Articles | Volume 15, issue 4
https://doi.org/10.5194/acp-15-1843-2015
https://doi.org/10.5194/acp-15-1843-2015
Research article
 | 
20 Feb 2015
Research article |  | 20 Feb 2015

SO2 photolysis as a source for sulfur mass-independent isotope signatures in stratospehric aerosols

A. R. Whitehill, B. Jiang, H. Guo, and S. Ono

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Kinetic isotope effects of 12CH3D  + OH and 13CH3D  + OH from 278 to 313 K
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Subject: Isotopes | Research Activity: Laboratory Studies | Altitude Range: Stratosphere | Science Focus: Chemistry (chemical composition and reactions)
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Cited articles

Ahmed, M. M.: Theoretical studies on the ground and excited states of SO3 triatomic molecule, Chem. Sci. Trans., 2, 781–796, https://doi.org/10.7598/cst2013.515, 2013.
Astholz, D. C., Glanzer, K., and Troe, J.: The spin-forbidden dissociation-recombination reaction SO3 → SO2 +O, J. Chem. Phys., 70, 2409–2413, https://doi.org/10.1063/1.437751, 1979.
Baroni, M., Thiemens, M. H., Delmas, R. J., and Savarino, J.: Mass-independent sulfur isotopic compositions in stratospheric volcanic eruptions, Science, 315, 84–87, https://doi.org/10.1126/science.1131754, 2007.
Baroni, M., Savarino, J., Cole-Dai, J., Rai, V. K., and Thiemens, M. H.: Anomalous sulfur isotope compositions of volcanic sulfate over the last millennium in Antarctic ice cores, J. Geophys. Res. Atmos., 113, D20112, https://doi.org/10.1029/2008JD010185, 2008.
Becke, A. D.: Density-functional exchange-energy approximation with correct asymptotic behavior, Phys. Rev. A, 38, 3098–3100, https://doi.org/10.1103/PhysRevA.38.3098, 1988.
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