Assessing the near surface sensitivity of SCIAMACHY atmospheric CO₂ retrieved using (FSI) WFM-DOAS

Abstract. Satellite observations of atmospheric CO₂ offer the potential to identify regional carbon surface sources and sinks and to investigate carbon cycle processes. The extent to which satellite measurements are useful however, depends on the near surface sensitivity of the chosen sensor. In this paper, the capability of the SCIAMACHY instrument on board ENVISAT, to observe lower tropospheric and surface CO₂ variability is examined. To achieve this, atmospheric CO₂ retrieved from SCIAMACHY near infrared (NIR) spectral measurements, using the Full Spectral Initiation (FSI) WFM-DOAS algorithm, is compared to in-situ aircraft observations over Siberia and additionally to tower and surface CO₂ data over Mongolia, Europe and North America.

Preliminary validation of daily averaged SCIAMACHY/FSI CO₂ against ground based Fourier Transform Spectrometer (FTS) column measurements made at Park Falls, reveal a negative bias of about −2.0% for collocated measurements within ±1.0° of the site. However, at this spatial threshold SCIAMACHY can only capture the variability of the FTS observations at monthly timescales. To observe day to day variability of the FTS observations, the collocation limits must be increased. Furthermore, comparisons to in-situ CO₂ observations demonstrate that SCIAMACHY is capable of observing a seasonal signal that is representative of lower tropospheric variability on (at least) monthly timescales. Out of seventeen time series comparisons, eleven have correlation coefficients of 0.7 or more, and have similar seasonal cycle amplitudes. Additional evidence of the near surface sensitivity of SCIAMACHY, is provided through the significant correlation of FSI derived CO₂ with MODIS vegetation indices at over twenty selected locations in the United States. The SCIAMACHY/MODIS comparison reveals that at many of the sites, the amount of CO₂ variability is coincident with the amount of vegetation activity. The presented analysis suggests that SCIAMACHY has the potential to detect CO₂ variability within the lowermost troposphere arising from the activity of the terrestrial biosphere.