Articles | Volume 14, issue 7
https://doi.org/10.5194/acp-14-3397-2014
© Author(s) 2014. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/acp-14-3397-2014
© Author(s) 2014. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Research article
| 
07 Apr 2014
Research article |
| 07 Apr 2014
Sensitivity of tropospheric chemical composition to halogen-radical chemistry using a fully coupled size-resolved multiphase chemistry–global climate system: halogen distributions, aerosol composition, and sensitivity of climate-relevant gases
M. S. Long
School of Engineering and Applied Sciences, Harvard University, Cambridge, MA, USA
W. C. Keene
Department of Environmental Sciences, University of Virginia, Charlottesville, VA 22904, USA
R. C. Easter
Atmospheric Sciences and Global Change Division, Pacific Northwest National Laboratory, Richland, Washington, USA
R. Sander
Air Chemistry Department, Max-Planck Institute of Chemistry, 55020 Mainz, Germany
Department of Atmospheric University of Wyoming, Laramie, WY 82071, USA
A. Kerkweg
Institute for Atmospheric Physics, University of Mainz, 55099 Mainz, Germany
D. Erickson
Computer Science and Mathematics Division, Oak Ridge National Laboratory, Oak Ridge, TN USA
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Cited
40 citations as recorded by crossref.
- Modeling the observed tropospheric BrO background: Importance of multiphase chemistry and implications for ozone, OH, and mercury J. Schmidt et al. https://doi.org/10.1002/2015JD024229
- Global impacts of tropospheric halogens (Cl, Br, I) on oxidants and composition in GEOS-Chem T. Sherwen et al. https://doi.org/10.5194/acp-16-12239-2016
- Near-Explicit Multiphase Modeling of Halogen Chemistry in a Mixed Urban and Maritime Coastal Area E. Hoffmann et al. https://doi.org/10.1021/acsearthspacechem.9b00184
- Global impact of nitrate photolysis in sea-salt aerosol on NOx, OH, and O3 in the marine boundary layer P. Kasibhatla et al. https://doi.org/10.5194/acp-18-11185-2018
- Ambient air quality in the Kathmandu Valley, Nepal, during the pre-monsoon: concentrations and sources of particulate matter and trace gases M. Islam et al. https://doi.org/10.5194/acp-20-2927-2020
- Impact of the Water Molecule on the Gas-Phase Reaction between Acetone and Cl Atoms C. Fan et al. https://doi.org/10.1021/acsearthspacechem.1c00023
- Global inorganic nitrate production mechanisms: comparison of a global model with nitrate isotope observations B. Alexander et al. https://doi.org/10.5194/acp-20-3859-2020
- Marine Aerosol Production via Detrainment of Bubble Plumes Generated in Natural Seawater With a Forced‐Air Venturi A. Frossard et al. https://doi.org/10.1029/2019JD030299
- Effects of halogens on European air-quality T. Sherwen et al. https://doi.org/10.1039/C7FD00026J
- Effect of sea salt aerosol on tropospheric bromine chemistry L. Zhu et al. https://doi.org/10.5194/acp-19-6497-2019
- Marine aerosol distributions from shipborne observations over the South China Sea: diurnal variation characteristics and their controlling factors Z. Qiao et al. https://doi.org/10.5194/acp-25-18227-2025
- Atmospheric Wet Deposition in Remote Regions: Benchmarks for Environmental Change W. Keene et al. https://doi.org/10.1175/JAS-D-14-0378.1
- Formation mechanism and source apportionment of nitrate in atmospheric aerosols K. Xin et al. https://doi.org/10.30852/sb.2023.2225
- Factors That Modulate Properties of Primary Marine Aerosol Generated From Ambient Seawater on Ships at Sea W. Keene et al. https://doi.org/10.1002/2017JD026872
- Tropospheric ozone and its precursors from the urban to the global scale from air quality to short-lived climate forcer P. Monks et al. https://doi.org/10.5194/acp-15-8889-2015
- Christian Junge – a pioneer in global atmospheric chemistry R. Duce et al. https://doi.org/10.1007/s10874-022-09437-0
