Articles | Volume 7, issue 12
https://doi.org/10.5194/acp-7-3055-2007
© Author(s) 2007. This work is licensed under
the Creative Commons Attribution-NonCommercial-ShareAlike 2.5 License.
the Creative Commons Attribution-NonCommercial-ShareAlike 2.5 License.
https://doi.org/10.5194/acp-7-3055-2007
© Author(s) 2007. This work is licensed under
the Creative Commons Attribution-NonCommercial-ShareAlike 2.5 License.
the Creative Commons Attribution-NonCommercial-ShareAlike 2.5 License.
15 Jun 2007
Understanding the kinetics of the ClO dimer cycle
M. von Hobe
Forschungszentrum Jülich GmbH, Institute for Chemistry and Dynamics of the Geosphere (ICG-1), Jülich, Germany
R. J. Salawitch
Jet Propulsion Laboratory, California Institute of Technology, Pasadena, California, USA
T. Canty
Jet Propulsion Laboratory, California Institute of Technology, Pasadena, California, USA
H. Keller-Rudek
Max-Planck-Institute for Chemistry, Atmospheric Chemistry Division, Mainz, Germany
G. K. Moortgat
Max-Planck-Institute for Chemistry, Atmospheric Chemistry Division, Mainz, Germany
J.-U. Grooß
Forschungszentrum Jülich GmbH, Institute for Chemistry and Dynamics of the Geosphere (ICG-1), Jülich, Germany
R. Müller
Forschungszentrum Jülich GmbH, Institute for Chemistry and Dynamics of the Geosphere (ICG-1), Jülich, Germany
F. Stroh
Forschungszentrum Jülich GmbH, Institute for Chemistry and Dynamics of the Geosphere (ICG-1), Jülich, Germany
Viewed
Total article views: 3,765 (including HTML, PDF, and XML)
Cumulative views and downloads
(calculated since 01 Feb 2013, article published on 14 Aug 2006)
| HTML | XML | Total | BibTeX | EndNote | |
|---|---|---|---|---|---|
| 1,994 | 1,576 | 195 | 3,765 | 204 | 188 |
- HTML: 1,994
- PDF: 1,576
- XML: 195
- Total: 3,765
- BibTeX: 204
- EndNote: 188
Total article views: 3,224 (including HTML, PDF, and XML)
Cumulative views and downloads
(calculated since 01 Feb 2013, article published on 15 Jun 2007)
| HTML | XML | Total | BibTeX | EndNote | |
|---|---|---|---|---|---|
| 1,737 | 1,309 | 178 | 3,224 | 175 | 176 |
- HTML: 1,737
- PDF: 1,309
- XML: 178
- Total: 3,224
- BibTeX: 175
- EndNote: 176
Total article views: 541 (including HTML, PDF, and XML)
Cumulative views and downloads
(calculated since 01 Feb 2013, article published on 14 Aug 2006)
| HTML | XML | Total | BibTeX | EndNote | |
|---|---|---|---|---|---|
| 257 | 267 | 17 | 541 | 29 | 12 |
- HTML: 257
- PDF: 267
- XML: 17
- Total: 541
- BibTeX: 29
- EndNote: 12
Cited
45 citations as recorded by crossref.
