Articles | Volume 12, issue 16
https://doi.org/10.5194/acp-12-7499-2012
© Author(s) 2012. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/acp-12-7499-2012
© Author(s) 2012. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Research article
| 
17 Aug 2012
Research article |
| 17 Aug 2012
Peroxy radical chemistry and OH radical production during the NO3-initiated oxidation of isoprene
A. J. Kwan
Division of Engineering and Applied Science, California Institute of Technology, Pasadena, CA 91125, USA
now at: Energy Storage Division, NEXT ENERGY EWE-Forschungszentrum für Energietechnologie e.V., 26129 Oldenburg, Germany
soon at (September 2012): United States Agency for International Development, Washington, DC, 20523 USA
A. W. H. Chan
Division of Chemistry and Chemical Engineering, California Institute of Technology, Pasadena, CA 91125, USA
now at: Department of Environmental Science, Policy, and Management, University of California, Berkeley, Berkeley, CA 94720, USA
N. L. Ng
Division of Chemistry and Chemical Engineering, California Institute of Technology, Pasadena, CA 91125, USA
now at: School of Chemical and Biomolecular Engineering and School of Earth and Atmospheric Sciences, Georgia Institute of Technology, Atlanta, GA 30332, USA
H. G. Kjaergaard
Copenhagen Center for Atmospheric Chemistry, Department of Chemistry, University of Copenhagen, 2100 Copenhagen Ø, Denmark
J. H. Seinfeld
Division of Engineering and Applied Science, California Institute of Technology, Pasadena, CA 91125, USA
Division of Chemistry and Chemical Engineering, California Institute of Technology, Pasadena, CA 91125, USA
P. O. Wennberg
Division of Engineering and Applied Science, California Institute of Technology, Pasadena, CA 91125, USA
Division of Geology and Planetary Sciences, California Institute of Technology, Pasadena, CA 91125, USA
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Cited
56 citations as recorded by crossref.
- A Four Carbon Organonitrate as a Significant Product of Secondary Isoprene Chemistry E. Tsiligiannis et al. 10.1029/2021GL097366
- Photochemical degradation of isoprene-derived 4,1-nitrooxy enal F. Xiong et al. 10.5194/acp-16-5595-2016
- Impact of ozone and inlet design on the quantification of isoprene-derived organic nitrates by thermal dissociation cavity ring-down spectroscopy (TD-CRDS) P. Dewald et al. 10.5194/amt-14-5501-2021
- Experimental and theoretical study on the impact of a nitrate group on the chemistry of alkoxy radicals A. Novelli et al. 10.1039/D0CP05555G
- Importance of Oxidants and Temperature in the Formation of Biogenic Organosulfates and Nitrooxy Organosulfates D. Bryant et al. 10.1021/acsearthspacechem.1c00204
- Formation of condensable organic vapors from anthropogenic and biogenic volatile organic compounds (VOCs) is strongly perturbed by NO<sub><i>x</i></sub> in eastern China Y. Liu et al. 10.5194/acp-21-14789-2021
- Effects of Chemical Complexity on the Autoxidation Mechanisms of Endocyclic Alkene Ozonolysis Products: From Methylcyclohexenes toward Understanding α-Pinene M. Rissanen et al. 10.1021/jp510966g
- Organic Peroxides in Aerosol: Key Reactive Intermediates for Multiphase Processes in the Atmosphere S. Wang et al. 10.1021/acs.chemrev.2c00430
- Overview of the Focused Isoprene eXperiment at the California Institute of Technology (FIXCIT): mechanistic chamber studies on the oxidation of biogenic compounds T. Nguyen et al. 10.5194/acp-14-13531-2014
- Gas-Phase Reactions of Isoprene and Its Major Oxidation Products P. Wennberg et al. 10.1021/acs.chemrev.7b00439
