Articles | Volume 15, issue 16
https://doi.org/10.5194/acp-15-9435-2015
© Author(s) 2015. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/acp-15-9435-2015
© Author(s) 2015. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Research article
| 
24 Aug 2015
Research article |
| 24 Aug 2015
Investigation of post-depositional processing of nitrate in East Antarctic snow: isotopic constraints on photolytic loss, re-oxidation, and source inputs
Key Laboratory for Polar Science of State Oceanic Administration, Polar Research Institute of China, Shanghai 200062, China
Department of Earth, Environmental and Planetary Sciences and Institute at Brown for Environment and Society, Brown University, Providence, Rhode Island 02912, USA
A. M. Buffen
Department of Earth, Environmental and Planetary Sciences and Institute at Brown for Environment and Society, Brown University, Providence, Rhode Island 02912, USA
M. G. Hastings
CORRESPONDING AUTHOR
Department of Earth, Environmental and Planetary Sciences and Institute at Brown for Environment and Society, Brown University, Providence, Rhode Island 02912, USA
C. Li
The State Key Laboratory of the Cryospheric Sciences, Cold and Arid Regions Environmental and Engineering Research Institute, Chinese Academy of Sciences, Lanzhou 730000, China
H. Ma
Key Laboratory for Polar Science of State Oceanic Administration, Polar Research Institute of China, Shanghai 200062, China
Y. Li
Key Laboratory for Polar Science of State Oceanic Administration, Polar Research Institute of China, Shanghai 200062, China
B. Sun
Key Laboratory for Polar Science of State Oceanic Administration, Polar Research Institute of China, Shanghai 200062, China
C. An
Key Laboratory for Polar Science of State Oceanic Administration, Polar Research Institute of China, Shanghai 200062, China
S. Jiang
Key Laboratory for Polar Science of State Oceanic Administration, Polar Research Institute of China, Shanghai 200062, China
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Cited
40 citations as recorded by crossref.
- Spatial variation of isotopic compositions of snowpack nitrate related to post-depositional processes in eastern Dronning Maud Land, East Antarctica K. Noro et al. 10.2343/geochemj.2.0519
- Potential genesis and implications of calcium nitrate in Antarctic snow K. Mahalinganathan & M. Thamban 10.5194/tc-10-825-2016
- Isotope Fractionation of Nitrate During Volatilization in Snow: A Field Investigation in Antarctica G. Shi et al. 10.1029/2019GL081968
- The importance of alkyl nitrates and sea ice emissions to atmospheric NOx sources and cycling in the summertime Southern Ocean marine boundary layer J. Burger et al. 10.5194/acp-22-1081-2022
- Pollution drives multidecadal decline in subarctic methanesulfonic acid J. Chalif et al. 10.1038/s41561-024-01543-w
- Stable isotopic composition in snowpack along the traverse from a coastal location to Dome A (East Antarctica): Results from observations and numerical modeling T. Ma et al. 10.1016/j.polar.2020.100510
- Developments in the investigation of nitrogen and oxygen stable isotopes in atmospheric nitrate S. Saud et al. 10.1016/j.scca.2022.100003
- Treated wastewater and weak removal mechanisms enhance nitrate pollution in metropolitan rivers G. Zhao et al. 10.1016/j.envres.2023.116182
- Using stable isotopes to distinguish atmospheric nitrate production and its contribution to the surface ocean across hemispheres G. Shi et al. 10.1016/j.epsl.2021.116914
- Impacts of post-depositional processing on nitrate isotopes in the snow and the overlying atmosphere at Summit, Greenland Z. Jiang et al. 10.5194/tc-16-2709-2022
- Modeling the Complete Nitrogen and Oxygen Isotopic Imprint of Nitrate Photolysis in Snow G. Shi et al. 10.1029/2023GL103778
- Analysis of nitrate in the snow and atmosphere at Summit, Greenland: Chemistry and transport D. Fibiger et al. 10.1002/2015JD024187
- Nitrate photolysis in ice and snow: A critical review of its multiphase chemistry C. Blaszczak-Boxe & A. Saiz-Lopez 10.1016/j.atmosenv.2018.09.002
- Photolytic modification of seasonal nitrate isotope cycles in East Antarctica P. Akers et al. 10.5194/acp-22-15637-2022
- Impacts of the photo-driven post-depositional processing on snow nitrate and its isotopes at Summit, Greenland: a model-based study Z. Jiang et al. 10.5194/tc-15-4207-2021
