Articles | Volume 15, issue 4
https://doi.org/10.5194/acp-15-1843-2015
© Author(s) 2015. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/acp-15-1843-2015
© Author(s) 2015. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
SO2 photolysis as a source for sulfur mass-independent isotope signatures in stratospehric aerosols
A. R. Whitehill
CORRESPONDING AUTHOR
Department of Earth, Atmospheric, and Planetary Sciences, Massachusetts Institute of Technology, 77 Massachusetts Ave., Cambridge, MA 02139, USA
B. Jiang
Department of Chemistry and Chemical Biology, University of New Mexico, Albuquerque, NM 87131, USA
H. Guo
Department of Chemistry and Chemical Biology, University of New Mexico, Albuquerque, NM 87131, USA
S. Ono
Department of Earth, Atmospheric, and Planetary Sciences, Massachusetts Institute of Technology, 77 Massachusetts Ave., Cambridge, MA 02139, USA
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Cited
66 citations as recorded by crossref.
- Simultaneous fractionation of sulfur dioxide explains mass independent fractionation of sulfur isotopes in Archean sedimentary pyrites M. Chen et al. 10.1016/j.chemgeo.2021.120640
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- Sulfur Isotopic Fractionation of Carbonyl Sulfide during Degradation by Soil Bacteria K. Kamezaki et al. 10.1021/acs.est.5b05325
- Ratios of Sulfur Isotopes (32S, 33S, 34S, and 36S) in Archean Rocks of Karelia: Evidence of Microbial Life and the Anoxic Atmosphere T. Velivetskaya et al. 10.2113/RGG20234602
- Multiple sulfur isotopes in post-Archean deposits as a potential tracer for fluid mixing processes: An example from an iron oxide–copper–gold (IOCG) deposit in southern Peru R. Li et al. 10.1016/j.chemgeo.2021.120230
- Atmospheric ozone destruction and the end-Permian crisis: Evidence from multiple sulfur isotopes R. Li et al. 10.1016/j.chemgeo.2024.121936
- An analysis of Δ36S/Δ33S dependence on definitions of sulfur mass-independent fractionation Y. Endo et al. 10.1016/j.chemgeo.2024.122157
- Adsorption and photocatalytic removal of SO2 using natural and synthetic zeolites-supported TiO2 in a solar parabolic trough collector Z. Razavi et al. 10.1016/j.jclepro.2021.127376
- Capture of SO3isomers in the oxidation of sulfur monoxide with molecular oxygen Z. Wu et al. 10.1039/C7CC09389F
- VUV pressure-broadening in sulfur dioxide J. Lyons et al. 10.1016/j.jqsrt.2018.02.013
- Cosmic symplectite recorded irradiation by nearby massive stars in the solar system's parent molecular cloud L. Vacher et al. 10.1016/j.gca.2021.06.026
- Formation of secondary aerosol by 222 nm Far-UVC irradiation on SO2 Z. Liang et al. 10.1016/j.atmosenv.2024.120559
- The near-UV absorber OSSO and its isomers Z. Wu et al. 10.1039/C8CC00999F
- Five-S-isotope evidence of two distinct mass-independent sulfur isotope effects and implications for the modern and Archean atmospheres M. Lin et al. 10.1073/pnas.1803420115
- Radical chemistry in oxidation flow reactors for atmospheric chemistry research Z. Peng & J. Jimenez 10.1039/C9CS00766K
- Sulfur-isotope anomalies recorded in Antarctic ice cores as a potential proxy for tracing past ozone layer depletion events S. Dasari et al. 10.1093/pnasnexus/pgac170
- Retrospective Isotopic Analysis of Summertime Urban Atmospheric Sulfate in South Asia Using Improved Source Constraints S. Dasari & D. Widory 10.1021/acsestair.3c00060
- Total Absorption Cross Section for UV Excitation of Sulfur Monoxide K. Sarka & S. Nanbu 10.1021/acs.jpca.9b01921
- Sulfur isotope fractionation by broadband UV radiation to optically thin SO 2 under reducing atmosphere Y. Endo et al. 10.1016/j.epsl.2016.07.057
- Bulk and grain-scale minor sulfur isotope data reveal complexities in the dynamics of Earth’s oxygenation G. Izon et al. 10.1073/pnas.2025606119
- Photoabsorption cross‐section measurements of 32S, 33S, 34S, and 36S sulfur dioxide from 190 to 220 nm Y. Endo et al. 10.1002/2014JD021671