- Secondary organic aerosol from chlorine-initiated oxidation of isoprene D. Wang & L. Ruiz 10.5194/acp-17-13491-2017
- A comprehensive organic nitrate chemistry: insights into the lifetime of atmospheric organic nitrates A. Zare et al. 10.5194/acp-18-15419-2018
- Secondary Organic Aerosol Mass Yields from NO3 Oxidation of α-Pinene and Δ-Carene: Effect of RO2 Radical Fate D. Day et al. 10.1021/acs.jpca.2c04419
- Accretion product formation in the self-reaction of ethene-derived hydroxy peroxy radicals S. Murphy et al. 10.1039/D3EA00020F
- Nitrate radicals and biogenic volatile organic compounds: oxidation, mechanisms, and organic aerosol N. Ng et al. 10.5194/acp-17-2103-2017
- Effects of NO x on the molecular composition of secondary organic aerosol formed by the ozonolysis and photooxidation of α-pinene J. Park et al. 10.1016/j.atmosenv.2017.07.022
- Vapor-Pressure Pathways Initiate but Hydrolysis Products Dominate the Aerosol Estimated from Organic Nitrates A. Zare et al. 10.1021/acsearthspacechem.9b00067
- Comprehensive isoprene and terpene gas-phase chemistry improves simulated surface ozone in the southeastern US R. Schwantes et al. 10.5194/acp-20-3739-2020
- Concurrent dominant pathways of multifunctional products formed from nocturnal isoprene oxidation H. Li et al. 10.1016/j.chemosphere.2023.138185
- Effect of NO2 on nocturnal chemistry of isoprene: Gaseous oxygenated products and secondary organic aerosol formation Y. Chen et al. 10.1016/j.scitotenv.2022.156908
- In Situ Observation of Multiphase Oxidation-Driven Secondary Organic Aerosol Formation during Cloud Processing at a Mountain Site in Southern China M. Gao et al. 10.1021/acs.estlett.3c00331
- Products and Mechanism of the Reaction of 1-Pentadecene with NO3 Radicals and the Effect of a −ONO2 Group on Alkoxy Radical Decomposition G. Yeh et al. 10.1021/acs.jpca.5b07468
- Investigation of the formation of benzoyl peroxide, benzoic anhydride, and other potential aerosol products from gas–phase reactions of benzoylperoxy radicals C. Strollo & P. Ziemann 10.1016/j.atmosenv.2016.01.011
- Identification and semi-quantification of biogenic organic nitrates in ambient particulate matters by UHPLC/ESI-MS R. Li et al. 10.1016/j.atmosenv.2017.12.038
- Nocturnal atmospheric chemistry of NO3 and N2O5 over Changzhou in the Yangtze River Delta in China C. Lin et al. 10.1016/j.jes.2021.09.016
- Night-time atmospheric degradation of a series of butyl methacrylates M. Teruel et al. 10.1016/j.cplett.2016.09.040
- Observation of isoprene hydroxynitrates in the southeastern United States and implications for the fate of NO<sub><i>x</i></sub> F. Xiong et al. 10.5194/acp-15-11257-2015
- Theoretical Study of Isoprene Dissociative Photoionization Q. Ma et al. 10.1063/1674-0068/30/cjcp1606131
- On Rates and Mechanisms of OH and O3 Reactions with Isoprene-Derived Hydroxy Nitrates L. Lee et al. 10.1021/jp4107603
- Secondary Organic Aerosol Formation from Reaction of 3-Methylfuran with Nitrate Radicals T. Joo et al. 10.1021/acsearthspacechem.9b00068
- Comparison of isoprene chemical mechanisms under atmospheric night-time conditions in chamber experiments: evidence of hydroperoxy aldehydes and epoxy products from NO3 oxidation P. Carlsson et al. 10.5194/acp-23-3147-2023
- Isoprene NO3 Oxidation Products from the RO2 + HO2 Pathway R. Schwantes et al. 10.1021/acs.jpca.5b06355
- Gas-Particle Partitioning and SOA Yields of Organonitrate Products from NO3-Initiated Oxidation of Isoprene under Varied Chemical Regimes B. Brownwood et al. 10.1021/acsearthspacechem.0c00311