- Isotopic constraints on sources, production, and phase partitioning for nitrate in the atmosphere and snowfall in coastal East Antarctica G. Shi et al. 10.1016/j.epsl.2021.117300
- An Investigation Into the Origin of Nitrate in Arctic Sea Ice S. Clark et al. 10.1029/2019GB006279
- The impact of snow nitrate photolysis on boundary layer chemistry and the recycling and redistribution of reactive nitrogen across Antarctica and Greenland in a global chemical transport model M. Zatko et al. 10.5194/acp-16-2819-2016
- Nitrate preservation in snow at Dome A, East Antarctica from ice core concentration and isotope records S. Jiang et al. 10.1016/j.atmosenv.2019.06.031
- An inverse model to correct for the effects of post-depositional processing on ice-core nitrate and its isotopes: model framework and applications at Summit, Greenland, and Dome C, Antarctica Z. Jiang et al. 10.5194/acp-24-4895-2024
- Deposition, recycling, and archival of nitrate stable isotopes between the air–snow interface: comparison between Dronning Maud Land and Dome C, Antarctica V. Winton et al. 10.5194/acp-20-5861-2020
- Nitrate Photochemistry at the Air–Ice Interface and in Other Ice Reservoirs A. McFall et al. 10.1021/acs.est.8b00095
- Air-snow exchange of reactive nitrogen species at Ny-Ålesund, Svalbard (Arctic) A. Ianniello et al. 10.1007/s12210-016-0536-4
- Isotopic evidence that recent agriculture overprints climate variability in nitrogen deposition to the Tibetan Plateau Z. Li et al. 10.1016/j.envint.2020.105614
- Snow Nitrate Isotopes in Central Antarctica Record the Prolonged Period of Stratospheric Ozone Depletion From ∼1960 to 2000 G. Shi et al. 10.1029/2022GL098986
- Triple oxygen isotopic evidence for atmospheric nitrate and its application in source identification for river systems in the Qinghai-Tibetan Plateau X. Xia et al. 10.1016/j.scitotenv.2019.06.204
- Latitudinal difference in sulfate formation from methanesulfonate oxidation in Antarctic snow imprinted on 17O-excess signature S. Hattori et al. 10.1016/j.apgeochem.2024.105901
- Unveiling unique microbial nitrogen cycling and nitrification driver in coastal Antarctica P. Han et al. 10.1038/s41467-024-47392-4
- Nitrate deposition and preservation in the snowpack along a traverse from coast to the ice sheet summit (Dome A) in East Antarctica G. Shi et al. 10.5194/tc-12-1177-2018
- Role of mineral dust in the nitrate preservation during the glacial period: Insights from the RICE ice core A. Venugopal et al. 10.1016/j.gloplacha.2022.103745
- Distinguishing summertime atmospheric production of nitrate across the East Antarctic Ice Sheet G. Shi et al. 10.1016/j.gca.2018.03.025
- Quantum Yield of Nitrite from the Photolysis of Aqueous Nitrate above 300 nm K. Benedict et al. 10.1021/acs.est.6b06370
- Spatial variations in snowpack chemistry, isotopic composition of NO3− and nitrogen deposition from the ice sheet margin to the coast of western Greenland C. Curtis et al. 10.5194/bg-15-529-2018
- Organic tracers from biomass burning in snow from the coast to the ice sheet summit of East Antarctica G. Shi et al. 10.1016/j.atmosenv.2018.12.058
- Brief communication: Spatial and temporal variations in surface snow chemistry along a traverse from coastal East Antarctica to the ice sheet summit (Dome A) G. Shi et al. 10.5194/tc-15-1087-2021
- Atmospheric nitrate export in streams along a montane to urban gradient I. Bourgeois et al. 10.1016/j.scitotenv.2018.03.141
- Nitrogen atmospheric deposition in a high-altitude Alpine environment: A chemical and isotopic approach to investigate the influence from anthropized areas R. Balestrini et al. 10.1016/j.atmosenv.2024.120513
- Sunlight-driven nitrate loss records Antarctic surface mass balance P. Akers et al. 10.1038/s41467-022-31855-7
- Monsoon Fringe Area Moisture Transportation Revealed by Water Stable Isotopes: A Lanzhou River Valley Case Study J. Du et al. 10.3389/fenvs.2022.843948
- The impact of snow nitrate photolysis on boundary layer chemistry and the recycling and redistribution of reactive nitrogen across Antarctica in a global chemical transport model M. Zatko et al. 10.5194/acpd-15-18963-2015
39 citations as recorded by crossref.