- Use of Isotope Effects To Understand the Present and Past of the Atmosphere and Climate and Track the Origin of Life M. Thiemens & M. Lin 10.1002/anie.201812322
- Effect of Mass-Independent Isotope Fractionation of Sulfur (Δ33S and Δ36S) during SO2 Photolysis in Experiments with a Broadband Light Source A. Ignatiev et al. 10.1134/S0016702919070061
- Sulfur Isotope Anomalies (Δ33S) in Urban Air Pollution Linked to Mineral-Dust-Associated Sulfate S. Dasari et al. 10.1021/acs.estlett.2c00312
- Absorption spectra measurements at ~1 cm<sup>–1</sup> spectral resolution of <sup>32</sup>S, <sup>33</sup>S, <sup>34</sup>S, and <sup>36</sup>S sulfur dioxide for the 206–220 nm region and applications to modeling of the isotopic self-shielding Y. Endo et al. 10.2343/geochemj.GJ22004
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- Tracing the origin of elevated springtime atmospheric sulfate on the southern Himalayan-Tibetan plateau S. Dasari et al. 10.1039/D3VA00085K
- Sunlight as an energetic driver in the synthesis of molecules necessary for life R. Rapf & V. Vaida 10.1039/C6CP00980H
- Seasonality in the Δ<sup>33</sup>S measured in urban aerosols highlights an additional oxidation pathway for atmospheric SO<sub>2</sub> D. Au Yang et al. 10.5194/acp-19-3779-2019
- Atmospheric SO2 oxidation by NO2 plays no role in the mass independent sulfur isotope fractionation of urban aerosols D. Au Yang et al. 10.1016/j.atmosenv.2018.09.007
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- Deposition of sulfate aerosols with positive Δ33S in the Neoarchean G. Paris et al. 10.1016/j.gca.2020.06.028
- Intercomparison measurements of two 33S-enriched sulfur isotope standards L. Geng et al. 10.1039/C8JA00451J
- Multiple Sulfur Isotopic Evidence for Sulfate Formation in Haze Pollution X. Han et al. 10.1021/acs.est.3c05072
- The mass-independent oxygen isotopic composition in sulfate aerosol-a useful tool to identify sulfate formation: a review Y. Zhao et al. 10.1016/j.atmosres.2020.105447
- Primary sulfur isotope signatures preserved in high-grade Archean barite deposits of the Sargur Group, Dharwar Craton, India É. Muller et al. 10.1016/j.precamres.2017.04.029
- Accurate characterization of the lowest triplet potential energy surface of SO2 with a coupled cluster method P. Kumar et al. 10.1063/1.5088959
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- Volcanic Plume Impact on the Atmosphere and Climate: O- and S-Isotope Insight into Sulfate Aerosol Formation E. Martin 10.3390/geosciences8060198
- An analytical formulation of isotope fractionation due to self-shielding J. Lyons 10.1016/j.gca.2020.05.001
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- Coupling sulfur and oxygen isotope ratios in sediment melts across the Archean-Proterozoic transition J. Liebmann et al. 10.1016/j.gca.2021.05.045
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- Atmospheric sulfur cycle elucidated by isotopologue measurements S. HATTORI et al. 10.3724/j.issn.1007-2802.20240068
- Continuous-Flow Stable Sulfur Isotope Analysis of Organic and Inorganic Compounds by EA-MC-ICPMS A. Horst et al. 10.1021/acs.analchem.4c00439
- A new type of isotopic anomaly in shergottite sulfides H. Franz et al. 10.1111/maps.13404
- SO2 Oxidation Kinetics Leave a Consistent Isotopic Imprint on Volcanic Ice Core Sulfate E. Gautier et al. 10.1029/2018JD028456
- Negative Ion Formation by Thermal Surface Ionization of Sulfur Dioxide K. Marciszuk et al. 10.1002/cphc.202000388
- Multiple Sulfur Isotope Compositions in Mesoarchean Sulfide Deposits of the Karelian Craton: Implications for Determining the Sulfur Source, Biogeochemical Processes, and Deposit Genesis S. Vysotskiy et al. 10.2113/RGG20214413
- Recombination reactions as a possible mechanism of mass-independent fractionation of sulfur isotopes in the Archean atmosphere of Earth D. Babikov 10.1073/pnas.1620977114