- Characteristics of fresh and aged volatile organic compounds from open burning of crop residues X. Niu et al. 10.1016/j.scitotenv.2020.138545
- A large source of low-volatility secondary organic aerosol M. Ehn et al. 10.1038/nature13032
- Key Role of NO3 Radicals in the Production of Isoprene Nitrates and Nitrooxyorganosulfates in Beijing J. Hamilton et al. 10.1021/acs.est.0c05689
- Theoretical and experimental study of peroxy and alkoxy radicals in the NO3-initiated oxidation of isoprene L. Vereecken et al. 10.1039/D0CP06267G
- Ozone and organic nitrates over the eastern United States: Sensitivity to isoprene chemistry J. Mao et al. 10.1002/jgrd.50817
- Observations of total RONO<sub>2</sub> over the boreal forest: NO<sub>x</sub> sinks and HNO<sub>3</sub> sources E. Browne et al. 10.5194/acp-13-4543-2013
- Variability in Aromatic Aerosol Yields under Very Low NOxConditions at Different HO2/RO2Regimes W. Peng et al. 10.1021/acs.est.1c04392
- Molecular composition and volatility of multi-generation products formed from isoprene oxidation by nitrate radical R. Wu et al. 10.5194/acp-21-10799-2021
- Chemistry and deposition in the Model of Atmospheric composition at Global and Regional scales using Inversion Techniques for Trace gas Emissions (MAGRITTE v1.1) – Part 1: Chemical mechanism J. Müller et al. 10.5194/gmd-12-2307-2019
- Volatile isoprenoids and their importance for protection against environmental constraints in the Mediterranean area F. Loreto et al. 10.1016/j.envexpbot.2013.09.005
- Secondary Organic Aerosol (SOA) from Nitrate Radical Oxidation of Monoterpenes: Effects of Temperature, Dilution, and Humidity on Aerosol Formation, Mixing, and Evaporation C. Boyd et al. 10.1021/acs.est.7b01460
- Efficient HOx Radical Production from Isoprene Nighttime Chemistry Z. Moo et al. 10.1021/acsearthspacechem.3c00323
- A review of secondary organic aerosols formation focusing on organosulfates and organic nitrates W. Fan et al. 10.1016/j.jhazmat.2022.128406
- Secondary organic aerosol formation from the β-pinene+NO<sub>3</sub> system: effect of humidity and peroxy radical fate C. Boyd et al. 10.5194/acp-15-7497-2015
- Southeast Atmosphere Studies: learning from model-observation syntheses J. Mao et al. 10.5194/acp-18-2615-2018
- Importance of secondary organic aerosol formation of <i>α</i>-pinene, limonene, and <i>m</i>-cresol comparing day- and nighttime radical chemistry A. Mutzel et al. 10.5194/acp-21-8479-2021
- Fast photolysis of carbonyl nitrates from isoprene J. Müller et al. 10.5194/acp-14-2497-2014
- Photochemical reactions of 1,3-butadiene with nitrogen oxide in different matrices: Kinetic behavior, humidity effect, product and mechanisms Q. Wang et al. 10.1016/j.scitotenv.2020.137747
- Chemical Amplification - Cavity Attenuated Phase Shift Spectroscopy Measurements of Atmospheric Peroxy Radicals E. Wood & J. Charest 10.1021/ac502451m
- Key chemical NO<sub>x</sub> sink uncertainties and how they influence top-down emissions of nitrogen oxides T. Stavrakou et al. 10.5194/acp-13-9057-2013
- Highly oxygenated organic molecule (HOM) formation in the isoprene oxidation by NO<sub>3</sub> radical D. Zhao et al. 10.5194/acp-21-9681-2021
- Determination of Semivolatile Organic Nitrates in Ambient Atmosphere by Gas Chromatography/Electron Ionization–Mass Spectrometry R. Li et al. 10.3390/atmos10020088
- Understanding the impact of recent advances in isoprene photooxidation on simulations of regional air quality Y. Xie et al. 10.5194/acp-13-8439-2013
54 citations as recorded by crossref.
