Articles | Volume 15, issue 16
https://doi.org/10.5194/acp-15-9381-2015
© Author(s) 2015. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/acp-15-9381-2015
© Author(s) 2015. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Research article
| 
21 Aug 2015
Research article |
| 21 Aug 2015
Impacts of an unknown daytime HONO source on the mixing ratio and budget of HONO, and hydroxyl, hydroperoxyl, and organic peroxy radicals, in the coastal regions of China
Y. Tang
University of the Chinese Academy of Sciences, Beijing 100049, China
State Key Laboratory of Atmospheric Boundary Layer Physics and Atmospheric Chemistry (LAPC), Institute of Atmospheric Physics (IAP), Chinese Academy of Sciences, Beijing 100029, China
State Key Laboratory of Atmospheric Boundary Layer Physics and Atmospheric Chemistry (LAPC), Institute of Atmospheric Physics (IAP), Chinese Academy of Sciences, Beijing 100029, China
F. Wang
University of the Chinese Academy of Sciences, Beijing 100049, China
State Key Laboratory of Atmospheric Boundary Layer Physics and Atmospheric Chemistry (LAPC), Institute of Atmospheric Physics (IAP), Chinese Academy of Sciences, Beijing 100029, China
Anhui Meteorological Bureau, Hefei 230061, China
State Key Laboratory of Atmospheric Boundary Layer Physics and Atmospheric Chemistry (LAPC), Institute of Atmospheric Physics (IAP), Chinese Academy of Sciences, Beijing 100029, China
Y. Qu
State Key Laboratory of Atmospheric Boundary Layer Physics and Atmospheric Chemistry (LAPC), Institute of Atmospheric Physics (IAP), Chinese Academy of Sciences, Beijing 100029, China
Y. Chen
State Key Laboratory of Atmospheric Boundary Layer Physics and Atmospheric Chemistry (LAPC), Institute of Atmospheric Physics (IAP), Chinese Academy of Sciences, Beijing 100029, China
J. Lin
University of the Chinese Academy of Sciences, Beijing 100049, China
State Key Laboratory of Atmospheric Boundary Layer Physics and Atmospheric Chemistry (LAPC), Institute of Atmospheric Physics (IAP), Chinese Academy of Sciences, Beijing 100029, China
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- Characterization of fungal communities in aerosols: Coastal waters vs. open oceans Z. Teng et al. 10.1016/j.gloplacha.2023.104311
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- A systematic review of reactive nitrogen simulations with chemical transport models in China H. Zhang et al. 10.1016/j.atmosres.2024.107586
- Photoenhanced Uptake of NO2 and HONO Formation on Real Urban Grime J. Liu et al. 10.1021/acs.estlett.9b00308
- Effect of vertical parameterization of a missing daytime source of HONO on concentrations of HONO, O3 and secondary organic aerosols in eastern China Y. Guo et al. 10.1016/j.atmosenv.2019.117208
- Per- and polyfluoroalkyl substances (PFASs) in precipitation from mainland China: Contributions of unknown precursors and short-chain (C2 C3) perfluoroalkyl carboxylic acids H. Chen et al. 10.1016/j.watres.2019.01.019
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- Role of Nitrogen Dioxide in the Production of Sulfate during Chinese Haze-Aerosol Episodes L. Li et al. 10.1021/acs.est.7b05222
- Development of a laser-photofragmentation laser-induced fluorescence instrument for the detection of nitrous acid and hydroxyl radicals in the atmosphere B. Bottorff et al. 10.5194/amt-14-6039-2021
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- Amplified role of potential HONO sources in O3 formation in North China Plain during autumn haze aggravating processes J. Zhang et al. 10.5194/acp-22-3275-2022
- Photoenhanced Heterogeneous Uptake of NO2 and HONO Formation on Authentic Winter Time Urban Grime C. Yu et al. 10.1021/acsearthspacechem.2c00054
- Barrierless Reactions with Loose Transition States Govern the Yields and Lifetimes of Organic Nitrates Derived from Isoprene I. Piletic et al. 10.1021/acs.jpca.7b08229
- Influence of Chinese New Year overlapping COVID-19 lockdown on HONO sources in Shijiazhuang Y. Liu et al. 10.1016/j.scitotenv.2020.141025
- Explicit diagnosis of the local ozone production rate and the ozone-NOx-VOC sensitivities Z. Tan et al. 10.1016/j.scib.2018.07.001
- In situ monitoring of atmospheric nitrous acid based on multi-pumping flow system and liquid waveguide capillary cell Y. Liu et al. 10.1016/j.jes.2015.11.034
- Implementation and refinement of a surface model for heterogeneous HONO formation in a 3-D chemical transport model P. Karamchandani et al. 10.1016/j.atmosenv.2015.01.046
- A Comprehensive Model Test of the HONO Sources Constrained to Field Measurements at Rural North China Plain Y. Liu et al. 10.1021/acs.est.8b06367
- Nitrous acid emission from open burning of major crop residues in mainland China L. Cui et al. 10.1016/j.atmosenv.2020.117950
48 citations as recorded by crossref.
