Articles | Volume 14, issue 22
https://doi.org/10.5194/acp-14-12455-2014
© Author(s) 2014. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/acp-14-12455-2014
© Author(s) 2014. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Modeling of gaseous methylamines in the global atmosphere: impacts of oxidation and aerosol uptake
Atmospheric Sciences Research Center, State University of New York, 251 Fuller Road, Albany, New York 12203, USA
Atmospheric Sciences Research Center, State University of New York, 251 Fuller Road, Albany, New York 12203, USA
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Cited
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- Theoretical Study of the Gaseous Hydrolysis of NO2 in the Presence of Amines C. He et al. 10.1021/acs.jpca.6b08305
- Observations of Gas-Phase Alkylamines at a Coastal Site in the East Mediterranean Atmosphere E. Tzitzikalaki et al. 10.3390/atmos12111454
- Competitive Uptake of Dimethylamine and Trimethylamine against Ammonia on Acidic Particles in Marine Atmospheres D. Chen et al. 10.1021/acs.est.1c08713
- Reducing chemical complexity in representation of new-particle formation: evaluation of simplification approaches T. Olenius et al. 10.1039/D2EA00174H
- Significant contributions of trimethylamine to sulfuric acid nucleation in polluted environments R. Cai et al. 10.1038/s41612-023-00405-3
- Effect of Humidity on the Reactive Uptake of Ammonia and Dimethylamine by Nitrogen-Containing Secondary Organic Aerosol N. Smith et al. 10.3390/atmos12111502
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64 citations as recorded by crossref.
- Quantum chemical modeling of atmospheric molecular clusters involving inorganic acids and methanesulfonic acid M. Engsvang et al. 10.1063/5.0152517
- New Particle Formation in the Atmosphere: From Molecular Clusters to Global Climate S. Lee et al. 10.1029/2018JD029356
- Mapping gaseous dimethylamine, trimethylamine, ammonia, and their particulate counterparts in marine atmospheres of China’s marginal seas – Part 2: Spatiotemporal heterogeneity, causes, and hypothesis Y. Gao et al. 10.5194/acp-22-1515-2022
- Emissions of intermediate-volatility and semi-volatile organic compounds from domestic fuels used in Delhi, India G. Stewart et al. 10.5194/acp-21-2407-2021
- Characteristics and potential source areas of aliphatic amines in PM2.5 in Yangzhou, China G. Cheng et al. 10.1016/j.apr.2019.11.002
- Ideas and perspectives: on the emission of amines from terrestrial vegetation in the context of new atmospheric particle formation J. Sintermann & A. Neftel 10.5194/bg-12-3225-2015
- Mechanism for Rapid Conversion of Amines to Ammonium Salts at the Air–Particle Interface W. Zhang et al. 10.1021/jacs.0c12207
- Investigation of the liquid-vapour interface of aqueous methylamine solutions by computer simulation methods R. Horváth et al. 10.1016/j.molliq.2019.110978
- Impacts of Future European Emission Reductions on Aerosol Particle Number Concentrations Accounting for Effects of Ammonia, Amines, and Organic Species J. Julin et al. 10.1021/acs.est.7b05122
- Nitric Acid and Organic Acids Suppress the Role of Methanesulfonic Acid in Atmospheric New Particle Formation Y. Knattrup et al. 10.1021/acs.jpca.3c04393
- Adsorption of Methylamine on Amorphous Ice under Interstellar Conditions. A Grand Canonical Monte Carlo Simulation Study R. Horváth et al. 10.1021/acs.jpca.8b01591
- Molecular analysis of secondary organic aerosol and brown carbon from the oxidation of indole F. Jiang et al. 10.5194/acp-24-2639-2024
- The driving effects of common atmospheric molecules for formation of prenucleation clusters: the case of sulfuric acid, formic acid, nitric acid, ammonia, and dimethyl amine C. Bready et al. 10.1039/D2EA00087C
- Atmospheric Bases-Enhanced Iodic Acid Nucleation: Altitude-Dependent Characteristics and Molecular Mechanisms J. Li et al. 10.1021/acs.est.4c06053
- Isocyanic acid (HNCO) and its fate in the atmosphere: a review M. Leslie et al. 10.1039/C9EM00003H
