Articles | Volume 15, issue 6
https://doi.org/10.5194/acp-15-3429-2015
© Author(s) 2015. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/acp-15-3429-2015
© Author(s) 2015. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Research article
| 
28 Mar 2015
Research article |
| 28 Mar 2015
Total sulfate vs. sulfuric acid monomer concenterations in nucleation studies
K. Neitola
CORRESPONDING AUTHOR
Finnish Meteorological Institute, Erik Palménin aukio 1, P.O. Box 503, 00100 Helsinki, Finland
Finnish Meteorological Institute, Erik Palménin aukio 1, P.O. Box 503, 00100 Helsinki, Finland
Laboratory of Aerosol Chemistry and Physics, Institute of Chemical Process Fundamentals Academy of Sciences of the Czech Republic, Rozvojová 135, 165 02 Prague 6, Czech Republic
U. Makkonen
Finnish Meteorological Institute, Erik Palménin aukio 1, P.O. Box 503, 00100 Helsinki, Finland
M. Sipilä
Department of Physical Sciences, University of Helsinki, P.O. Box 64, 00014 Helsinki, Finland
R. L. Mauldin III
Institute for Arctic and Alpine Research, University of Colorado, Boulder, CO 80309, USA
Department of Physical Sciences, University of Helsinki, P.O. Box 64, 00014 Helsinki, Finland
N. Sarnela
Department of Physical Sciences, University of Helsinki, P.O. Box 64, 00014 Helsinki, Finland
T. Jokinen
Department of Physical Sciences, University of Helsinki, P.O. Box 64, 00014 Helsinki, Finland
H. Lihavainen
Finnish Meteorological Institute, Erik Palménin aukio 1, P.O. Box 503, 00100 Helsinki, Finland
M. Kulmala
Department of Physical Sciences, University of Helsinki, P.O. Box 64, 00014 Helsinki, Finland
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Cited
15 citations as recorded by crossref.
- Can formaldehyde contribute to atmospheric new particle formation from sulfuric acid and water? C. Wang et al. 10.1016/j.atmosenv.2018.12.057
- A one-year, on-line, multi-site observational study on water-soluble inorganic ions in PM 2.5 over the Pearl River Delta region, China J. Liu et al. 10.1016/j.scitotenv.2017.06.039
- Size resolved chemical composition of nanoparticles from reactions of sulfuric acid with ammonia and dimethylamine H. Chen et al. 10.1080/02786826.2018.1490005
- Inversely modeling homogeneous H<sub>2</sub>SO<sub>4</sub> − H<sub>2</sub>O nucleation rate in exhaust-related conditions M. Olin et al. 10.5194/acp-19-6367-2019
- Temperature-Dependent Diffusion of H2SO4 in Air at Atmospherically Relevant Conditions: Laboratory Measurements Using Laminar Flow Technique D. Brus et al. 10.3390/atmos8070132
- From O2–-Initiated SO2 Oxidation to Sulfate Formation in the Gas Phase N. Tsona et al. 10.1021/acs.jpca.8b03381
- Laboratory observations of temperature and humidity dependencies of nucleation and growth rates of sub‐3 nm particles H. Yu et al. 10.1002/2016JD025619
- Effect of dimethylamine on the gas phase sulfuric acid concentration measured by Chemical Ionization Mass Spectrometry L. Rondo et al. 10.1002/2015JD023868
- The striking effect of vertical mixing in the planetary boundary layer on new particle formation in the Yangtze River Delta S. Lai et al. 10.1016/j.scitotenv.2022.154607
- Reevaluating the contribution of sulfuric acid and the origin of organic compounds in atmospheric nanoparticle growth V. Vakkari et al. 10.1002/2015GL066459
- Overview: Homogeneous nucleation from the vapor phase—The experimental science B. Wyslouzil & J. Wölk 10.1063/1.4962283
- Laboratory study of H<sub>2</sub>SO<sub>4</sub>/H<sub>2</sub>O nucleation using a new technique – a laminar co-flow tube T. Trávníčková et al. 10.1080/16000889.2018.1446643
- Wintertime new particle formation and its contribution to cloud condensation nuclei in the Northeastern United States F. Yu et al. 10.5194/acp-20-2591-2020
- Formation and growth of sub-3-nm aerosol particles in experimental chambers L. Dada et al. 10.1038/s41596-019-0274-z
- On the Ship Particle Number Emission Index: Size‐Resolved Microphysics and Key Controlling Parameters J. Mao et al. 10.1029/2020JD034427
15 citations as recorded by crossref.
- Can formaldehyde contribute to atmospheric new particle formation from sulfuric acid and water? C. Wang et al. 10.1016/j.atmosenv.2018.12.057
- A one-year, on-line, multi-site observational study on water-soluble inorganic ions in PM 2.5 over the Pearl River Delta region, China J. Liu et al. 10.1016/j.scitotenv.2017.06.039
- Size resolved chemical composition of nanoparticles from reactions of sulfuric acid with ammonia and dimethylamine H. Chen et al. 10.1080/02786826.2018.1490005
- Inversely modeling homogeneous H<sub>2</sub>SO<sub>4</sub> − H<sub>2</sub>O nucleation rate in exhaust-related conditions M. Olin et al. 10.5194/acp-19-6367-2019
- Temperature-Dependent Diffusion of H2SO4 in Air at Atmospherically Relevant Conditions: Laboratory Measurements Using Laminar Flow Technique D. Brus et al. 10.3390/atmos8070132
- From O2–-Initiated SO2 Oxidation to Sulfate Formation in the Gas Phase N. Tsona et al. 10.1021/acs.jpca.8b03381
- Laboratory observations of temperature and humidity dependencies of nucleation and growth rates of sub‐3 nm particles H. Yu et al. 10.1002/2016JD025619
- Effect of dimethylamine on the gas phase sulfuric acid concentration measured by Chemical Ionization Mass Spectrometry L. Rondo et al. 10.1002/2015JD023868
- The striking effect of vertical mixing in the planetary boundary layer on new particle formation in the Yangtze River Delta S. Lai et al. 10.1016/j.scitotenv.2022.154607
- Reevaluating the contribution of sulfuric acid and the origin of organic compounds in atmospheric nanoparticle growth V. Vakkari et al. 10.1002/2015GL066459
- Overview: Homogeneous nucleation from the vapor phase—The experimental science B. Wyslouzil & J. Wölk 10.1063/1.4962283
- Laboratory study of H<sub>2</sub>SO<sub>4</sub>/H<sub>2</sub>O nucleation using a new technique – a laminar co-flow tube T. Trávníčková et al. 10.1080/16000889.2018.1446643
- Wintertime new particle formation and its contribution to cloud condensation nuclei in the Northeastern United States F. Yu et al. 10.5194/acp-20-2591-2020
- Formation and growth of sub-3-nm aerosol particles in experimental chambers L. Dada et al. 10.1038/s41596-019-0274-z
- On the Ship Particle Number Emission Index: Size‐Resolved Microphysics and Key Controlling Parameters J. Mao et al. 10.1029/2020JD034427
Saved (final revised paper)
Saved (preprint)
Latest update: 13 Dec 2024
Short summary
A discrepancy of 2 orders of magnitude was found between the measured sulfuric acid monomer concentration and total sulfate, when measured with independent methods (mass spectrometry and ion chromatography) with the same source of sulphuric acid vapor. The ion chromatography method produces the exact concentrations predicted by empirical equations, and the mass spectrometry method shows significantly lower values. The discrepancy is investigated thoroughly from different points of views.
A discrepancy of 2 orders of magnitude was found between the measured sulfuric acid monomer...
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