Articles | Volume 15, issue 16
https://doi.org/10.5194/acp-15-9253-2015
© Author(s) 2015. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/acp-15-9253-2015
© Author(s) 2015. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Organic photolysis reactions in tropospheric aerosols: effect on secondary organic aerosol formation and lifetime
A. Hodzic
CORRESPONDING AUTHOR
National Center for Atmospheric Research, Boulder, CO, USA
S. Madronich
National Center for Atmospheric Research, Boulder, CO, USA
P. S. Kasibhatla
Nicholas School of the Environment, Duke University, Durham, NC, USA
G. Tyndall
National Center for Atmospheric Research, Boulder, CO, USA
B. Aumont
LISA UMR CNRS 7583, Université Paris Est Créteil et Université Paris Diderot, Paris, France
J. L. Jimenez
University of Colorado, Boulder, CO, USA
J. Lee-Taylor
National Center for Atmospheric Research, Boulder, CO, USA
J. Orlando
National Center for Atmospheric Research, Boulder, CO, USA
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41 citations as recorded by crossref.
- SOA formation from the photooxidation of <i>α</i>-pinene: systematic exploration of the simulation of chamber data R. McVay et al. 10.5194/acp-16-2785-2016
- Rethinking the global secondary organic aerosol (SOA) budget: stronger production, faster removal, shorter lifetime A. Hodzic et al. 10.5194/acp-16-7917-2016
- In situ constraints on the vertical distribution of global aerosol D. Watson-Parris et al. 10.5194/acp-19-11765-2019
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- Organic aerosols over Indo-Gangetic Plain: Sources, distributions and climatic implications N. Singh et al. 10.1016/j.atmosenv.2017.03.008
- Photodegradation of Secondary Organic Aerosol Particles as a Source of Small, Oxygenated Volatile Organic Compounds K. Malecha & S. Nizkorodov 10.1021/acs.est.6b02313
- Constraining remote oxidation capacity with ATom observations K. Travis et al. 10.5194/acp-20-7753-2020
- Improving regional air quality predictions in the Indo-Gangetic Plain – case study of an intensive pollution episode in November 2017 B. Roozitalab et al. 10.5194/acp-21-2837-2021
- Modeled and observed properties related to the direct aerosol radiative effect of biomass burning aerosol over the southeastern Atlantic S. Doherty et al. 10.5194/acp-22-1-2022
- Photolytic Aging of Secondary Organic Aerosol: Evidence for a Substantial Photo-Recalcitrant Fraction R. O’Brien & J. Kroll 10.1021/acs.jpclett.9b01417
- Effect of vertical parameterization of a missing daytime source of HONO on concentrations of HONO, O3 and secondary organic aerosols in eastern China Y. Guo et al. 10.1016/j.atmosenv.2019.117208
- Effects of Photolysis on the Chemical and Optical Properties of Secondary Organic Material Over Extended Time Scales E. Walhout et al. 10.1021/acsearthspacechem.9b00109
- Environmental effects of stratospheric ozone depletion, UV radiation, and interactions with climate change: UNEP Environmental Effects Assessment Panel, Update 2020 R. Neale et al. 10.1007/s43630-020-00001-x
- Limited effect of anthropogenic nitrogen oxides on secondary organic aerosol formation Y. Zheng et al. 10.5194/acp-15-13487-2015
- Roles of semivolatile and intermediate-volatility organic compounds in secondary organic aerosol formation and its implication: A review Z. Ling et al. 10.1016/j.jes.2021.08.055
- Non-linear partitioning and organic volatility distributions of urban aerosols S. Madronich et al. 10.1039/C5FD00209E
- Isoprene-derived secondary organic aerosol in the global aerosol–chemistry–climate model ECHAM6.3.0–HAM2.3–MOZ1.0 S. Stadtler et al. 10.5194/gmd-11-3235-2018
- Secondary organic aerosol production from local emissions dominates the organic aerosol budget over Seoul, South Korea, during KORUS-AQ B. Nault et al. 10.5194/acp-18-17769-2018
- Formation and composition of the UTLS aerosol B. Martinsson et al. 10.1038/s41612-019-0097-1
- Photolysis of multifunctional carbonyl compounds under natural irradiation at EUPHORE A. Tomas et al. 10.1016/j.atmosenv.2021.118352
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- Photochemical transformation of residential wood combustion emissions: dependence of organic aerosol composition on OH exposure A. Hartikainen et al. 10.5194/acp-20-6357-2020
- Semivolatile POA and parameterized total combustion SOA in CMAQv5.2: impacts on source strength and partitioning B. Murphy et al. 10.5194/acp-17-11107-2017
- Photodegradation of Secondary Organic Aerosol Material Quantified with a Quartz Crystal Microbalance K. Malecha et al. 10.1021/acs.estlett.8b00231
- UV/Vis and IRMPD Spectroscopic Analysis of the Absorption Properties of Methylglyoxal Brown Carbon L. Vo et al. 10.1021/acsearthspacechem.1c00022
- Space‐Borne Estimation of Volcanic Sulfate Aerosol Lifetime C. Li & R. Cohen 10.1029/2020JD033883
- Non-OH chemistry in oxidation flow reactors for the study of atmospheric chemistry systematically examined by modeling Z. Peng et al. 10.5194/acp-16-4283-2016
- New SOA Treatments Within the Energy Exascale Earth System Model (E3SM): Strong Production and Sinks Govern Atmospheric SOA Distributions and Radiative Forcing S. Lou et al. 10.1029/2020MS002266
- Impact of the Atmospheric Photochemical Evolution of the Organic Component of Biomass Burning Aerosol on Its Radiative Forcing Efficiency: A Box Model Analysis T. Zhuravleva et al. 10.3390/atmos12121555
- The photolysis of α-hydroperoxycarbonyls Z. Liu et al. 10.1039/C7CP08421H
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- Photodegradation of Secondary Organic Aerosols by Long-Term Exposure to Solar Actinic Radiation V. Baboomian et al. 10.1021/acsearthspacechem.0c00088
- Labile Peroxides in Secondary Organic Aerosol M. Krapf et al. 10.1016/j.chempr.2016.09.007
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- Parameterized Yields of Semivolatile Products from Isoprene Oxidation under Different NOx Levels: Impacts of Chemical Aging and Wall-Loss of Reactive Gases L. Xing et al. 10.1021/acs.est.8b00373
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Latest update: 28 Mar 2023
Short summary
Our study combines process and global chemistry modeling to investigate the potential effect of gas- and particle-phase organic photolysis reactions on the formation and lifetime of secondary organic aerosols (SOAs). Photolysis of the oxidation intermediates that partition between gas and particle phases to form SOA is not included in 3D models. Our results suggest that exposure to UV light can suppress the formation of SOA or even lead to its substantial loss (comparable to wet deposition).
Our study combines process and global chemistry modeling to investigate the potential effect of...
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