- Sensitivity of tropospheric ozone to halogen chemistry in the chemistry–climate model LMDZ-INCA vNMHC C. Caram et al. https://doi.org/10.5194/gmd-16-4041-2023
- Tropospheric Halogen Chemistry: Sources, Cycling, and Impacts W. Simpson et al. https://doi.org/10.1021/cr5006638
- Consumption of reactive halogen species from sea-salt aerosol by secondary organic aerosol: slowing down the bromine explosion J. Buxmann et al. https://doi.org/10.1071/EN14226
- Enhanced ozone loss by active inorganic bromine chemistry in the tropical troposphere M. Le Breton et al. https://doi.org/10.1016/j.atmosenv.2017.02.003
- A global model of tropospheric chlorine chemistry: Organic versus inorganic sources and impact on methane oxidation R. Hossaini et al. https://doi.org/10.1002/2016JD025756
- Impact of Enhanced Ozone Deposition and Halogen Chemistry on Tropospheric Ozone over the Northern Hemisphere G. Sarwar et al. https://doi.org/10.1021/acs.est.5b01657
- Halogen chemistry reduces tropospheric O3 radiative forcing T. Sherwen et al. https://doi.org/10.5194/acp-17-1557-2017
- Stratospheric Injection of Brominated Very Short‐Lived Substances: Aircraft Observations in the Western Pacific and Representation in Global Models P. Wales et al. https://doi.org/10.1029/2017JD027978
- Importance of reactive halogens in the tropical marine atmosphere: a regional modelling study using WRF-Chem A. Badia et al. https://doi.org/10.5194/acp-19-3161-2019
- Active and widespread halogen chemistry in the tropical and subtropical free troposphere S. Wang et al. https://doi.org/10.1073/pnas.1505142112
- Influence of bromine and iodine chemistry on annual, seasonal, diurnal, and background ozone: CMAQ simulations over the Northern Hemisphere G. Sarwar et al. https://doi.org/10.1016/j.atmosenv.2019.06.020
- Global tropospheric halogen (Cl, Br, I) chemistry and its impact on oxidants X. Wang et al. https://doi.org/10.5194/acp-21-13973-2021
- Year‐round records of sea salt, gaseous, and particulate inorganic bromine in the atmospheric boundary layer at coastal (Dumont d'Urville) and central (Concordia) East Antarctic sites M. Legrand et al. https://doi.org/10.1002/2015JD024066
- The role of chlorine in global tropospheric chemistry X. Wang et al. https://doi.org/10.5194/acp-19-3981-2019
- Mercury oxidation from bromine chemistry in the free troposphere over the southeastern US S. Coburn et al. https://doi.org/10.5194/acp-16-3743-2016
- Global Observations of Tropospheric Bromine Monoxide (BrO) Columns From TROPOMI Y. Chen et al. https://doi.org/10.1029/2023JD039091
- Updating sea spray aerosol emissions in the Community Multiscale Air Quality (CMAQ) model version 5.0.2 B. Gantt et al. https://doi.org/10.5194/gmd-8-3733-2015
- Origins of aerosol chlorine during winter over north central Colorado, USA C. Jordan et al. https://doi.org/10.1002/2014JD022294
- Atmospheric Chemistry of CH3OCF2CHF2 E. Kjærgaard et al. https://doi.org/10.1021/acs.jpca.1c08973
- BrO and inferred Bry profiles over the western Pacific: relevance of inorganic bromine sources and a Bry minimum in the aged tropical tropopause layer T. Koenig et al. https://doi.org/10.5194/acp-17-15245-2017
- CAPRAM reduction towards an operational multiphase halogen and dimethyl sulfide chemistry treatment in the chemistry transport model COSMO-MUSCAT(5.04e) E. Hoffmann et al. https://doi.org/10.5194/gmd-13-2587-2020
- Paleo-Perspectives on Potential Future Changes in the Oxidative Capacity of the Atmosphere Due to Climate Change and Anthropogenic Emissions B. Alexander & L. Mickley https://doi.org/10.1007/s40726-015-0006-0
- Microphysics of the aqueous bulk counters the water activity driven rate acceleration of bromide oxidation by ozone from 289–245 K J. Edebeli et al. https://doi.org/10.1039/C8EM00417J
- First direct observation of sea salt aerosol production from blowing snow above sea ice M. Frey et al. https://doi.org/10.5194/acp-20-2549-2020
40 citations as recorded by crossref.