- Retrievals of chlorine chemistry kinetic parameters from Antarctic ClO microwave radiometer measurements S. Kremser et al. https://doi.org/10.5194/acp-11-5183-2011
- Comment on "Cosmic-ray-driven reaction and greenhouse effect of halogenated molecules: Culprits for atmospheric ozone depletion and global climate change" R. Müller & J. Grooß https://doi.org/10.1142/S0217979214820013
- Variability in Antarctic ozone loss in the last decade (2004–2013): high-resolution simulations compared to Aura MLS observations J. Kuttippurath et al. https://doi.org/10.5194/acp-15-10385-2015
- Do cosmic-ray-driven electron-induced reactions impact stratospheric ozone depletion and global climate change? J. Grooß & R. Müller https://doi.org/10.1016/j.atmosenv.2011.03.059
- Evaluation of simulated photolysis rates and their response to solar irradiance variability T. Sukhodolov et al. https://doi.org/10.1002/2015JD024277
- ClOOCl photolysis at high solar zenith angles: analysis of the RECONCILE self-match flight O. Sumińska-Ebersoldt et al. https://doi.org/10.5194/acp-12-1353-2012
- Basis Set Effects in the Description of the Cl-O Bond in ClO and XClO/ClOX Isomers (X = H, O, and Cl) Using DFT and CCSD(T) Methods K. Irving et al. https://doi.org/10.1155/2019/4057848
- UV Absorption Cross Sections of ClOOCl Are Consistent with Ozone Degradation Models H. Chen et al. https://doi.org/10.1126/science.1171305
- Spectroscopic and Thermochemical Properties of ClO, BrO, IO, and Their Anions Using Spinor-Based Coupled Cluster B. Bonar & K. Peterson https://doi.org/10.1021/acs.jpca.5c06884
- The kinetics of the ClOOCl catalytic cycle T. Canty et al. https://doi.org/10.1002/2016JD025710
- HCl and ClO in activated Arctic air; first retrieved vertical profiles from TELIS submillimetre limb spectra A. de Lange et al. https://doi.org/10.5194/amt-5-487-2012
- Heterogeneous chlorine activation on stratospheric aerosols and clouds in the Arctic polar vortex T. Wegner et al. https://doi.org/10.5194/acp-12-11095-2012
- A study of stratospheric chlorine partitioning based on new satellite measurements and modeling M. Santee et al. https://doi.org/10.1029/2007JD009057
- Reconciliation of essential process parameters for an enhanced predictability of Arctic stratospheric ozone loss and its climate interactions (RECONCILE): activities and results M. von Hobe et al. https://doi.org/10.5194/acp-13-9233-2013
- Evaluation of stratospheric chlorine chemistry for the Arctic spring 2005 using modelled and measured OClO column densities H. Oetjen et al. https://doi.org/10.5194/acp-11-689-2011
- Stratospheric ozone chemistry J. McConnell & J. Jin https://doi.org/10.3137/ao.460104
- ClClO2 Is the Most Stable Isomer of Cl2O2. Accurate Coupled Cluster Energetics and Electronic Spectra of Cl2O2 Isomers M. Matus et al. https://doi.org/10.1021/jp806220r
- Multi-photon dissociation dynamics of Freon 1110 induced by femtosecond laser pulse . Liu Yu-Zhu et al. https://doi.org/10.7498/aps.65.113301
- The UV/Vis absorption spectrum of matrix-isolated dichlorine peroxide, ClOOCl M. von Hobe et al. https://doi.org/10.1039/b814373k
- Photodissociation Cross Section of ClOOCl at 330 nm B. Jin et al. https://doi.org/10.1021/jp909374k
- Multiconfigurational study on the synchronous mechanisms of the ClO self-reaction leading to Cl or Cl2 Q. Meng et al. https://doi.org/10.1007/s00214-012-1194-y
- Revisiting Ozone Depletion M. von Hobe https://doi.org/10.1126/science.1151597
- Constraining the chlorine monoxide (ClO)/chlorine peroxide (ClOOCl) equilibrium constant from Aura Microwave Limb Sounder measurements of nighttime ClO M. Santee et al. https://doi.org/10.1073/pnas.0912659107