- A Four Carbon Organonitrate as a Significant Product of Secondary Isoprene Chemistry E. Tsiligiannis et al. 10.1029/2021GL097366
- Photochemical degradation of isoprene-derived 4,1-nitrooxy enal F. Xiong et al. 10.5194/acp-16-5595-2016
- Impact of ozone and inlet design on the quantification of isoprene-derived organic nitrates by thermal dissociation cavity ring-down spectroscopy (TD-CRDS) P. Dewald et al. 10.5194/amt-14-5501-2021
- Experimental and theoretical study on the impact of a nitrate group on the chemistry of alkoxy radicals A. Novelli et al. 10.1039/D0CP05555G
- Importance of Oxidants and Temperature in the Formation of Biogenic Organosulfates and Nitrooxy Organosulfates D. Bryant et al. 10.1021/acsearthspacechem.1c00204
- Formation of condensable organic vapors from anthropogenic and biogenic volatile organic compounds (VOCs) is strongly perturbed by NO<sub><i>x</i></sub> in eastern China Y. Liu et al. 10.5194/acp-21-14789-2021
- Effects of Chemical Complexity on the Autoxidation Mechanisms of Endocyclic Alkene Ozonolysis Products: From Methylcyclohexenes toward Understanding α-Pinene M. Rissanen et al. 10.1021/jp510966g
- Organic Peroxides in Aerosol: Key Reactive Intermediates for Multiphase Processes in the Atmosphere S. Wang et al. 10.1021/acs.chemrev.2c00430
- Overview of the Focused Isoprene eXperiment at the California Institute of Technology (FIXCIT): mechanistic chamber studies on the oxidation of biogenic compounds T. Nguyen et al. 10.5194/acp-14-13531-2014
- Gas-Phase Reactions of Isoprene and Its Major Oxidation Products P. Wennberg et al. 10.1021/acs.chemrev.7b00439
- Secondary organic aerosol from chlorine-initiated oxidation of isoprene D. Wang & L. Ruiz 10.5194/acp-17-13491-2017
- A comprehensive organic nitrate chemistry: insights into the lifetime of atmospheric organic nitrates A. Zare et al. 10.5194/acp-18-15419-2018
- Secondary Organic Aerosol Mass Yields from NO3 Oxidation of α-Pinene and Δ-Carene: Effect of RO2 Radical Fate D. Day et al. 10.1021/acs.jpca.2c04419
- Accretion product formation in the self-reaction of ethene-derived hydroxy peroxy radicals S. Murphy et al. 10.1039/D3EA00020F
- Nitrate radicals and biogenic volatile organic compounds: oxidation, mechanisms, and organic aerosol N. Ng et al. 10.5194/acp-17-2103-2017
- Effects of NO x on the molecular composition of secondary organic aerosol formed by the ozonolysis and photooxidation of α-pinene J. Park et al. 10.1016/j.atmosenv.2017.07.022
- Vapor-Pressure Pathways Initiate but Hydrolysis Products Dominate the Aerosol Estimated from Organic Nitrates A. Zare et al. 10.1021/acsearthspacechem.9b00067
- Comprehensive isoprene and terpene gas-phase chemistry improves simulated surface ozone in the southeastern US R. Schwantes et al. 10.5194/acp-20-3739-2020
- Concurrent dominant pathways of multifunctional products formed from nocturnal isoprene oxidation H. Li et al. 10.1016/j.chemosphere.2023.138185
- Effect of NO2 on nocturnal chemistry of isoprene: Gaseous oxygenated products and secondary organic aerosol formation Y. Chen et al. 10.1016/j.scitotenv.2022.156908
- In Situ Observation of Multiphase Oxidation-Driven Secondary Organic Aerosol Formation during Cloud Processing at a Mountain Site in Southern China M. Gao et al. 10.1021/acs.estlett.3c00331
- Products and Mechanism of the Reaction of 1-Pentadecene with NO3 Radicals and the Effect of a −ONO2 Group on Alkoxy Radical Decomposition G. Yeh et al. 10.1021/acs.jpca.5b07468
- Investigation of the formation of benzoyl peroxide, benzoic anhydride, and other potential aerosol products from gas–phase reactions of benzoylperoxy radicals C. Strollo & P. Ziemann 10.1016/j.atmosenv.2016.01.011
- Identification and semi-quantification of biogenic organic nitrates in ambient particulate matters by UHPLC/ESI-MS R. Li et al. 10.1016/j.atmosenv.2017.12.038
- Nocturnal atmospheric chemistry of NO3 and N2O5 over Changzhou in the Yangtze River Delta in China C. Lin et al. 10.1016/j.jes.2021.09.016
- Night-time atmospheric degradation of a series of butyl methacrylates M. Teruel et al. 10.1016/j.cplett.2016.09.040
- Observation of isoprene hydroxynitrates in the southeastern United States and implications for the fate of NO<sub><i>x</i></sub> F. Xiong et al. 10.5194/acp-15-11257-2015
- Theoretical Study of Isoprene Dissociative Photoionization Q. Ma et al. 10.1063/1674-0068/30/cjcp1606131