- The critical role of dimethylamine in the rapid formation of iodic acid particles in marine areas A. Ning et al. 10.1038/s41612-022-00316-9
- Rapid iodine oxoacid nucleation enhanced by dimethylamine in broad marine regions H. Zu et al. 10.5194/acp-24-5823-2024
- A new advance in the pollution profile, transformation process, and contribution to aerosol formation and aging of atmospheric amines X. Shen et al. 10.1039/D2EA00167E
- Mapping gaseous dimethylamine, trimethylamine, ammonia, and their particulate counterparts in marine atmospheres of China's marginal seas – Part 1: Differentiating marine emission from continental transport D. Chen et al. 10.5194/acp-21-16413-2021
- Rapid sulfuric acid–dimethylamine nucleation enhanced by nitric acid in polluted regions L. Liu et al. 10.1073/pnas.2108384118
- A systematic review of reactive nitrogen simulations with chemical transport models in China H. Zhang et al. 10.1016/j.atmosres.2024.107586
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- Characterization of biomass burning emissions from cooking fires, peat, crop residue, and other fuels with high-resolution proton-transfer-reaction time-of-flight mass spectrometry C. Stockwell et al. 10.5194/acp-15-845-2015
- Measurement report: Insights into the chemical composition and origin of molecular clusters and potential precursor molecules present in the free troposphere over the southern Indian Ocean: observations from the Maïdo Observatory (2150 m a.s.l., Réunion) R. Salignat et al. 10.5194/acp-24-3785-2024
- Cooling radiative forcing effect enhancement of atmospheric amines and mineral particles caused by heterogeneous uptake and oxidation W. Zhang et al. 10.5194/acp-24-9019-2024
- Seasonal variation of fine- and coarse-mode nitrates and related aerosols over East Asia: synergetic observations and chemical transport model analysis I. Uno et al. 10.5194/acp-17-14181-2017
- Molecular-scale simulations of organic compounds on ice: application to atmospheric and interstellar sciences S. Picaud & P. Jedlovszky 10.1080/08927022.2018.1502428
- Enhancing Potential of Trimethylamine Oxide on Atmospheric Particle Formation N. Myllys et al. 10.3390/atmos11010035
- Overlooked significance of iodic acid in new particle formation in the continental atmosphere A. Ning et al. 10.1073/pnas.2404595121
- New Particle Formation and Growth Mechanisms in Highly Polluted Environments H. Yu et al. 10.1007/s40726-017-0067-3
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- Global variability in atmospheric new particle formation mechanisms B. Zhao et al. 10.1038/s41586-024-07547-1
- Atmospheric oxidation mechanism and kinetics of indole initiated by ●OH and ●Cl: a computational study J. Xue et al. 10.5194/acp-22-11543-2022
- Adsorption of Methylamine at the Surface of Ice. A Grand Canonical Monte Carlo Simulation Study V. Szentirmai et al. 10.1021/acs.jpcc.6b05863
- Size‐Resolved Mixing States and Sources of Amine‐Containing Particles in the East China Sea Z. Liu et al. 10.1029/2020JD033162
- New particle formation (NPF) events in China urban clusters given by sever composite pollution background Q. Zhang et al. 10.1016/j.chemosphere.2020.127842
- The driving effects of common atmospheric molecules for formation of clusters: the case of sulfuric acid, formic acid, hydrochloric acid, ammonia, and dimethylamine O. Longsworth et al. 10.1039/D3EA00087G
- Catalytic effect of a single water molecule on the OH + CH2NH reaction M. Akbar Ali et al. 10.1039/C7CP07091H
- Causes and importance of new particle formation in the present‐day and preindustrial atmospheres H. Gordon et al. 10.1002/2017JD026844
- C1-C2 alkyl aminiums in urban aerosols: Insights from ambient and fuel combustion emission measurements in the Yangtze River Delta region of China W. Shen et al. 10.1016/j.envpol.2017.06.034
- Hygroscopic and phase transition properties of alkyl aminium sulfates at low relative humidities Y. Chu et al. 10.1039/C5CP02404H
- New Particle Formation from Methanesulfonic Acid and Amines/Ammonia as a Function of Temperature H. Chen & B. Finlayson-Pitts 10.1021/acs.est.6b04173