- Modeling the observed tropospheric BrO background: Importance of multiphase chemistry and implications for ozone, OH, and mercury J. Schmidt et al. https://doi.org/10.1002/2015JD024229
- Global impacts of tropospheric halogens (Cl, Br, I) on oxidants and composition in GEOS-Chem T. Sherwen et al. https://doi.org/10.5194/acp-16-12239-2016
- Near-Explicit Multiphase Modeling of Halogen Chemistry in a Mixed Urban and Maritime Coastal Area E. Hoffmann et al. https://doi.org/10.1021/acsearthspacechem.9b00184
- Global impact of nitrate photolysis in sea-salt aerosol on NOx, OH, and O3 in the marine boundary layer P. Kasibhatla et al. https://doi.org/10.5194/acp-18-11185-2018
- Ambient air quality in the Kathmandu Valley, Nepal, during the pre-monsoon: concentrations and sources of particulate matter and trace gases M. Islam et al. https://doi.org/10.5194/acp-20-2927-2020
- Impact of the Water Molecule on the Gas-Phase Reaction between Acetone and Cl Atoms C. Fan et al. https://doi.org/10.1021/acsearthspacechem.1c00023
- Global inorganic nitrate production mechanisms: comparison of a global model with nitrate isotope observations B. Alexander et al. https://doi.org/10.5194/acp-20-3859-2020
- Marine Aerosol Production via Detrainment of Bubble Plumes Generated in Natural Seawater With a Forced‐Air Venturi A. Frossard et al. https://doi.org/10.1029/2019JD030299
- Effects of halogens on European air-quality T. Sherwen et al. https://doi.org/10.1039/C7FD00026J
- Effect of sea salt aerosol on tropospheric bromine chemistry L. Zhu et al. https://doi.org/10.5194/acp-19-6497-2019
- Marine aerosol distributions from shipborne observations over the South China Sea: diurnal variation characteristics and their controlling factors Z. Qiao et al. https://doi.org/10.5194/acp-25-18227-2025
- Atmospheric Wet Deposition in Remote Regions: Benchmarks for Environmental Change W. Keene et al. https://doi.org/10.1175/JAS-D-14-0378.1
- Formation mechanism and source apportionment of nitrate in atmospheric aerosols K. Xin et al. https://doi.org/10.30852/sb.2023.2225
- Factors That Modulate Properties of Primary Marine Aerosol Generated From Ambient Seawater on Ships at Sea W. Keene et al. https://doi.org/10.1002/2017JD026872
- Tropospheric ozone and its precursors from the urban to the global scale from air quality to short-lived climate forcer P. Monks et al. https://doi.org/10.5194/acp-15-8889-2015
- Christian Junge – a pioneer in global atmospheric chemistry R. Duce et al. https://doi.org/10.1007/s10874-022-09437-0
- Sensitivity of tropospheric ozone to halogen chemistry in the chemistry–climate model LMDZ-INCA vNMHC C. Caram et al. https://doi.org/10.5194/gmd-16-4041-2023
- Tropospheric Halogen Chemistry: Sources, Cycling, and Impacts W. Simpson et al. https://doi.org/10.1021/cr5006638
- Consumption of reactive halogen species from sea-salt aerosol by secondary organic aerosol: slowing down the bromine explosion J. Buxmann et al. https://doi.org/10.1071/EN14226
- Enhanced ozone loss by active inorganic bromine chemistry in the tropical troposphere M. Le Breton et al. https://doi.org/10.1016/j.atmosenv.2017.02.003
- A global model of tropospheric chlorine chemistry: Organic versus inorganic sources and impact on methane oxidation R. Hossaini et al. https://doi.org/10.1002/2016JD025756
