Articles | Volume 5, issue 9
https://doi.org/10.5194/acp-5-2403-2005
© Author(s) 2005. This work is licensed under
the Creative Commons Attribution-NonCommercial-ShareAlike 2.5 License.
the Creative Commons Attribution-NonCommercial-ShareAlike 2.5 License.
https://doi.org/10.5194/acp-5-2403-2005
© Author(s) 2005. This work is licensed under
the Creative Commons Attribution-NonCommercial-ShareAlike 2.5 License.
the Creative Commons Attribution-NonCommercial-ShareAlike 2.5 License.
New insight into the atmospheric chloromethane budget gained using stable carbon isotope ratios
F. Keppler
Max-Planck-Institut für Kernphysik, Saupfercheckweg 1, 69 117 Heidelberg, Germany
School of Agriculture and Food Science, Queen’s University Belfast, Newforge Lane, Belfast BT9 5PX, UK
D. B. Harper
School of Agriculture and Food Science, Queen’s University Belfast, Newforge Lane, Belfast BT9 5PX, UK
T. Röckmann
Institute for Marine and Atmospheric Research Utrecht, Utrecht University, Utrecht, The Netherlands UK
Max-Planck-Institut für Kernphysik, Saupfercheckweg 1, 69 117 Heidelberg, Germany
R. M. Moore
Department of Oceanography, Dalhousie University, Halifax, Novia Scotia, B3H 4J1, Canada
J. T. G. Hamilton
School of Agriculture and Food Science, Queen’s University Belfast, Newforge Lane, Belfast BT9 5PX, UK
Department of Agriculture and Rural Development for Northern Ireland, Newforge Lane, Belfast BT9 5PX, UK
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90 citations as recorded by crossref.
- Microbial Synthesis and Transformation of Inorganic and Organic Chlorine Compounds S. Atashgahi et al. 10.3389/fmicb.2018.03079
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- Methyl sulfates as methoxy isotopic reference materials for δ13C and δ2H measurements M. Greule et al. 10.1002/rcm.8355
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- Sources and sinks of chloromethane in a salt marsh ecosystem: constraints from concentration and stable isotope measurements of laboratory incubation experiments F. Keppler et al. 10.1039/C9EM00540D
- White-rots, chlorine and the environment – a tale of many twists H. Anke & R. Weber 10.1016/j.mycol.2006.03.011
- Methyl chloride and methyl bromide emissions from baking: an unrecognized anthropogenic source B. Thornton et al. 10.1016/j.scitotenv.2016.01.213
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- Mechanistic aspects of the nucleophilic substitution of pectin. On the formation of chloromethane Y. Sailaukhanuly et al. 10.1016/j.chemosphere.2014.05.001
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- Exoplanet Biosignatures: A Framework for Their Assessment D. Catling et al. 10.1089/ast.2017.1737
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- Isotopic Characterization (2H, 13C, 37Cl, 81Br) of Abiotic Degradation of Methyl Bromide and Methyl Chloride in Water and Implications for Future Studies A. Horst et al. 10.1021/acs.est.9b02165
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- Mass spectrometric measurement of hydrogen isotope fractionation for the reactions of chloromethane with OH and Cl F. Keppler et al. 10.5194/acp-18-6625-2018
- Profiling of soil volatile organic compounds after long-term application of inorganic, organic and organic-inorganic mixed fertilizers and their effect on plant growth W. Raza et al. 10.1016/j.scitotenv.2017.07.023
- Organohalogen emissions from saline environments – spatial extrapolation using remote sensing as most promising tool K. Kotte et al. 10.5194/bg-9-1225-2012
- Potential Biosignatures in Super-Earth Atmospheres II. Photochemical Responses J. Grenfell et al. 10.1089/ast.2012.0926
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- Analytical system for stable carbon isotope measurements of low molecular weight (C<sub>2</sub>-C<sub>6</sub>) hydrocarbons A. Zuiderweg et al. 10.5194/amt-4-1161-2011
