Articles | Volume 14, issue 9
Atmos. Chem. Phys., 14, 4827–4841, 2014

Special issue: The TransBrom Sonne ship campaign in the West Pacific

Atmos. Chem. Phys., 14, 4827–4841, 2014

Research article 15 May 2014

Research article | 15 May 2014

A tropical West Pacific OH minimum and implications for stratospheric composition

M. Rex1, I. Wohltmann1, T. Ridder2, R. Lehmann1, K. Rosenlof3, P. Wennberg4, D. Weisenstein5, J. Notholt2, K. Krüger6,*, V. Mohr6, and S. Tegtmeier6 M. Rex et al.
  • 1Alfred Wegener Institute for Polar and Marine Research, Potsdam, Germany
  • 2Institute of Environmental Physics, University of Bremen, Bremen, Germany
  • 3NOAA ESRL Chemical Sciences Division, Boulder, CO, USA
  • 4California Institute of Technology, Pasadena, CA, USA
  • 5Atmospheric and Environmental Research, Inc., Lexington, MA, USA
  • 6Helmholtz Centre for Ocean Research Kiel (GEOMAR), Kiel, Germany
  • *now at: University of Oslo, Oslo, Norway

Abstract. Most of the short-lived biogenic and anthropogenic chemical species that are emitted into the atmosphere break down efficiently by reaction with OH and do not reach the stratosphere. Here we show the existence of a pronounced minimum in the tropospheric column of ozone over the West Pacific, the main source region for stratospheric air, and suggest a corresponding minimum of the tropospheric column of OH. This has the potential to amplify the impact of surface emissions on the stratospheric composition compared to the impact when assuming globally uniform OH conditions. Specifically, the role of emissions of biogenic halogenated species for the stratospheric halogen budget and the role of increasing emissions of SO2 in Southeast Asia or from minor volcanic eruptions for the increasing stratospheric aerosol loading need to be reassessed in light of these findings. This is also important since climate change will further modify OH abundances and emissions of halogenated species. Our study is based on ozone sonde measurements carried out during the TransBrom cruise with the RV Sonne roughly along 140–150° E in October 2009 and corroborating ozone and OH measurements from satellites, aircraft campaigns and FTIR instruments. Model calculations with the GEOS-Chem Chemistry and Transport Model (CTM) and the ATLAS CTM are used to simulate the tropospheric OH distribution over the West Pacific and the transport pathways to the stratosphere. The potential effect of the OH minimum on species transported into the stratosphere is shown via modeling the transport and chemistry of CH2Br2 and SO2.

Final-revised paper