- Spatial variation of isotopic compositions of snowpack nitrate related to post-depositional processes in eastern Dronning Maud Land, East Antarctica K. Noro et al. 10.2343/geochemj.2.0519
- Potential genesis and implications of calcium nitrate in Antarctic snow K. Mahalinganathan & M. Thamban 10.5194/tc-10-825-2016
- Isotope Fractionation of Nitrate During Volatilization in Snow: A Field Investigation in Antarctica G. Shi et al. 10.1029/2019GL081968
- The importance of alkyl nitrates and sea ice emissions to atmospheric NOx sources and cycling in the summertime Southern Ocean marine boundary layer J. Burger et al. 10.5194/acp-22-1081-2022
- Pollution drives multidecadal decline in subarctic methanesulfonic acid J. Chalif et al. 10.1038/s41561-024-01543-w
- Stable isotopic composition in snowpack along the traverse from a coastal location to Dome A (East Antarctica): Results from observations and numerical modeling T. Ma et al. 10.1016/j.polar.2020.100510
- Developments in the investigation of nitrogen and oxygen stable isotopes in atmospheric nitrate S. Saud et al. 10.1016/j.scca.2022.100003
- Treated wastewater and weak removal mechanisms enhance nitrate pollution in metropolitan rivers G. Zhao et al. 10.1016/j.envres.2023.116182
- Using stable isotopes to distinguish atmospheric nitrate production and its contribution to the surface ocean across hemispheres G. Shi et al. 10.1016/j.epsl.2021.116914
- Impacts of post-depositional processing on nitrate isotopes in the snow and the overlying atmosphere at Summit, Greenland Z. Jiang et al. 10.5194/tc-16-2709-2022
- Modeling the Complete Nitrogen and Oxygen Isotopic Imprint of Nitrate Photolysis in Snow G. Shi et al. 10.1029/2023GL103778
- Analysis of nitrate in the snow and atmosphere at Summit, Greenland: Chemistry and transport D. Fibiger et al. 10.1002/2015JD024187
- Nitrate photolysis in ice and snow: A critical review of its multiphase chemistry C. Blaszczak-Boxe & A. Saiz-Lopez 10.1016/j.atmosenv.2018.09.002
- Photolytic modification of seasonal nitrate isotope cycles in East Antarctica P. Akers et al. 10.5194/acp-22-15637-2022
- Impacts of the photo-driven post-depositional processing on snow nitrate and its isotopes at Summit, Greenland: a model-based study Z. Jiang et al. 10.5194/tc-15-4207-2021
- Isotopic constraints on sources, production, and phase partitioning for nitrate in the atmosphere and snowfall in coastal East Antarctica G. Shi et al. 10.1016/j.epsl.2021.117300
- An Investigation Into the Origin of Nitrate in Arctic Sea Ice S. Clark et al. 10.1029/2019GB006279
- The impact of snow nitrate photolysis on boundary layer chemistry and the recycling and redistribution of reactive nitrogen across Antarctica and Greenland in a global chemical transport model M. Zatko et al. 10.5194/acp-16-2819-2016
- Nitrate preservation in snow at Dome A, East Antarctica from ice core concentration and isotope records S. Jiang et al. 10.1016/j.atmosenv.2019.06.031
- An inverse model to correct for the effects of post-depositional processing on ice-core nitrate and its isotopes: model framework and applications at Summit, Greenland, and Dome C, Antarctica Z. Jiang et al. 10.5194/acp-24-4895-2024
- Deposition, recycling, and archival of nitrate stable isotopes between the air–snow interface: comparison between Dronning Maud Land and Dome C, Antarctica V. Winton et al. 10.5194/acp-20-5861-2020
- Nitrate Photochemistry at the Air–Ice Interface and in Other Ice Reservoirs A. McFall et al. 10.1021/acs.est.8b00095