- Methyl chloride from the Aura Microwave Limb Sounder: First global climatology and assessment of variability in the upper troposphere and stratosphere M. Santee et al. 10.1002/2013JD020235
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- Methyl chloride and isoprene emissions from tropical rain forest in Southeast Asia T. Saito et al. 10.1029/2008GL035241
- Chlorine isotope fractionation between chloride (Cl−) and dichlorine (Cl2) T. Giunta et al. 10.1016/j.gca.2017.07.003
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- Chlorine Isotope Effects and Composition of Naturally Produced Organochlorines from Chloroperoxidases, Flavin-Dependent Halogenases, and in Forest Soil C. Aeppli et al. 10.1021/es3037669
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- Long-term high frequency measurements of ethane, benzene and methyl chloride at Ragged Point, Barbados: Identification of long-range transport events A. Archibald et al. 10.12952/journal.elementa.000068
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- A new model suite to determine the influence of cosmic rays on (exo)planetary atmospheric biosignatures K. Herbst et al. 10.1051/0004-6361/201935888
- Triple‐Element Stable Isotope Analysis of Chloromethane Emitted by Royal Fern and Degraded by Club Moss S. Hartmann et al. 10.1029/2022JG007256
- Stable carbon isotope analysis of selected halocarbons at parts per trillion concentration in an urban location M. Mead et al. 10.1071/EN08037
- Fluorescence-Based Bacterial Bioreporter for Specific Detection of Methyl Halide Emissions in the Environment M. Farhan Ul Haque et al. 10.1128/AEM.01738-13
- Explicitly correlated potential energy surface of the CH3Cl–He van der Waals complex and applications A. Ben Krid et al. 10.1063/5.0038677
- Identification of methyl chloride-emitting plants and atmospheric measurements on a subtropical island Y. Yokouchi et al. 10.1016/j.chemosphere.2007.03.028
- Global methyl halide emissions from biomass burning during 2003–2021 X. Hu et al. 10.1016/j.ese.2022.100228
- Chloromethane Degradation in Soils: A Combined Microbial and Two‐Dimensional Stable Isotope Approach N. Jaeger et al. 10.2134/jeq2017.09.0358
- Emission estimates of methyl chloride from industrial sources in China based on high frequency atmospheric observations S. Li et al. 10.1007/s10874-016-9354-4
- On-line screening of soil VOCs exchange responses to moisture, temperature and root presence D. Asensio et al. 10.1007/s11104-006-9190-4
- High-resolution millimeter-wave spectroscopy of CH2DCl: Paving the way for future astronomical observations of chloromethane isotopologues M. Melosso et al. 10.1016/j.jqsrt.2020.106982
- Isotopic composition of polyhalomethanes from marine macrophytes – systematic effects of the halogen substituents on isotopic composition E. Bahlmann et al. 10.1071/EN14210
- Transfer of a Catabolic Pathway for Chloromethane in Methylobacterium Strains Highlights Different Limitations for Growth with Chloromethane or with Dichloromethane J. Michener et al. 10.3389/fmicb.2016.01116
- Probing the diversity of chloromethane-degrading bacteria by comparative genomics and isotopic fractionation T. Nadalig et al. 10.3389/fmicb.2014.00523
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- Abiotic Methyl Bromide Formation from Vegetation, and Its Strong Dependence on Temperature A. Wishkerman et al. 10.1021/es800411j
- Stable hydrogen-isotope analysis of methyl chloride emitted from heated halophytic plants M. Greule et al. 10.1016/j.atmosenv.2012.09.007
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- Methyl chloride in a deep ice core from Siple Dome, Antarctica E. Saltzman et al. 10.1029/2008GL036266
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87 citations as recorded by crossref.