- Multiple Sulfur Isotope Constraints on Sources and Formation Processes of Sulfate in Beijing PM2.5 Aerosol X. Han et al. 10.1021/acs.est.7b00280
- One possible source of mass-independent fractionation of sulfur isotopes in the Archean atmosphere of Earth D. Babikov et al. 10.1016/j.gca.2017.01.029
- Use of Isotope Effects To Understand the Present and Past of the Atmosphere and Climate and Track the Origin of Life M. Thiemens & M. Lin 10.1002/ange.201812322
- Pure rotational spectrum of cis-OSOO M. Nakajima & Y. Endo 10.1016/j.cplett.2019.03.061
- Sulfur isotopes in diamonds reveal differences in continent construction K. Smit et al. 10.1126/science.aaw9548
- Application of the Sulfur Recovery Method by the Kiba Reagent for the Subsequent Isotope Analysis of Natural Sulfates and Sulfuric Acid V. Yakovenko et al. 10.1134/S0016702921040091
- Computational analysis of vibrational modes in tetra-sulfur using dimensionally reduced potential energy surface I. Gayday et al. 10.1080/00268976.2019.1574038
- Persistent Draining of the Stratospheric 10Be Reservoir After the Samalas Volcanic Eruption (1257 CE) M. Baroni et al. 10.1029/2018JD029823
- Ab initio study on the molecular structure and spectroscopic properties of isomers of SO3 L. Chi et al. 10.1016/j.saa.2020.118746
- Sulfur mass-independent fractionation during SO2 photolysis in low-temperature/pressure atmospheres Y. Endo et al. 10.1016/j.chemgeo.2022.121064
- Multiple sulfur-isotope signatures in Archean sulfates and their implications for the chemistry and dynamics of the early atmosphere É. Muller et al. 10.1073/pnas.1520522113
- A multiple sulfur record of super-large volcanic eruptions in Archaean pyrite nodules A. Agangi et al. 10.1016/j.epsl.2022.117737
- A small S-MIF signal in Martian regolith pyrite: Implications for the atmosphere A. Tomkins et al. 10.1016/j.gca.2020.07.022
- Sources of auriferous fluids associated with a Neoarchean BIF-hosted orogenic gold deposit revealed by the multiple sulfur isotopic compositions of zoned pyrites L. Liu et al. 10.1007/s00410-021-01788-3
- Isotope shifts and band progressions in SO2 rovibrational energy levels: using quantum theory to extract rotational constants P. Kumar & B. Poirier 10.1080/00268976.2019.1567850
65 citations as recorded by crossref.
- Simultaneous fractionation of sulfur dioxide explains mass independent fractionation of sulfur isotopes in Archean sedimentary pyrites M. Chen et al. 10.1016/j.chemgeo.2021.120640
- A seawater-sulfate origin for early Earth’s volcanic sulfur H. Ohmoto 10.1038/s41561-020-0601-6
- Sulfur Isotopic Fractionation of Carbonyl Sulfide during Degradation by Soil Bacteria K. Kamezaki et al. 10.1021/acs.est.5b05325
- Ratios of Sulfur Isotopes (32S, 33S, 34S, and 36S) in Archean Rocks of Karelia: Evidence of Microbial Life and the Anoxic Atmosphere T. Velivetskaya et al. 10.2113/RGG20234602
- Multiple sulfur isotopes in post-Archean deposits as a potential tracer for fluid mixing processes: An example from an iron oxide–copper–gold (IOCG) deposit in southern Peru R. Li et al. 10.1016/j.chemgeo.2021.120230
- Atmospheric ozone destruction and the end-Permian crisis: Evidence from multiple sulfur isotopes R. Li et al. 10.1016/j.chemgeo.2024.121936
- An analysis of Δ36S/Δ33S dependence on definitions of sulfur mass-independent fractionation Y. Endo et al. 10.1016/j.chemgeo.2024.122157
- Adsorption and photocatalytic removal of SO2 using natural and synthetic zeolites-supported TiO2 in a solar parabolic trough collector Z. Razavi et al. 10.1016/j.jclepro.2021.127376
- Capture of SO3isomers in the oxidation of sulfur monoxide with molecular oxygen Z. Wu et al. 10.1039/C7CC09389F
- VUV pressure-broadening in sulfur dioxide J. Lyons et al. 10.1016/j.jqsrt.2018.02.013
- Cosmic symplectite recorded irradiation by nearby massive stars in the solar system's parent molecular cloud L. Vacher et al. 10.1016/j.gca.2021.06.026
- Formation of secondary aerosol by 222 nm Far-UVC irradiation on SO2 Z. Liang et al. 10.1016/j.atmosenv.2024.120559