- Nitrous acid in marine boundary layer over eastern Bohai Sea, China: Characteristics, sources, and implications L. Wen et al. 10.1016/j.scitotenv.2019.03.225
- Measurement report: Surface exchange fluxes of HONO during the growth process of paddy fields in the Huaihe River Basin, China F. Meng et al. 10.5194/acp-24-14191-2024
- Impacts of potential HONO sources on the concentrations of oxidants and secondary organic aerosols in the Beijing-Tianjin-Hebei region of China J. Zhang et al. 10.1016/j.scitotenv.2018.08.030
- Pollution characteristics and potential sources of nitrous acid (HONO) in early autumn 2018 of Beijing C. Jia et al. 10.1016/j.scitotenv.2020.139317
- Unveiling the effect of O2 on the photochemical reaction of NO2 with polycyclic aromatic hydrocarbons W. Yang et al. 10.1007/s11356-023-30289-y
- Updated emission inventories of power plants in simulating air quality during haze periods over East China L. Zhang et al. 10.5194/acp-18-2065-2018
- Double High-Level Ozone and PM2.5 Co-Pollution Episodes in Shanghai, China: Pollution Characteristics and Significant Role of Daytime HONO K. Yang et al. 10.3390/atmos12050557
- Direct Observation of HONO Emissions from Real-World Residential Natural Gas Heating in China X. Ding et al. 10.1021/acs.est.2c09386
- Impact of soil–atmosphere HONO exchange on concentrations of HONO and O3 in the North China Plain H. Ran et al. 10.1016/j.scitotenv.2024.172336
- Rapid and high-precision cavity-enhanced spectroscopic measurement of HONO and NO2: Application to emissions from heavy-duty diesel vehicles in chassis dynamometer tests and in mobile monitoring M. Wang et al. 10.1016/j.talanta.2024.127386
- Elucidating the effect of HONO on O3 pollution by a case study in southwest China Y. Yang et al. 10.1016/j.scitotenv.2020.144127
- High-resolution vertical distribution and sources of HONO and NO2 in the nocturnal boundary layer in urban Beijing, China F. Meng et al. 10.5194/acp-20-5071-2020
- The promotion effect of nitrous acid on aerosol formation in wintertime in Beijing: the possible contribution of traffic-related emissions Y. Liu et al. 10.5194/acp-20-13023-2020
- Ozone pollution in China: A review of concentrations, meteorological influences, chemical precursors, and effects T. Wang et al. 10.1016/j.scitotenv.2016.10.081
- Quantum Yield of Nitrite from the Photolysis of Aqueous Nitrate above 300 nm K. Benedict et al. 10.1021/acs.est.6b06370
- Persistent Heavy Winter Nitrate Pollution Driven by Increased Photochemical Oxidants in Northern China X. Fu et al. 10.1021/acs.est.9b07248
- A review of measurements and model simulations of atmospheric nitrous acid L. Wang et al. 10.1016/j.atmosenv.2025.121094
- Emission of nitrous acid from soil and biological soil crusts represents an important source of HONO in the remote atmosphere in Cyprus H. Meusel et al. 10.5194/acp-18-799-2018
- Measurement of heterogeneous uptake of NO2 on inorganic particles, sea water and urban grime C. Yu et al. 10.1016/j.jes.2021.01.018
- Seasonal effects of additional HONO sources and the heterogeneous reactions of N2O5 on nitrate in the North China Plain Y. Qu et al. 10.1016/j.scitotenv.2019.06.436
- Light-Enhanced Heterogeneous Conversion of NO2 to HONO on Solid Films Consisting of Fluorene and Fluorene/Na2SO4: An Impact on Urban and Indoor Atmosphere J. Liu et al. 10.1021/acs.est.0c02627
- Abundant NH3 in China Enhances Atmospheric HONO Production by Promoting the Heterogeneous Reaction of SO2 with NO2 S. Ge et al. 10.1021/acs.est.9b04196
- Observation-Based Diagnostics of Reactive Nitrogen Recycling through HONO Heterogenous Production: Divergent Implications for Ozone Production and Emission Control K. Chong et al. 10.1021/acs.est.3c07967
- Effect of potential HONO sources on peroxyacetyl nitrate (PAN) formation in eastern China in winter J. Zhang et al. 10.1016/j.jes.2020.03.039
- Nitrous acid budgets in the coastal atmosphere: potential daytime marine sources X. Zhong et al. 10.5194/acp-23-14761-2023
- Contribution of nitrous acid to the atmospheric oxidation capacity in an industrial zone in the Yangtze River Delta region of China J. Zheng et al. 10.5194/acp-20-5457-2020
- Influence of ship direct emission on HONO sources in channel environment Y. Guo et al. 10.1016/j.atmosenv.2020.117819
- Air quality and health benefits from ultra-low emission control policy indicated by continuous emission monitoring: a case study in the Yangtze River Delta region, China Y. Zhang et al. 10.5194/acp-21-6411-2021