- Polar stratospheric chlorine kinetics from a self‐match flight during SOLVE‐II/EUPLEX R. Schofield et al. https://doi.org/10.1029/2007GL031740
- HOCl chemistry in the Antarctic Stratospheric Vortex 2002, as observed with the Michelson Interferometer for Passive Atmospheric Sounding (MIPAS) T. von Clarmann et al. https://doi.org/10.5194/acp-9-1817-2009
- Sensitivity of polar stratospheric ozone loss to uncertainties in chemical reaction kinetics S. Kawa et al. https://doi.org/10.5194/acp-9-8651-2009
- UV Absorption Spectrum of the ClO Dimer (Cl2O2) between 200 and 420 nm D. Papanastasiou et al. https://doi.org/10.1021/jp9065345
- Constraints for the photolysis rate and the equilibrium constant of ClO‐dimer from airborne and balloon‐borne measurements of chlorine compounds A. Kleinböhl et al. https://doi.org/10.1002/2013JD021433
- UV Photolysis of ClOOCl and the Ozone Hole J. Lin et al. https://doi.org/10.1002/asia.201100151
- Photodissociation dynamics of ClOOCl at 248.4 and 308.4 nm W. Huang et al. https://doi.org/10.1039/c0cp02453h
- Technical note: Evaluation of the simultaneous measurements of mesospheric OH, HO2, and O3 under a photochemical equilibrium assumption – a statistical approach M. Kulikov et al. https://doi.org/10.5194/acp-18-7453-2018
- Multiphoton ionization and dissociation dynamics of Freon-113 induced by femtosecond laser pulse . Liu Yu-Zhu et al. https://doi.org/10.7498/aps.65.053302
- First remote sensing measurements of ClOOCl along with ClO and ClONO2 in activated and deactivated Arctic vortex conditions using new ClOOCl IR absorption cross sections G. Wetzel et al. https://doi.org/10.5194/acp-10-931-2010
- Thermodynamic Properties of the XO2, X2O, XYO, X2O2, and XYO2 (X, Y = Cl, Br, and I) Isomers D. Grant et al. https://doi.org/10.1021/jp911320p
- Chlorine peroxide (Cl2O2) and its isomers: structures, spectroscopy, formation and thermochemistry Ľ. Horný et al. https://doi.org/10.1080/00268976.2016.1143984
- Does Cosmic-Ray-Induced Heterogeneous Chemistry Influence Stratospheric Polar Ozone Loss? R. Müller & J. Grooß https://doi.org/10.1103/PhysRevLett.103.228501
- The impact of transport across the polar vortex edge on Match ozone loss estimates J. Grooß et al. https://doi.org/10.5194/acp-8-565-2008
- Kinetic and thermochemical studies of the ClO + ClO + M ⇄ Cl2O2 + M reaction V. Ferracci & D. Rowley https://doi.org/10.1039/c0cp00308e
- Photodissociation cross sections of ClOOCl at 248.4 and 266 nm C. Lien et al. https://doi.org/10.1063/1.3257682
- The Cl + O3 reaction: a detailed QCT simulation of molecular beam experiments M. Menéndez et al. https://doi.org/10.1039/C5CP04323A
- Diurnal variations of reactive chlorine and nitrogen oxides observed by MIPAS-B inside the January 2010 Arctic vortex G. Wetzel et al. https://doi.org/10.5194/acp-12-6581-2012
- A Match-based approach to the estimation of polar stratospheric ozone loss using Aura Microwave Limb Sounder observations N. Livesey et al. https://doi.org/10.5194/acp-15-9945-2015
- Estimation of Arctic ozone loss in winter 2004/05 based on assimilation of EOS MLS and SBUV/2 observations D. Jackson & Y. Orsolini https://doi.org/10.1002/qj.316
- Evidence for heterogeneous chlorine activation in the tropical UTLS M. von Hobe et al. https://doi.org/10.5194/acp-11-241-2011
- UV spectroscopic determination of the chlorine monoxide (ClO) ∕ chlorine peroxide (ClOOCl) thermal equilibrium constant J. Klobas & D. Wilmouth https://doi.org/10.5194/acp-19-6205-2019
45 citations as recorded by crossref.