- The near-UV absorber OSSO and its isomers Z. Wu et al. 10.1039/C8CC00999F
- Five-S-isotope evidence of two distinct mass-independent sulfur isotope effects and implications for the modern and Archean atmospheres M. Lin et al. 10.1073/pnas.1803420115
- Radical chemistry in oxidation flow reactors for atmospheric chemistry research Z. Peng & J. Jimenez 10.1039/C9CS00766K
- Sulfur-isotope anomalies recorded in Antarctic ice cores as a potential proxy for tracing past ozone layer depletion events S. Dasari et al. 10.1093/pnasnexus/pgac170
- Retrospective Isotopic Analysis of Summertime Urban Atmospheric Sulfate in South Asia Using Improved Source Constraints S. Dasari & D. Widory 10.1021/acsestair.3c00060
- Total Absorption Cross Section for UV Excitation of Sulfur Monoxide K. Sarka & S. Nanbu 10.1021/acs.jpca.9b01921
- Sulfur isotope fractionation by broadband UV radiation to optically thin SO 2 under reducing atmosphere Y. Endo et al. 10.1016/j.epsl.2016.07.057
- Bulk and grain-scale minor sulfur isotope data reveal complexities in the dynamics of Earth’s oxygenation G. Izon et al. 10.1073/pnas.2025606119
- Photoabsorption cross‐section measurements of 32S, 33S, 34S, and 36S sulfur dioxide from 190 to 220 nm Y. Endo et al. 10.1002/2014JD021671
- Use of Isotope Effects To Understand the Present and Past of the Atmosphere and Climate and Track the Origin of Life M. Thiemens & M. Lin 10.1002/anie.201812322
- Effect of Mass-Independent Isotope Fractionation of Sulfur (Δ33S and Δ36S) during SO2 Photolysis in Experiments with a Broadband Light Source A. Ignatiev et al. 10.1134/S0016702919070061
- Sulfur Isotope Anomalies (Δ33S) in Urban Air Pollution Linked to Mineral-Dust-Associated Sulfate S. Dasari et al. 10.1021/acs.estlett.2c00312
- Absorption spectra measurements at ~1 cm<sup>–1</sup> spectral resolution of <sup>32</sup>S, <sup>33</sup>S, <sup>34</sup>S, and <sup>36</sup>S sulfur dioxide for the 206–220 nm region and applications to modeling of the isotopic self-shielding Y. Endo et al. 10.2343/geochemj.GJ22004
- Giant Mesozoic gold ores derived from subducted oceanic slab and overlying sediments K. Qiu et al. 10.1016/j.gca.2023.01.002
- Tracing the origin of elevated springtime atmospheric sulfate on the southern Himalayan-Tibetan plateau S. Dasari et al. 10.1039/D3VA00085K
- Sunlight as an energetic driver in the synthesis of molecules necessary for life R. Rapf & V. Vaida 10.1039/C6CP00980H
- Seasonality in the Δ<sup>33</sup>S measured in urban aerosols highlights an additional oxidation pathway for atmospheric SO<sub>2</sub> D. Au Yang et al. 10.5194/acp-19-3779-2019
- Atmospheric SO2 oxidation by NO2 plays no role in the mass independent sulfur isotope fractionation of urban aerosols D. Au Yang et al. 10.1016/j.atmosenv.2018.09.007
- In-situ quadruple sulfur isotopic compositions of pyrites in the ca. 3.2–2.72 Ga metasedimentary rocks from the Pilbara Craton, Western Australia L. Liu et al. 10.1016/j.chemgeo.2020.119837
- Deposition of sulfate aerosols with positive Δ33S in the Neoarchean G. Paris et al. 10.1016/j.gca.2020.06.028
- Intercomparison measurements of two 33S-enriched sulfur isotope standards L. Geng et al. 10.1039/C8JA00451J
- Multiple Sulfur Isotopic Evidence for Sulfate Formation in Haze Pollution X. Han et al. 10.1021/acs.est.3c05072
- The mass-independent oxygen isotopic composition in sulfate aerosol-a useful tool to identify sulfate formation: a review Y. Zhao et al. 10.1016/j.atmosres.2020.105447
- Primary sulfur isotope signatures preserved in high-grade Archean barite deposits of the Sargur Group, Dharwar Craton, India É. Muller et al. 10.1016/j.precamres.2017.04.029
- Accurate characterization of the lowest triplet potential energy surface of SO2 with a coupled cluster method P. Kumar et al. 10.1063/1.5088959
- Spectroscopic identification of the •SSNO isomers L. Wang et al. 10.1063/5.0020669
