Articles | Volume 6, issue 11
Atmos. Chem. Phys., 6, 3611–3623, 2006

Special issue: SAGE III Ozone loss and validation experiment II and the validation...

Atmos. Chem. Phys., 6, 3611–3623, 2006

  06 Sep 2006

06 Sep 2006

Liquid particle composition and heterogeneous reactions in a mountain wave Polar Stratospheric Cloud

D. Lowe1, A. R. MacKenzie1, H. Schlager2, C. Voigt2, A. Dörnbrack2, M. J. Mahoney3, and F. Cairo4 D. Lowe et al.
  • 1Environmental Science Dept., Lancaster University, Lancaster, UK
  • 2Institute for Atmospheric Physics, DLR, Oberpfaffenhofen, Germany
  • 3Jet Propulsion Laboratory, California Institute of Technology, Pasadena, California, USA
  • 4Institute of Atmospheric Sciences and Climate of the National Research Council (CNR-ISAC), Rome, Italy

Abstract. Mountain wave polar stratospheric clouds (PSCs) were detected on 8 February 2003 above the Scandinavian Mountains by in-situ instruments onboard the M55 Geophysica aircraft. PSC particle composition, backscatter and chlorine activation for this case are studied with a recently developed non-equilibrium microphysical box model for liquid aerosol. Results from the microphysical model, run on quasi-lagrangian trajectories, show that the PSC observed was composed of supercooled ternary (H2O/HNO3/H2SO4) solution (STS) particles, which are out of equilibrium with the gas phase. The measured condensed nitric acid and aerosol backscatter of the PSC can well be simulated with the model. Up to 0.15 ppbv Cl2 can be released by the PSC within 2 h, showing the propensity of these small-scale clouds for chlorine activation. Equilibrium calculations – of the sort commonly used in large scale chemistry transport models – overestimate the measured condensed nitrate by up to a factor of 3, and overestimates chlorine activation by 10%, in this mountain wave cloud.

Final-revised paper