- Retrievals of chlorine chemistry kinetic parameters from Antarctic ClO microwave radiometer measurements S. Kremser et al. https://doi.org/10.5194/acp-11-5183-2011
- Comment on "Cosmic-ray-driven reaction and greenhouse effect of halogenated molecules: Culprits for atmospheric ozone depletion and global climate change" R. Müller & J. Grooß https://doi.org/10.1142/S0217979214820013
- Variability in Antarctic ozone loss in the last decade (2004–2013): high-resolution simulations compared to Aura MLS observations J. Kuttippurath et al. https://doi.org/10.5194/acp-15-10385-2015
- Do cosmic-ray-driven electron-induced reactions impact stratospheric ozone depletion and global climate change? J. Grooß & R. Müller https://doi.org/10.1016/j.atmosenv.2011.03.059
- Evaluation of simulated photolysis rates and their response to solar irradiance variability T. Sukhodolov et al. https://doi.org/10.1002/2015JD024277
- ClOOCl photolysis at high solar zenith angles: analysis of the RECONCILE self-match flight O. Sumińska-Ebersoldt et al. https://doi.org/10.5194/acp-12-1353-2012
- Basis Set Effects in the Description of the Cl-O Bond in ClO and XClO/ClOX Isomers (X = H, O, and Cl) Using DFT and CCSD(T) Methods K. Irving et al. https://doi.org/10.1155/2019/4057848
- UV Absorption Cross Sections of ClOOCl Are Consistent with Ozone Degradation Models H. Chen et al. https://doi.org/10.1126/science.1171305
- Spectroscopic and Thermochemical Properties of ClO, BrO, IO, and Their Anions Using Spinor-Based Coupled Cluster B. Bonar & K. Peterson https://doi.org/10.1021/acs.jpca.5c06884
- The kinetics of the ClOOCl catalytic cycle T. Canty et al. https://doi.org/10.1002/2016JD025710
- HCl and ClO in activated Arctic air; first retrieved vertical profiles from TELIS submillimetre limb spectra A. de Lange et al. https://doi.org/10.5194/amt-5-487-2012
- Heterogeneous chlorine activation on stratospheric aerosols and clouds in the Arctic polar vortex T. Wegner et al. https://doi.org/10.5194/acp-12-11095-2012
- A study of stratospheric chlorine partitioning based on new satellite measurements and modeling M. Santee et al. https://doi.org/10.1029/2007JD009057
- Reconciliation of essential process parameters for an enhanced predictability of Arctic stratospheric ozone loss and its climate interactions (RECONCILE): activities and results M. von Hobe et al. https://doi.org/10.5194/acp-13-9233-2013
- Evaluation of stratospheric chlorine chemistry for the Arctic spring 2005 using modelled and measured OClO column densities H. Oetjen et al. https://doi.org/10.5194/acp-11-689-2011
- Stratospheric ozone chemistry J. McConnell & J. Jin https://doi.org/10.3137/ao.460104
- ClClO2 Is the Most Stable Isomer of Cl2O2. Accurate Coupled Cluster Energetics and Electronic Spectra of Cl2O2 Isomers M. Matus et al. https://doi.org/10.1021/jp806220r
- Multi-photon dissociation dynamics of Freon 1110 induced by femtosecond laser pulse . Liu Yu-Zhu et al. https://doi.org/10.7498/aps.65.113301
- The UV/Vis absorption spectrum of matrix-isolated dichlorine peroxide, ClOOCl M. von Hobe et al. https://doi.org/10.1039/b814373k
- Photodissociation Cross Section of ClOOCl at 330 nm B. Jin et al. https://doi.org/10.1021/jp909374k
- Multiconfigurational study on the synchronous mechanisms of the ClO self-reaction leading to Cl or Cl2 Q. Meng et al. https://doi.org/10.1007/s00214-012-1194-y
- Revisiting Ozone Depletion M. von Hobe https://doi.org/10.1126/science.1151597
- Constraining the chlorine monoxide (ClO)/chlorine peroxide (ClOOCl) equilibrium constant from Aura Microwave Limb Sounder measurements of nighttime ClO M. Santee et al. https://doi.org/10.1073/pnas.0912659107
