Articles | Volume 12, issue 24
https://doi.org/10.5194/acp-12-12227-2012
© Author(s) 2012. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/acp-12-12227-2012
© Author(s) 2012. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Research article
| 
21 Dec 2012
Research article |
| 21 Dec 2012
Surface/bulk partitioning and acid/base speciation of aqueous decanoate: direct observations and atmospheric implications
N. L. Prisle
University of Helsinki, Department of Physics, P.O. Box 48, 00014, University of Helsinki, Helsinki, Finland
N. Ottosson
University of Uppsala, Department of Physics and Astronomy, Box 516, 75120, Uppsala, Sweden
now at: FOM Institute AMOLF, Science Park 104, 1098 XG Amsterdam, The Netherlands
G. Öhrwall
University of Lund, MAX-lab, Box 118, 22100, Lund, Sweden
J. Söderström
University of Uppsala, Department of Physics and Astronomy, Box 516, 75120, Uppsala, Sweden
M. Dal Maso
University of Helsinki, Department of Physics, P.O. Box 48, 00014, University of Helsinki, Helsinki, Finland
O. Björneholm
University of Uppsala, Department of Physics and Astronomy, Box 516, 75120, Uppsala, Sweden
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- Surface pKa of octanoic, nonanoic, and decanoic fatty acids at the air–water interface: applications to atmospheric aerosol chemistry B. Wellen et al. 10.1039/C7CP04527A
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- Hygroscopicity of amino acids and their effect on the water uptake of ammonium sulfate in the mixed aerosol particles Q. Luo et al. 10.1016/j.scitotenv.2020.139318
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- Aqueous-phase aerosols on the air-water interface: Response of fatty acid Langmuir monolayers to atmospheric inorganic ions S. Li et al. 10.1016/j.scitotenv.2016.12.072
- A predictive thermodynamic framework of cloud droplet activation for chemically unresolved aerosol mixtures, including surface tension, non-ideality, and bulk–surface partitioning N. Prisle 10.5194/acp-21-16387-2021
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41 citations as recorded by crossref.
- Quantitative alignment parameter estimation for analyzing X-ray photoelectron spectra M. Ozon et al. 10.1107/S1600577523004150
- Surfactant effect on cloud condensation nuclei for two‐component internally mixed aerosols S. Petters & M. Petters 10.1002/2015JD024090
- Statistical Mechanics of Multilayer Sorption: Surface Concentration Modeling and XPS Measurement A. Toribio et al. 10.1021/acs.jpclett.8b00332
- Chemical Composition and Properties of the Liquid–Vapor Interface of Aqueous C1 to C4 Monofunctional Acid and Alcohol Solutions M. Lee et al. 10.1021/acs.jpca.6b09261
- Shifted equilibria of organic acids and bases in the aqueous surface region J. Werner et al. 10.1039/C8CP01898G
- Aqueous Ammonium Nitrate Investigated Using Photoelectron Spectroscopy of Cylindrical and Flat Liquid Jets T. Gallo et al. 10.1021/acs.jpcb.4c01755
- Inversion model for extracting chemically resolved depth profiles across liquid interfaces of various configurations from XPS data: PROPHESY M. Ozon et al. 10.1107/S1600577523006124
- Alcohols at the aqueous surface: chain length and isomer effects M. Walz et al. 10.1039/C5CP06463E
- Comparison of six approaches to predicting droplet activation of surface active aerosol – Part 1: moderately surface active organics S. Vepsäläinen et al. 10.5194/acp-22-2669-2022
- Surface pKa of Saturated Carboxylic Acids at the Air/Water Interface: A Quantum Chemical Approach Y. Vysotsky et al. 10.1021/acs.jpcc.0c03785
- Water-polyamide chemical interplay in desalination membranes explored by ambient pressure X-ray photoelectron spectroscopy S. Gericke et al. 10.1039/D0CP01842B
- Direct observation of the complex S(IV) equilibria at the liquid-vapor interface T. Buttersack et al. 10.1038/s41467-024-53186-5
- Solution chemistry in the surface region of aqueous solutions I. Persson et al. 10.1515/pac-2019-1106
- Surface behavior of amphiphiles in aqueous solution: a comparison between different pentanol isomers M. Walz et al. 10.1039/C5CP01870F