- High-resolution modeling of gaseous methylamines over a polluted region in China: source-dependent emissions and implications of spatial variations J. Mao et al. 10.5194/acp-18-7933-2018
- Piperazine Enhancing Sulfuric Acid-Based New Particle Formation: Implications for the Atmospheric Fate of Piperazine F. Ma et al. 10.1021/acs.est.9b02117
- Current state of aerosol nucleation parameterizations for air-quality and climate modeling K. Semeniuk & A. Dastoor 10.1016/j.atmosenv.2018.01.039
- Influence of atmospheric conditions on the role of trifluoroacetic acid in atmospheric sulfuric acid–dimethylamine nucleation L. Liu et al. 10.5194/acp-21-6221-2021
- Characteristics of dimethylaminium and trimethylaminium in atmospheric particles ranging from supermicron to nanometer sizes over eutrophic marginal seas of China and oligotrophic open oceans P. Yu et al. 10.1016/j.scitotenv.2016.07.114
- Amine Volatilization from Herbicide Salts: Implications for Herbicide Formulations and Atmospheric Chemistry A. Sharkey et al. 10.1021/acs.est.2c03740
- Characteristics and sources of aerosol aminiums over the eastern coast of China: insights from the integrated observations in a coastal city, adjacent island and surrounding marginal seas S. Zhou et al. 10.5194/acp-19-10447-2019
- Hygroscopic Characteristics of Alkylaminium Carboxylate Aerosols M. Gomez-Hernandez et al. 10.1021/acs.est.5b04691
- Global atmospheric particle formation from CERN CLOUD measurements E. Dunne et al. 10.1126/science.aaf2649
- Nonagricultural emissions enhance dimethylamine and modulate urban atmospheric nucleation Y. Chang et al. 10.1016/j.scib.2023.05.033
- Contribution of marine biological emissions to gaseous methylamines in the atmosphere: An emission inventory based on multi-source data sets Q. Zhang et al. 10.1016/j.scitotenv.2023.165285
- Discovery of a Potent Source of Gaseous Amines in Urban China Y. Chang et al. 10.1021/acs.estlett.1c00229
- Photodissociation dynamics of methylamine in the blue edge of the A-band. II. The NH2 + CH3 channel J. Cachón et al. 10.1063/5.0159855
- Changes in the new particle formation and shrinkage events of the atmospheric ions during the COVID-19 lockdown A. Kamra et al. 10.1016/j.uclim.2022.101214
- Computational studies on the gas phase reaction of methylenimine (CH2NH) with water molecules M. Ali 10.1038/s41598-020-67515-3
- Theoretical Study of the Gaseous Hydrolysis of NO2 in the Presence of Amines C. He et al. 10.1021/acs.jpca.6b08305
- Observations of Gas-Phase Alkylamines at a Coastal Site in the East Mediterranean Atmosphere E. Tzitzikalaki et al. 10.3390/atmos12111454
- Competitive Uptake of Dimethylamine and Trimethylamine against Ammonia on Acidic Particles in Marine Atmospheres D. Chen et al. 10.1021/acs.est.1c08713
- Reducing chemical complexity in representation of new-particle formation: evaluation of simplification approaches T. Olenius et al. 10.1039/D2EA00174H
- Significant contributions of trimethylamine to sulfuric acid nucleation in polluted environments R. Cai et al. 10.1038/s41612-023-00405-3
- Effect of Humidity on the Reactive Uptake of Ammonia and Dimethylamine by Nitrogen-Containing Secondary Organic Aerosol N. Smith et al. 10.3390/atmos12111502
- Emissions of non-methane volatile organic compounds from combustion of domestic fuels in Delhi, India G. Stewart et al. 10.5194/acp-21-2383-2021
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Latest update: 11 Dec 2024
Short summary
Global lifetimes and concentrations of gaseous methylamines (MMA, DMA, and TMA) have been simulated.
Oxidation and aerosol uptakes are dominant sinks for these methylamines. The oxidation alone leads to their lifetimes of 5-10h in most parts of low and middle latitude regions. The uptake by secondary species can shorten their lifetime to as low as 1-2h over central Europe, eastern Asia, and the eastern US.
The modeled concentrations are substantially lower than observed values available.
Global lifetimes and concentrations of gaseous methylamines (MMA, DMA, and TMA) have been...
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