- On Rates and Mechanisms of OH and O3 Reactions with Isoprene-Derived Hydroxy Nitrates L. Lee et al. 10.1021/jp4107603
- Secondary Organic Aerosol Formation from Reaction of 3-Methylfuran with Nitrate Radicals T. Joo et al. 10.1021/acsearthspacechem.9b00068
- Comparison of isoprene chemical mechanisms under atmospheric night-time conditions in chamber experiments: evidence of hydroperoxy aldehydes and epoxy products from NO3 oxidation P. Carlsson et al. 10.5194/acp-23-3147-2023
- Isoprene NO3 Oxidation Products from the RO2 + HO2 Pathway R. Schwantes et al. 10.1021/acs.jpca.5b06355
- Gas-Particle Partitioning and SOA Yields of Organonitrate Products from NO3-Initiated Oxidation of Isoprene under Varied Chemical Regimes B. Brownwood et al. 10.1021/acsearthspacechem.0c00311
- Characteristics of fresh and aged volatile organic compounds from open burning of crop residues X. Niu et al. 10.1016/j.scitotenv.2020.138545
- A large source of low-volatility secondary organic aerosol M. Ehn et al. 10.1038/nature13032
- Key Role of NO3 Radicals in the Production of Isoprene Nitrates and Nitrooxyorganosulfates in Beijing J. Hamilton et al. 10.1021/acs.est.0c05689
- Theoretical and experimental study of peroxy and alkoxy radicals in the NO3-initiated oxidation of isoprene L. Vereecken et al. 10.1039/D0CP06267G
- Ozone and organic nitrates over the eastern United States: Sensitivity to isoprene chemistry J. Mao et al. 10.1002/jgrd.50817
- Observations of total RONO<sub>2</sub> over the boreal forest: NO<sub>x</sub> sinks and HNO<sub>3</sub> sources E. Browne et al. 10.5194/acp-13-4543-2013
- Variability in Aromatic Aerosol Yields under Very Low NOxConditions at Different HO2/RO2Regimes W. Peng et al. 10.1021/acs.est.1c04392
- Molecular composition and volatility of multi-generation products formed from isoprene oxidation by nitrate radical R. Wu et al. 10.5194/acp-21-10799-2021
- Chemistry and deposition in the Model of Atmospheric composition at Global and Regional scales using Inversion Techniques for Trace gas Emissions (MAGRITTE v1.1) – Part 1: Chemical mechanism J. Müller et al. 10.5194/gmd-12-2307-2019
- Volatile isoprenoids and their importance for protection against environmental constraints in the Mediterranean area F. Loreto et al. 10.1016/j.envexpbot.2013.09.005
- Secondary Organic Aerosol (SOA) from Nitrate Radical Oxidation of Monoterpenes: Effects of Temperature, Dilution, and Humidity on Aerosol Formation, Mixing, and Evaporation C. Boyd et al. 10.1021/acs.est.7b01460
- Efficient HOx Radical Production from Isoprene Nighttime Chemistry Z. Moo et al. 10.1021/acsearthspacechem.3c00323
- A review of secondary organic aerosols formation focusing on organosulfates and organic nitrates W. Fan et al. 10.1016/j.jhazmat.2022.128406
- Secondary organic aerosol formation from the β-pinene+NO<sub>3</sub> system: effect of humidity and peroxy radical fate C. Boyd et al. 10.5194/acp-15-7497-2015
- Southeast Atmosphere Studies: learning from model-observation syntheses J. Mao et al. 10.5194/acp-18-2615-2018
- Importance of secondary organic aerosol formation of <i>α</i>-pinene, limonene, and <i>m</i>-cresol comparing day- and nighttime radical chemistry A. Mutzel et al. 10.5194/acp-21-8479-2021
- Fast photolysis of carbonyl nitrates from isoprene J. Müller et al. 10.5194/acp-14-2497-2014
- Photochemical reactions of 1,3-butadiene with nitrogen oxide in different matrices: Kinetic behavior, humidity effect, product and mechanisms Q. Wang et al. 10.1016/j.scitotenv.2020.137747
- Chemical Amplification - Cavity Attenuated Phase Shift Spectroscopy Measurements of Atmospheric Peroxy Radicals E. Wood & J. Charest 10.1021/ac502451m
- Key chemical NO<sub>x</sub> sink uncertainties and how they influence top-down emissions of nitrogen oxides T. Stavrakou et al. 10.5194/acp-13-9057-2013
- Highly oxygenated organic molecule (HOM) formation in the isoprene oxidation by NO<sub>3</sub> radical D. Zhao et al. 10.5194/acp-21-9681-2021
2 citations as recorded by crossref.
- Determination of Semivolatile Organic Nitrates in Ambient Atmosphere by Gas Chromatography/Electron Ionization–Mass Spectrometry R. Li et al. 10.3390/atmos10020088
- Understanding the impact of recent advances in isoprene photooxidation on simulations of regional air quality Y. Xie et al. 10.5194/acp-13-8439-2013
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