- In Situ Self‐Assembling Micellar Depots that Can Actively Trap and Passively Release NO with Long‐Lasting Activity to Reverse Osteoporosis Y. Lin et al. 10.1002/adma.201705605
- Propensity, free energy contributions and conformation of primary n-alcohols at a water surface V. Ekholm et al. 10.1039/D1CP02818A
- Effects of surface tension time-evolution for CCN activation of a complex organic surfactant J. Lin et al. 10.1039/C9EM00426B
- Pre-deliquescent water uptake in deposited nanoparticles observed with in situ ambient pressure X-ray photoelectron spectroscopy J. Lin et al. 10.5194/acp-21-4709-2021
- Surfaces of Atmospheric Droplet Models Probed with Synchrotron XPS on a Liquid Microjet N. Prisle 10.1021/acs.accounts.3c00201
- Impact of Tetrabutylammonium on the Oxidation of Bromide by Ozone S. Chen et al. 10.1021/acsearthspacechem.1c00233
- Surface pKa of octanoic, nonanoic, and decanoic fatty acids at the air–water interface: applications to atmospheric aerosol chemistry B. Wellen et al. 10.1039/C7CP04527A
- Succinic acid in aqueous solution: connecting microscopic surface composition and macroscopic surface tension J. Werner et al. 10.1039/C4CP02776K
- Comparison of six approaches to predicting droplet activation of surface active aerosol – Part 2: Strong surfactants S. Vepsäläinen et al. 10.5194/acp-23-15149-2023
- Strong enrichment of atmospherically relevant organic ions at the aqueous interface: the role of ion pairing and cooperative effects V. Ekholm et al. 10.1039/C8CP04525A
- Treatment of non-ideality in the SPACCIM multiphase model – Part 1: Model development A. Rusumdar et al. 10.5194/gmd-9-247-2016
- Description of surfactant 2D monolayer formation at the air/water interface within semiempirical quantum chemistry E. Kartashynska & D. Vollhardt 10.1016/j.jciso.2024.100110
- Effect of surface–bulk partitioning on the heterogeneous oxidation of aqueous saccharide aerosols H. Fan et al. 10.1039/C8CP06785F
- Hygroscopicity of amino acids and their effect on the water uptake of ammonium sulfate in the mixed aerosol particles Q. Luo et al. 10.1016/j.scitotenv.2020.139318
- Impact of acidity and surface-modulated acid dissociation on cloud response to organic aerosol G. Sengupta et al. 10.5194/acp-24-1467-2024
- A Monolayer Partitioning Scheme for Droplets of Surfactant Solutions J. Malila & N. Prisle 10.1029/2018MS001456
- Cloud droplet activation of organic–salt mixtures predicted from two model treatments of the droplet surface J. Lin et al. 10.1039/C8EM00345A
- Orcinol and resorcinol induce local ordering of water molecules near the liquid–vapor interface H. Yang et al. 10.1039/D2EA00015F
- Sodium–carboxylate contact ion pair formation induces stabilization of palmitic acid monolayers at high pH E. Adams et al. 10.1039/C7CP00167C
- Superficial Tale of Two Functional Groups: On the Surface Propensity of Aqueous Carboxylic Acids, Alkyl Amines, and Amino Acids O. Björneholm et al. 10.1021/acs.accounts.2c00494
- Screening of cloud microorganisms isolated at the Puy de Dôme (France) station for the production of biosurfactants P. Renard et al. 10.5194/acp-16-12347-2016
- Chemical equilibria of aqueous ammonium–carboxylate systems in aqueous bulk, close to and at the water–air interface Y. Blanco et al. 10.1039/C9CP02449B
- Core level photoelectron spectroscopy of heterogeneous reactions at liquid–vapor interfaces: Current status, challenges, and prospects R. Dupuy et al. 10.1063/5.0036178
- Surface modulated dissociation of organic aerosol acids and bases in different atmospheric environments G. Sengupta & N. Prisle 10.1080/02786826.2024.2323641
- Aqueous-phase aerosols on the air-water interface: Response of fatty acid Langmuir monolayers to atmospheric inorganic ions S. Li et al. 10.1016/j.scitotenv.2016.12.072
- A predictive thermodynamic framework of cloud droplet activation for chemically unresolved aerosol mixtures, including surface tension, non-ideality, and bulk–surface partitioning N. Prisle 10.5194/acp-21-16387-2021
- Photoelectron angular distributions as sensitive probes of surfactant layer structure at the liquid–vapor interface R. Dupuy et al. 10.1039/D1CP05621B
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