- Microbial Synthesis and Transformation of Inorganic and Organic Chlorine Compounds S. Atashgahi et al. 10.3389/fmicb.2018.03079
- Chloromethane formation and degradation in the fern phyllosphere N. Jaeger et al. 10.1016/j.scitotenv.2018.03.316
- 13C‐chloromethane incubations provide evidence for novel bacterial chloromethane degraders in a living tree fern E. Kröber et al. 10.1111/1462-2920.15638
- Anthropogenic emissions of ozone-depleting substance CH3Cl during 2000–2020 in China X. Hu et al. 10.1016/j.envpol.2022.119903
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- Carbon isotopic signatures of methanol and acetaldehyde emitted from biomass burning source K. Yamada et al. 10.1029/2009GL038962
- Sources and sinks of methyl bromide and methyl chloride in the tallgrass prairie: Applying a stable isotope tracer technique over highly variable gross fluxes R. Rhew 10.1029/2011JG001704
- Methyl sulfates as methoxy isotopic reference materials for δ13C and δ2H measurements M. Greule et al. 10.1002/rcm.8355
- Spatial variation in natural formation of chloroform in the soils of four coniferous forests C. Albers et al. 10.1007/s10533-010-9467-9
- Sources and sinks of chloromethane in a salt marsh ecosystem: constraints from concentration and stable isotope measurements of laboratory incubation experiments F. Keppler et al. 10.1039/C9EM00540D
- White-rots, chlorine and the environment – a tale of many twists H. Anke & R. Weber 10.1016/j.mycol.2006.03.011
- Methyl chloride and methyl bromide emissions from baking: an unrecognized anthropogenic source B. Thornton et al. 10.1016/j.scitotenv.2016.01.213
- Isotope ratio studies of atmospheric organic compounds: Principles, methods, applications and potential I. Gensch et al. 10.1016/j.ijms.2014.02.004
- Mechanistic aspects of the nucleophilic substitution of pectin. On the formation of chloromethane Y. Sailaukhanuly et al. 10.1016/j.chemosphere.2014.05.001
- Atmospheric deuterium fractionation: HCHO and HCDO yields in the CH<sub>2</sub>DO + O<sub>2</sub> reaction E. Nilsson et al. 10.5194/acp-7-5873-2007
- Study of the Carbon-13 and Deuterium Kinetic Isotope Effects in the Cl and OH Reactions of CH4 and CH3Cl S. Sellevåg et al. 10.1021/jp0549778
- Precise ground state molecular parameters of chloromethane L. Nová Stříteská et al. 10.1016/j.molstruc.2008.08.015
- Exoplanet Biosignatures: A Framework for Their Assessment D. Catling et al. 10.1089/ast.2017.1737
- Determination of carbon isotope ratios of methanol and acetaldehyde in air samples by gas chromatography-isotope ratio mass spectrometry combined with headspace solid-phase microextraction K. Yamada et al. 10.1080/10256016.2010.505686
- Chloromethane emissions in human breath F. Keppler et al. 10.1016/j.scitotenv.2017.06.202
- The search for signs of life on exoplanets at the interface of chemistry and planetary science S. Seager & W. Bains 10.1126/sciadv.1500047
- Stable isotope determination of ester and ether methyl moieties in plant methoxyl groups M. Greule & F. Keppler 10.1080/10256016.2011.616270
- A BIOMASS-BASED MODEL TO ESTIMATE THE PLAUSIBILITY OF EXOPLANET BIOSIGNATURE GASES S. Seager et al. 10.1088/0004-637X/775/2/104
- Isotopic Characterization (2H, 13C, 37Cl, 81Br) of Abiotic Degradation of Methyl Bromide and Methyl Chloride in Water and Implications for Future Studies A. Horst et al. 10.1021/acs.est.9b02165
- Absence of humic substance reduction by the acidophilic Fe(III)-reducing strain Acidiphilium SJH: implications for its Fe(III) reduction mechanism and for the stimulation of natural organohalogen formation M. Emmerich & A. Kappler 10.1007/s10533-011-9621-z
- Mass spectrometric measurement of hydrogen isotope fractionation for the reactions of chloromethane with OH and Cl F. Keppler et al. 10.5194/acp-18-6625-2018
- Profiling of soil volatile organic compounds after long-term application of inorganic, organic and organic-inorganic mixed fertilizers and their effect on plant growth W. Raza et al. 10.1016/j.scitotenv.2017.07.023
- Organohalogen emissions from saline environments – spatial extrapolation using remote sensing as most promising tool K. Kotte et al. 10.5194/bg-9-1225-2012
- Potential Biosignatures in Super-Earth Atmospheres II. Photochemical Responses J. Grenfell et al. 10.1089/ast.2012.0926
- A Photochemical Source of Methyl Chloride in Saline Waters R. Moore 10.1021/es071920l