- Polar stratospheric chlorine kinetics from a self‐match flight during SOLVE‐II/EUPLEX R. Schofield et al. https://doi.org/10.1029/2007GL031740
- HOCl chemistry in the Antarctic Stratospheric Vortex 2002, as observed with the Michelson Interferometer for Passive Atmospheric Sounding (MIPAS) T. von Clarmann et al. https://doi.org/10.5194/acp-9-1817-2009
- Sensitivity of polar stratospheric ozone loss to uncertainties in chemical reaction kinetics S. Kawa et al. https://doi.org/10.5194/acp-9-8651-2009
- UV Absorption Spectrum of the ClO Dimer (Cl2O2) between 200 and 420 nm D. Papanastasiou et al. https://doi.org/10.1021/jp9065345
- Constraints for the photolysis rate and the equilibrium constant of ClO‐dimer from airborne and balloon‐borne measurements of chlorine compounds A. Kleinböhl et al. https://doi.org/10.1002/2013JD021433
- UV Photolysis of ClOOCl and the Ozone Hole J. Lin et al. https://doi.org/10.1002/asia.201100151
- Photodissociation dynamics of ClOOCl at 248.4 and 308.4 nm W. Huang et al. https://doi.org/10.1039/c0cp02453h
- Technical note: Evaluation of the simultaneous measurements of mesospheric OH, HO2, and O3 under a photochemical equilibrium assumption – a statistical approach M. Kulikov et al. https://doi.org/10.5194/acp-18-7453-2018
- Multiphoton ionization and dissociation dynamics of Freon-113 induced by femtosecond laser pulse . Liu Yu-Zhu et al. https://doi.org/10.7498/aps.65.053302
- First remote sensing measurements of ClOOCl along with ClO and ClONO2 in activated and deactivated Arctic vortex conditions using new ClOOCl IR absorption cross sections G. Wetzel et al. https://doi.org/10.5194/acp-10-931-2010
- Thermodynamic Properties of the XO2, X2O, XYO, X2O2, and XYO2 (X, Y = Cl, Br, and I) Isomers D. Grant et al. https://doi.org/10.1021/jp911320p
- Chlorine peroxide (Cl2O2) and its isomers: structures, spectroscopy, formation and thermochemistry Ľ. Horný et al. https://doi.org/10.1080/00268976.2016.1143984
- Does Cosmic-Ray-Induced Heterogeneous Chemistry Influence Stratospheric Polar Ozone Loss? R. Müller & J. Grooß https://doi.org/10.1103/PhysRevLett.103.228501
- The impact of transport across the polar vortex edge on Match ozone loss estimates J. Grooß et al. https://doi.org/10.5194/acp-8-565-2008
- Kinetic and thermochemical studies of the ClO + ClO + M ⇄ Cl2O2 + M reaction V. Ferracci & D. Rowley https://doi.org/10.1039/c0cp00308e
- Photodissociation cross sections of ClOOCl at 248.4 and 266 nm C. Lien et al. https://doi.org/10.1063/1.3257682
- The Cl + O3 reaction: a detailed QCT simulation of molecular beam experiments M. Menéndez et al. https://doi.org/10.1039/C5CP04323A
- Diurnal variations of reactive chlorine and nitrogen oxides observed by MIPAS-B inside the January 2010 Arctic vortex G. Wetzel et al. https://doi.org/10.5194/acp-12-6581-2012
- A Match-based approach to the estimation of polar stratospheric ozone loss using Aura Microwave Limb Sounder observations N. Livesey et al. https://doi.org/10.5194/acp-15-9945-2015
- Estimation of Arctic ozone loss in winter 2004/05 based on assimilation of EOS MLS and SBUV/2 observations D. Jackson & Y. Orsolini https://doi.org/10.1002/qj.316
- Evidence for heterogeneous chlorine activation in the tropical UTLS M. von Hobe et al. https://doi.org/10.5194/acp-11-241-2011
- UV spectroscopic determination of the chlorine monoxide (ClO) ∕ chlorine peroxide (ClOOCl) thermal equilibrium constant J. Klobas & D. Wilmouth https://doi.org/10.5194/acp-19-6205-2019
Saved (final revised paper)
Latest update: 09 Aug 2026
Altmetrics
Final-revised paper
Preprint