- Air-snow exchange of reactive nitrogen species at Ny-Ålesund, Svalbard (Arctic) A. Ianniello et al. 10.1007/s12210-016-0536-4
- Isotopic evidence that recent agriculture overprints climate variability in nitrogen deposition to the Tibetan Plateau Z. Li et al. 10.1016/j.envint.2020.105614
- Snow Nitrate Isotopes in Central Antarctica Record the Prolonged Period of Stratospheric Ozone Depletion From ∼1960 to 2000 G. Shi et al. 10.1029/2022GL098986
- Triple oxygen isotopic evidence for atmospheric nitrate and its application in source identification for river systems in the Qinghai-Tibetan Plateau X. Xia et al. 10.1016/j.scitotenv.2019.06.204
- Latitudinal difference in sulfate formation from methanesulfonate oxidation in Antarctic snow imprinted on 17O-excess signature S. Hattori et al. 10.1016/j.apgeochem.2024.105901
- Unveiling unique microbial nitrogen cycling and nitrification driver in coastal Antarctica P. Han et al. 10.1038/s41467-024-47392-4
- Nitrate deposition and preservation in the snowpack along a traverse from coast to the ice sheet summit (Dome A) in East Antarctica G. Shi et al. 10.5194/tc-12-1177-2018
- Role of mineral dust in the nitrate preservation during the glacial period: Insights from the RICE ice core A. Venugopal et al. 10.1016/j.gloplacha.2022.103745
- Distinguishing summertime atmospheric production of nitrate across the East Antarctic Ice Sheet G. Shi et al. 10.1016/j.gca.2018.03.025
- Quantum Yield of Nitrite from the Photolysis of Aqueous Nitrate above 300 nm K. Benedict et al. 10.1021/acs.est.6b06370
- Spatial variations in snowpack chemistry, isotopic composition of NO3− and nitrogen deposition from the ice sheet margin to the coast of western Greenland C. Curtis et al. 10.5194/bg-15-529-2018
- Organic tracers from biomass burning in snow from the coast to the ice sheet summit of East Antarctica G. Shi et al. 10.1016/j.atmosenv.2018.12.058
- Brief communication: Spatial and temporal variations in surface snow chemistry along a traverse from coastal East Antarctica to the ice sheet summit (Dome A) G. Shi et al. 10.5194/tc-15-1087-2021
- Atmospheric nitrate export in streams along a montane to urban gradient I. Bourgeois et al. 10.1016/j.scitotenv.2018.03.141
- Nitrogen atmospheric deposition in a high-altitude Alpine environment: A chemical and isotopic approach to investigate the influence from anthropized areas R. Balestrini et al. 10.1016/j.atmosenv.2024.120513
- Sunlight-driven nitrate loss records Antarctic surface mass balance P. Akers et al. 10.1038/s41467-022-31855-7
- Monsoon Fringe Area Moisture Transportation Revealed by Water Stable Isotopes: A Lanzhou River Valley Case Study J. Du et al. 10.3389/fenvs.2022.843948
Saved (final revised paper)
Latest update: 02 Apr 2025
Short summary
We evaluate isotopic composition of NO3- in different environments across East Antarctica. At high snow accumulation sites, isotopic ratios are suggestive of preservation of NO3- deposition. At low accumulation sites, isotopes are sensitive to both the loss of NO3- due to photolysis and secondary formation of NO3- within the snow. The imprint of post-depositional alteration is not uniform with depth, making it difficult to predict the isotopic composition at depth from near-surface data alone.
We evaluate isotopic composition of NO3- in different environments across East Antarctica. At...
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