- Impact of Enhanced Ozone Deposition and Halogen Chemistry on Tropospheric Ozone over the Northern Hemisphere G. Sarwar et al. https://doi.org/10.1021/acs.est.5b01657
- Halogen chemistry reduces tropospheric O3 radiative forcing T. Sherwen et al. https://doi.org/10.5194/acp-17-1557-2017
- Stratospheric Injection of Brominated Very Short‐Lived Substances: Aircraft Observations in the Western Pacific and Representation in Global Models P. Wales et al. https://doi.org/10.1029/2017JD027978
- Importance of reactive halogens in the tropical marine atmosphere: a regional modelling study using WRF-Chem A. Badia et al. https://doi.org/10.5194/acp-19-3161-2019
- Active and widespread halogen chemistry in the tropical and subtropical free troposphere S. Wang et al. https://doi.org/10.1073/pnas.1505142112
- Influence of bromine and iodine chemistry on annual, seasonal, diurnal, and background ozone: CMAQ simulations over the Northern Hemisphere G. Sarwar et al. https://doi.org/10.1016/j.atmosenv.2019.06.020
- Global tropospheric halogen (Cl, Br, I) chemistry and its impact on oxidants X. Wang et al. https://doi.org/10.5194/acp-21-13973-2021
- Year‐round records of sea salt, gaseous, and particulate inorganic bromine in the atmospheric boundary layer at coastal (Dumont d'Urville) and central (Concordia) East Antarctic sites M. Legrand et al. https://doi.org/10.1002/2015JD024066
- The role of chlorine in global tropospheric chemistry X. Wang et al. https://doi.org/10.5194/acp-19-3981-2019
- Mercury oxidation from bromine chemistry in the free troposphere over the southeastern US S. Coburn et al. https://doi.org/10.5194/acp-16-3743-2016
- Global Observations of Tropospheric Bromine Monoxide (BrO) Columns From TROPOMI Y. Chen et al. https://doi.org/10.1029/2023JD039091
- Updating sea spray aerosol emissions in the Community Multiscale Air Quality (CMAQ) model version 5.0.2 B. Gantt et al. https://doi.org/10.5194/gmd-8-3733-2015
- Origins of aerosol chlorine during winter over north central Colorado, USA C. Jordan et al. https://doi.org/10.1002/2014JD022294
- Atmospheric Chemistry of CH3OCF2CHF2 E. Kjærgaard et al. https://doi.org/10.1021/acs.jpca.1c08973
- BrO and inferred Bry profiles over the western Pacific: relevance of inorganic bromine sources and a Bry minimum in the aged tropical tropopause layer T. Koenig et al. https://doi.org/10.5194/acp-17-15245-2017
- CAPRAM reduction towards an operational multiphase halogen and dimethyl sulfide chemistry treatment in the chemistry transport model COSMO-MUSCAT(5.04e) E. Hoffmann et al. https://doi.org/10.5194/gmd-13-2587-2020
- Paleo-Perspectives on Potential Future Changes in the Oxidative Capacity of the Atmosphere Due to Climate Change and Anthropogenic Emissions B. Alexander & L. Mickley https://doi.org/10.1007/s40726-015-0006-0
- Microphysics of the aqueous bulk counters the water activity driven rate acceleration of bromide oxidation by ozone from 289–245 K J. Edebeli et al. https://doi.org/10.1039/C8EM00417J
- First direct observation of sea salt aerosol production from blowing snow above sea ice M. Frey et al. https://doi.org/10.5194/acp-20-2549-2020
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