S. Bikkina et al. 10.1016/j.scitotenv.2020.144472
- Temperature‐Dependence of the Rates of Reaction of Trifluoroacetic Acid with Criegee Intermediates R. Chhantyal‐Pun et al. 10.1002/anie.201703700
- The atmospheric impacts of monoterpene ozonolysis on global stabilised Criegee intermediate budgets and SO<sub>2</sub> oxidation: experiment, theory and modelling M. Newland et al. 10.5194/acp-18-6095-2018
- How does substitution affect the unimolecular reaction rates of Criegee intermediates? C. Yin & K. Takahashi 10.1039/C7CP01091E
- Theoretical kinetics studies on the temperature and pressure dependence of the reaction of ammonia with the Criegee intermediate CH2OO A. Nazari & V. Saheb 10.1007/s00214-022-02930-5
- Atmospheric Kinetics: Bimolecular Reactions of Carbonyl Oxide by a Triple-Level Strategy B. Long et al. 10.1021/jacs.1c02029
- Toward Building a Physical Proxy for Gas-Phase Sulfuric Acid Concentration Based on Its Budget Analysis in Polluted Yangtze River Delta, East China L. Yang et al. 10.1021/acs.est.1c00738
- An Estimation of the Levels of Stabilized Criegee Intermediates in the UK Urban and Rural Atmosphere Using the Steady-State Approximation and the Potential Effects of These Intermediates on Tropospheric Oxidation Cycles M. H. Khan et al. 10.1002/kin.21101
- Gas-phase broadband spectroscopy using active sources: progress, status, and applications [Invited] K. Cossel et al. 10.1364/JOSAB.34.000104
- Surprisingly long lifetime of methacrolein oxide, an isoprene derived Criegee intermediate, under humid conditions Y. Lin et al. 10.1038/s42004-021-00451-z
- Direct kinetic measurements and theoretical predictions of an isoprene-derived Criegee intermediate R. Caravan et al. 10.1073/pnas.1916711117
- Competition between H2O and (H2O)2 reactions with CH2OO/CH3CHOO L. Lin et al. 10.1039/C5CP06446E
- Low-pressure and nascent yields of stabilized Criegee intermediates CH2OO and CH3CHOO in ozonolysis of propene L. Yang et al. 10.1039/D3CP02590J
- Emission characteristics of 99 NMVOCs in different seasonal days and the relationship with air quality parameters in Beijing, China Y. Gu et al. 10.1016/j.ecoenv.2018.11.091
- Quantification of Gas-to-Particle Conversion Rates of Sulfur in the Terrestrial Atmosphere Using High-Sensitivity Measurements of Cosmogenic 35S M. Lin et al. 10.1021/acsearthspacechem.7b00047
- Molecular response of poplar to single and combined ozone and drought J. Zhang et al. 10.1016/j.scitotenv.2018.11.195
- Increased primary and secondary H<sub>2</sub>SO<sub>4</sub> showing the opposing roles in secondary organic aerosol formation from ethyl methacrylate ozonolysis P. Zhang et al. 10.5194/acp-21-7099-2021
- Oligomerization reactions for precursors to secondary organic aerosol: Comparison between two formation mechanisms for the oligomeric hydroxyalkyl hydroperoxides Q. Zhao et al. 10.1016/j.atmosenv.2017.07.008
- Investigation of potential interferences in the detection of atmospheric RO<sub><i>x</i></sub> radicals by laser-induced fluorescence under dark conditions H. Fuchs et al. 10.5194/amt-9-1431-2016
- Formation of secondary organic aerosols from the ozonolysis of dihydrofurans Y. Diaz-de-Mera et al. 10.5194/acp-17-2347-2017
- Criegee intermediates and their impacts on the troposphere M. Khan et al. 10.1039/C7EM00585G
- Formation of nighttime sulfuric acid from the ozonolysis of alkenes in Beijing Y. Guo et al. 10.5194/acp-21-5499-2021
- Water vapour effects on secondary organic aerosol formation in isoprene ozonolysis Y. Sakamoto et al. 10.1039/C6CP04521A
- Unimolecular decomposition rates of a methyl-substituted Criegee intermediate syn-CH3CHOO Y. Li et al. 10.1039/D0RA01406K
- The favorable routes for the hydrolysis of CH2OO with (H2O)n (n = 1–4) investigated by global minimum searching combined with quantum chemical methods R. Wang et al. 10.1039/D0CP00028K
- Identification of the Criegee intermediate reaction network in ethylene ozonolysis: impact on energy conversion strategies and atmospheric chemistry A. Rousso et al. 10.1039/C9CP00473D
- Formation of secondary organic aerosols from the ozonolysis of Cis-3-hexenyl acetate: The effect of acidic seed particles and SO2 D. Shi et al. 10.1016/j.atmosenv.2023.119907
- Kinetics of dimethyl sulfide (DMS) reactions with isoprene-derived Criegee intermediates studied with direct UV absorption M. Kuo et al. 10.5194/acp-20-12983-2020
- Trends in stabilisation of Criegee intermediates from alkene ozonolysis M. Newland et al. 10.1039/D0CP00897D
- Reaction Kinetics of Criegee Intermediates with Nitric Acid J. Yang et al. 10.1021/acs.jpca.2c04596
- Impacts of Mixed Gaseous and Particulate Pollutants on Secondary Particle Formation during Ozonolysis of Butyl Vinyl Ether P. Zhang et al. 10.1021/acs.est.9b07650