- Volcanic Plume Impact on the Atmosphere and Climate: O- and S-Isotope Insight into Sulfate Aerosol Formation E. Martin 10.3390/geosciences8060198
- An analytical formulation of isotope fractionation due to self-shielding J. Lyons 10.1016/j.gca.2020.05.001
- Total Pressure Dependence of Sulfur Mass‐Independent Fractionation by SO2Photolysis Y. Endo et al. 10.1029/2018GL080730
- Coupling sulfur and oxygen isotope ratios in sediment melts across the Archean-Proterozoic transition J. Liebmann et al. 10.1016/j.gca.2021.05.045
- Photochemistry of Sulfur Dioxide and the Origin of Mass-Independent Isotope Fractionation in Earth's Atmosphere S. Ono 10.1146/annurev-earth-060115-012324
- Final State Resolved Quantum Predissociation Dynamics of SO2(C̃1B2) and Its Isotopomers via a Crossing with a Singlet Repulsive State C. Xie et al. 10.1021/acs.jpca.7b04629
- Atmospheric sulfur cycle elucidated by isotopologue measurements S. HATTORI et al. 10.3724/j.issn.1007-2802.20240068
- Continuous-Flow Stable Sulfur Isotope Analysis of Organic and Inorganic Compounds by EA-MC-ICPMS A. Horst et al. 10.1021/acs.analchem.4c00439
- A new type of isotopic anomaly in shergottite sulfides H. Franz et al. 10.1111/maps.13404
- SO2 Oxidation Kinetics Leave a Consistent Isotopic Imprint on Volcanic Ice Core Sulfate E. Gautier et al. 10.1029/2018JD028456
- Negative Ion Formation by Thermal Surface Ionization of Sulfur Dioxide K. Marciszuk et al. 10.1002/cphc.202000388
- Multiple Sulfur Isotope Compositions in Mesoarchean Sulfide Deposits of the Karelian Craton: Implications for Determining the Sulfur Source, Biogeochemical Processes, and Deposit Genesis S. Vysotskiy et al. 10.2113/RGG20214413
- Recombination reactions as a possible mechanism of mass-independent fractionation of sulfur isotopes in the Archean atmosphere of Earth D. Babikov 10.1073/pnas.1620977114
- Multiple Sulfur Isotope Constraints on Sources and Formation Processes of Sulfate in Beijing PM2.5 Aerosol X. Han et al. 10.1021/acs.est.7b00280
- One possible source of mass-independent fractionation of sulfur isotopes in the Archean atmosphere of Earth D. Babikov et al. 10.1016/j.gca.2017.01.029
- Use of Isotope Effects To Understand the Present and Past of the Atmosphere and Climate and Track the Origin of Life M. Thiemens & M. Lin 10.1002/ange.201812322
- Pure rotational spectrum of cis-OSOO M. Nakajima & Y. Endo 10.1016/j.cplett.2019.03.061
- Sulfur isotopes in diamonds reveal differences in continent construction K. Smit et al. 10.1126/science.aaw9548
- Application of the Sulfur Recovery Method by the Kiba Reagent for the Subsequent Isotope Analysis of Natural Sulfates and Sulfuric Acid V. Yakovenko et al. 10.1134/S0016702921040091
- Computational analysis of vibrational modes in tetra-sulfur using dimensionally reduced potential energy surface I. Gayday et al. 10.1080/00268976.2019.1574038
- Persistent Draining of the Stratospheric 10Be Reservoir After the Samalas Volcanic Eruption (1257 CE) M. Baroni et al. 10.1029/2018JD029823
- Ab initio study on the molecular structure and spectroscopic properties of isomers of SO3 L. Chi et al. 10.1016/j.saa.2020.118746
- Sulfur mass-independent fractionation during SO2 photolysis in low-temperature/pressure atmospheres Y. Endo et al. 10.1016/j.chemgeo.2022.121064
- Multiple sulfur-isotope signatures in Archean sulfates and their implications for the chemistry and dynamics of the early atmosphere É. Muller et al. 10.1073/pnas.1520522113
- A multiple sulfur record of super-large volcanic eruptions in Archaean pyrite nodules A. Agangi et al. 10.1016/j.epsl.2022.117737
- A small S-MIF signal in Martian regolith pyrite: Implications for the atmosphere A. Tomkins et al. 10.1016/j.gca.2020.07.022
- Sources of auriferous fluids associated with a Neoarchean BIF-hosted orogenic gold deposit revealed by the multiple sulfur isotopic compositions of zoned pyrites L. Liu et al. 10.1007/s00410-021-01788-3
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