- Explainable Machine Learning Reveals the Unknown Sources of Atmospheric HONO during COVID-19 Z. Gao et al. 10.1021/acsestair.4c00087
- Characterization of fungal communities in aerosols: Coastal waters vs. open oceans Z. Teng et al. 10.1016/j.gloplacha.2023.104311
- Different HONO Sources for Three Layers at the Urban Area of Beijing W. Zhang et al. 10.1021/acs.est.0c02146
- Characterization and source analysis of water-soluble inorganic ionic species in PM2.5 during a wintertime particle pollution episode in Nanjing, China Y. Zhan et al. 10.1016/j.atmosres.2021.105769
- A systematic review of reactive nitrogen simulations with chemical transport models in China H. Zhang et al. 10.1016/j.atmosres.2024.107586
- Photoenhanced Uptake of NO2 and HONO Formation on Real Urban Grime J. Liu et al. 10.1021/acs.estlett.9b00308
- Effect of vertical parameterization of a missing daytime source of HONO on concentrations of HONO, O3 and secondary organic aerosols in eastern China Y. Guo et al. 10.1016/j.atmosenv.2019.117208
- Per- and polyfluoroalkyl substances (PFASs) in precipitation from mainland China: Contributions of unknown precursors and short-chain (C2 C3) perfluoroalkyl carboxylic acids H. Chen et al. 10.1016/j.watres.2019.01.019
- Daytime formation of nitrous acid at a coastal remote site in Cyprus indicating a common ground source of atmospheric HONO and NO H. Meusel et al. 10.5194/acp-16-14475-2016
- Impacts of chlorine emissions on secondary pollutants in China Y. Zhang et al. 10.1016/j.atmosenv.2020.118177
- Role of Nitrogen Dioxide in the Production of Sulfate during Chinese Haze-Aerosol Episodes L. Li et al. 10.1021/acs.est.7b05222
- Development of a laser-photofragmentation laser-induced fluorescence instrument for the detection of nitrous acid and hydroxyl radicals in the atmosphere B. Bottorff et al. 10.5194/amt-14-6039-2021
- Measurement of HONO flux using the aerodynamic gradient method over an agricultural field in the Huaihe River Basin, China F. Meng et al. 10.1016/j.jes.2021.09.005
- HONO chemistry affected by relative humidity and ammonia in the North China Plain during winter H. Ran et al. 10.1016/j.atmosenv.2025.121114
- Combined impacts of nitrous acid and nitryl chloride on lower-tropospheric ozone: new module development in WRF-Chem and application to China L. Zhang et al. 10.5194/acp-17-9733-2017
- Amplified role of potential HONO sources in O3 formation in North China Plain during autumn haze aggravating processes J. Zhang et al. 10.5194/acp-22-3275-2022
- Photoenhanced Heterogeneous Uptake of NO2 and HONO Formation on Authentic Winter Time Urban Grime C. Yu et al. 10.1021/acsearthspacechem.2c00054
- Barrierless Reactions with Loose Transition States Govern the Yields and Lifetimes of Organic Nitrates Derived from Isoprene I. Piletic et al. 10.1021/acs.jpca.7b08229
- Influence of Chinese New Year overlapping COVID-19 lockdown on HONO sources in Shijiazhuang Y. Liu et al. 10.1016/j.scitotenv.2020.141025
- Explicit diagnosis of the local ozone production rate and the ozone-NOx-VOC sensitivities Z. Tan et al. 10.1016/j.scib.2018.07.001
4 citations as recorded by crossref.
- In situ monitoring of atmospheric nitrous acid based on multi-pumping flow system and liquid waveguide capillary cell Y. Liu et al. 10.1016/j.jes.2015.11.034
- Implementation and refinement of a surface model for heterogeneous HONO formation in a 3-D chemical transport model P. Karamchandani et al. 10.1016/j.atmosenv.2015.01.046
- A Comprehensive Model Test of the HONO Sources Constrained to Field Measurements at Rural North China Plain Y. Liu et al. 10.1021/acs.est.8b06367
- Nitrous acid emission from open burning of major crop residues in mainland China L. Cui et al. 10.1016/j.atmosenv.2020.117950
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Latest update: 24 Apr 2025
Short summary
High daytime HONO mixing ratios in experiments suggest that an unknown daytime HONO source (P unknown) could exist. P unknown≈19.60×NO2×J(NO2) was obtained using observed data from 13 field experiments across the globe, then coupled into the WRF-Chem model. Simulations indicated that elevated P unknown was found in the coastal regions of China; the additional HONO sources, especially the P unknown produced significant increases of radicals in the major cities, and accelerated the radical cycles.
High daytime HONO mixing ratios in experiments suggest that an unknown daytime HONO source (P...
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