Articles | Volume 14, issue 24
https://doi.org/10.5194/acp-14-13601-2014
© Author(s) 2014. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/acp-14-13601-2014
© Author(s) 2014. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
A physically based framework for modeling the organic fractionation of sea spray aerosol from bubble film Langmuir equilibria
S. M. Burrows
Atmospheric Science and Global Change Division, Pacific Northwest National Laboratory, Richland, Washington, USA
O. Ogunro
Ocean and Atmospheric Chemistry, Department of Chemistry, New Mexico Institute of Mining and Technology, Socorro, New Mexico
A. A. Frossard
Scripps Institution of Oceanography, University of California, San Diego, La Jolla, California, USA
L. M. Russell
Scripps Institution of Oceanography, University of California, San Diego, La Jolla, California, USA
P. J. Rasch
Atmospheric Science and Global Change Division, Pacific Northwest National Laboratory, Richland, Washington, USA
S. M. Elliott
Climate Ocean Sea Ice Modeling team, Computational Physics and Methods group, Los Alamos National Laboratory, Los Alamos, New Mexico, USA
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123 citations as recorded by crossref.
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117 citations as recorded by crossref.
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- Selectivity Across the Interface: A Test of Surface Activity in the Composition of Organic-Enriched Aerosols from Bubble Bursting R. Cochran et al. 10.1021/acs.jpclett.6b00489
- Compound jetting from bubble bursting at an air-oil-water interface B. Ji et al. 10.1038/s41467-021-26382-w
- Roles of marine biota in the formation of atmospheric bioaerosols, cloud condensation nuclei, and ice-nucleating particles over the North Pacific Ocean, Bering Sea, and Arctic Ocean K. Kawana et al. 10.5194/acp-24-1777-2024
- Secondary Organic Aerosol Formation Regulates Cloud Condensation Nuclei in the Global Remote Troposphere M. Liu & H. Matsui 10.1029/2022GL100543
- New index of organic mass enrichment in sea spray aerosols linked with senescent status in marine phytoplankton Y. Miyazaki et al. 10.1038/s41598-020-73718-5
- Regeneration of PFOS loaded activated carbon by hot water and subsequent aeration enrichment of PFOS from eluent W. Wang et al. 10.1016/j.carbon.2018.04.005
- Influence of Water Concentrations of Perfluoroalkyl Acids (PFAAs) on Their Size-Resolved Enrichment in Nascent Sea Spray Aerosols B. Sha et al. 10.1021/acs.est.0c03804
- Sea Spray Aerosols Contain the Major Component of Human Lung Surfactant E. Van Acker et al. 10.1021/acs.est.1c04075
- The influence of marine microbial activities on aerosol production: A laboratory mesocosm study P. Alpert et al. 10.1002/2015JD023469
- Concerted measurements of lipids in seawater and on submicrometer aerosol particles at the Cabo Verde islands: biogenic sources, selective transfer and high enrichments N. Triesch et al. 10.5194/acp-21-4267-2021
- Probing the impact of a phytoplankton bloom on the chemistry of nascent sea spray aerosol using high-resolution mass spectrometry N. Radoman et al. 10.1039/D2EA00028H
- Untangling the influence of Antarctic and Southern Ocean life on clouds M. Mallet et al. 10.1525/elementa.2022.00130
- Collapse Mechanisms of Nascent and Aged Sea Spray Aerosol Proxy Films K. Carter-Fenk & H. Allen 10.3390/atmos9120503
- Discriminating Abiotic and Biotic Fingerprints of Amino Acids and Fatty Acids in Ice Grains Relevant to Ocean Worlds F. Klenner et al. 10.1089/ast.2019.2188
- Ocean Biogeochemistry in GFDL's Earth System Model 4.1 and Its Response to Increasing Atmospheric CO2 C. Stock et al. 10.1029/2019MS002043
- Implementing marine organic aerosols into the GEOS-Chem model B. Gantt et al. 10.5194/gmd-8-619-2015
- Surface pKa of octanoic, nonanoic, and decanoic fatty acids at the air–water interface: applications to atmospheric aerosol chemistry B. Wellen et al. 10.1039/C7CP04527A
- Measurement report: Summertime fluorescence characteristics of atmospheric water-soluble organic carbon in the marine boundary layer of the western Arctic Ocean J. Jung et al. 10.5194/acp-23-4663-2023
- Water-to-Air Transfer of Nano/Microsized Particulates: Enrichment Effect in Bubble Bursting Jet Drops B. Ji et al. 10.1021/acs.nanolett.2c01102
- Evaluating Uncertainties in Marine Biogeochemical Models: Benchmarking Aerosol Precursors O. Ogunro et al. 10.3390/atmos9050184
- Influence of open ocean biogeochemistry on aerosol and clouds: Recent findings and perspectives K. Sellegri et al. 10.1525/elementa.2023.00058
- Representations of Precipitation Diurnal Cycle in the Amazon as Simulated by Observationally Constrained Cloud‐System Resolving and Global Climate Models S. Tai et al. 10.1029/2021MS002586
- The Science Case for a Return to Enceladus M. Cable et al. 10.3847/PSJ/abfb7a
- A Molecular Scale Investigation of Organic/Inorganic Ion Selectivity at the Air–Liquid Interface O. Ozgurel et al. 10.1021/acsearthspacechem.1c00394
- Phycotoxin-Enriched Sea Spray Aerosols: Methods, Mechanisms, and Human Exposure E. Van Acker et al. 10.1021/acs.est.1c00995
- Marine Aerosols and Clouds S. Brooks & D. Thornton 10.1146/annurev-marine-121916-063148
- Isotopic Insights into Organic Composition Differences between Supermicron and Submicron Sea Spray Aerosol D. Crocker et al. 10.1021/acs.est.2c02154
- Factors controlling the transfer of biogenic organic species from seawater to sea spray aerosol M. Santander et al. 10.1038/s41598-022-07335-9
- Multiphase Chemistry at the Atmosphere–Biosphere Interface Influencing Climate and Public Health in the Anthropocene U. Pöschl & M. Shiraiwa 10.1021/cr500487s
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Short summary
The air over the ocean is full of sea spray particles ejected by bubbles that burst in the wake of breaking waves. The smallest of such particles, less than a micrometer in diameter, include organic matter derived from ocean biota. This paper introduces a method to calculate the chemical composition of spray particles. Ocean organic matter is divided into several classes using a global model. Basic chemistry relationships predict the amount of organic material in emitted spray.
The air over the ocean is full of sea spray particles ejected by bubbles that burst in the wake...
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