- Temperature‐Dependence of the Rates of Reaction of Trifluoroacetic Acid with Criegee Intermediates R. Chhantyal‐Pun et al. 10.1002/ange.201703700
- Estimating the atmospheric concentration of Criegee intermediates and their possible interference in a FAGE-LIF instrument A. Novelli et al. 10.5194/acp-17-7807-2017
- Low-Pressure and Nascent Yields of Thermalized Criegee Intermediate in Ozonolysis of Ethene L. Yang et al. 10.1021/acs.jpclett.2c02940
- Heterogeneous interactions between SO<sub>2</sub> and organic peroxides in submicron aerosol S. Wang et al. 10.5194/acp-21-6647-2021
- The reaction of Criegee intermediates with formamide and its implication to atmospheric aerosols Y. Wei et al. 10.1016/j.chemosphere.2022.133717
- Processes governing the surface ozone over a tropical hill station in the Western Ghats R. Ajayakumar et al. 10.1016/j.atmosenv.2023.120286
- Unimolecular decay strongly limits the atmospheric impact of Criegee intermediates L. Vereecken et al. 10.1039/C7CP05541B
- Insights into air pollution chemistry and sulphate formation from nitrous acid (HONO) measurements during haze events in Beijing W. Bloss et al. 10.1039/D0FD00100G
- Impact of the water dimer on the atmospheric reactivity of carbonyl oxides J. Anglada & A. Solé 10.1039/C6CP02531E
- Impacts of SO2, Relative Humidity, and Seed Acidity on Secondary Organic Aerosol Formation in the Ozonolysis of Butyl Vinyl Ether P. Zhang et al. 10.1021/acs.est.9b02702
- Evaluated kinetic and photochemical data for atmospheric chemistry: Volume VII – Criegee intermediates R. Cox et al. 10.5194/acp-20-13497-2020
- Reactions between hydroxyl-substituted alkylperoxy radicals and Criegee intermediates: correlations of the electronic characteristics of methyl substituents and the reactivity Q. Zhao et al. 10.1039/C7CP00869D
- Bimolecular sinks of Criegee intermediates derived from hydrofluoroolefins – a computational analysis N. Watson & J. Beames 10.1039/D3EA00102D
- DFT investigations on the mechanisms and kinetics for the DMS + O3 reaction S. Wang et al. 10.1002/poc.4558
- Criegee Intermediate-Mediated Oxidation of Dimethyl Disulfide: Effect of Formic Acid and Its Atmospheric Relevance G. Babu et al. 10.1021/acs.jpca.3c04730
- Ozonolysis of <i>α</i>-phellandrene – Part 2: Compositional analysis of secondary organic aerosol highlights the role of stabilised Criegee intermediates F. Mackenzie-Rae et al. 10.5194/acp-18-4673-2018
- Multiphase Mechanism for the Production of Sulfuric Acid from SO2 by Criegee Intermediates Formed During the Heterogeneous Reaction of Ozone with Squalene N. Heine et al. 10.1021/acs.jpclett.8b01171
- Effect of Carbon Chain Length on Nascent Yields of Stabilized Criegee Intermediates in Ozonolysis of a Series of Terminal Alkenes L. Yang & J. Zhang 10.1021/jacs.4c08051
- Relative Reactivity Measurements of Stabilized CH2OO, Produced by Ethene Ozonolysis, Toward Acetic Acid and Water Vapor Using Chemical Ionization Mass Spectrometry R. Yajima et al. 10.1021/acs.jpca.7b05065
- Unimolecular decomposition kinetics of the stabilised Criegee intermediates CH2OO and CD2OO D. Stone et al. 10.1039/C8CP05332D
- Online Quantification of Criegee Intermediates of α-Pinene Ozonolysis by Stabilization with Spin Traps and Proton-Transfer Reaction Mass Spectrometry Detection C. Giorio et al. 10.1021/jacs.6b10981
- Optical property variations from a precursor (isoprene) to its atmospheric oxidation products Y. Zeng et al. 10.1016/j.atmosenv.2018.09.017
- Implementation of a chemical background method for atmospheric OH measurements by laser-induced fluorescence: characterisation and observations from the UK and China R. Woodward-Massey et al. 10.5194/amt-13-3119-2020
- A novel reaction between ammonia and Criegee intermediates can form amines and suppress oligomers from isoprene X. Li et al. 10.1016/j.scitotenv.2024.177389
1 citations as recorded by crossref.
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Short summary
Stabilised Criegee intermediates (SCIs) are formed through alkene-ozone reactions, which occur throughout the atmospheric boundary layer. Recent direct laboratory studies have shown that SCI react rapidly with SO2, NO2 and other trace gases, affecting air quality and climate. We present experimental data from the EUPHORE atmospheric simulation chamber, in which we determine the effects of the ozonolysis of isoprene, on the oxidation of SO2 as a function of H2O and dimethyl sulfide concentration.
Stabilised Criegee intermediates (SCIs) are formed through alkene-ozone reactions, which occur...
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