- Analytical system for stable carbon isotope measurements of low molecular weight (C<sub>2</sub>-C<sub>6</sub>) hydrocarbons A. Zuiderweg et al. 10.5194/amt-4-1161-2011
- Methyl chloride from the Aura Microwave Limb Sounder: First global climatology and assessment of variability in the upper troposphere and stratosphere M. Santee et al. 10.1002/2013JD020235
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- Chlorine Isotope Fractionation of the Major Chloromethane Degradation Processes in the Environment F. Keppler et al. 10.1021/acs.est.9b06139
- Methyl chloride and isoprene emissions from tropical rain forest in Southeast Asia T. Saito et al. 10.1029/2008GL035241
- Chlorine isotope fractionation between chloride (Cl−) and dichlorine (Cl2) T. Giunta et al. 10.1016/j.gca.2017.07.003
- Methyl chloride isotopic signatures from Irish forest soils and a comparison between abiotic and biogenic methyl halide soil fluxes K. Redeker & R. Kalin 10.1111/j.1365-2486.2011.02600.x
- Chlorine Isotope Effects and Composition of Naturally Produced Organochlorines from Chloroperoxidases, Flavin-Dependent Halogenases, and in Forest Soil C. Aeppli et al. 10.1021/es3037669
- Halogenated organic species over the tropical South American rainforest S. Gebhardt et al. 10.5194/acp-8-3185-2008
- Long-term high frequency measurements of ethane, benzene and methyl chloride at Ragged Point, Barbados: Identification of long-range transport events A. Archibald et al. 10.12952/journal.elementa.000068
- A halocarbon survey from a seagrass dominated subtropical lagoon, Ria Formosa (Portugal): flux pattern and isotopic composition I. Weinberg et al. 10.5194/bg-12-1697-2015
- Methanol consumption drives the bacterial chloromethane sink in a forest soil P. Chaignaud et al. 10.1038/s41396-018-0228-4
- Effects of temperature and soil moisture on methyl halide and chloroform fluxes from drained peatland pasture soils M. Khan et al. 10.1039/C1EM10639B
- Chloromethane release from carbonaceous meteorite affords new insight into Mars lander findings F. Keppler et al. 10.1038/srep07010
- Stable carbon isotope ratios of ethane over the North Pacific: Atmospheric measurements and global chemical transport modeling T. Saito et al. 10.1029/2010JD014602
- Methyl chloride emissions from halophyte leaf litter: Dependence on temperature and chloride content L. Derendorp et al. 10.1016/j.chemosphere.2011.12.035
- A review of exoplanetary biosignatures J. Grenfell 10.1016/j.physrep.2017.08.003
- A new model suite to determine the influence of cosmic rays on (exo)planetary atmospheric biosignatures K. Herbst et al. 10.1051/0004-6361/201935888
- Triple‐Element Stable Isotope Analysis of Chloromethane Emitted by Royal Fern and Degraded by Club Moss S. Hartmann et al. 10.1029/2022JG007256
- Stable carbon isotope analysis of selected halocarbons at parts per trillion concentration in an urban location M. Mead et al. 10.1071/EN08037
- Fluorescence-Based Bacterial Bioreporter for Specific Detection of Methyl Halide Emissions in the Environment M. Farhan Ul Haque et al. 10.1128/AEM.01738-13
- Explicitly correlated potential energy surface of the CH3Cl–He van der Waals complex and applications A. Ben Krid et al. 10.1063/5.0038677
- Identification of methyl chloride-emitting plants and atmospheric measurements on a subtropical island Y. Yokouchi et al. 10.1016/j.chemosphere.2007.03.028
- Global methyl halide emissions from biomass burning during 2003–2021 X. Hu et al. 10.1016/j.ese.2022.100228
- Chloromethane Degradation in Soils: A Combined Microbial and Two‐Dimensional Stable Isotope Approach N. Jaeger et al. 10.2134/jeq2017.09.0358
- Emission estimates of methyl chloride from industrial sources in China based on high frequency atmospheric observations S. Li et al. 10.1007/s10874-016-9354-4
- On-line screening of soil VOCs exchange responses to moisture, temperature and root presence D. Asensio et al. 10.1007/s11104-006-9190-4
- High-resolution millimeter-wave spectroscopy of CH2DCl: Paving the way for future astronomical observations of chloromethane isotopologues M. Melosso et al. 10.1016/j.jqsrt.2020.106982
- Isotopic composition of polyhalomethanes from marine macrophytes – systematic effects of the halogen substituents on isotopic composition E. Bahlmann et al. 10.1071/EN14210
- Transfer of a Catabolic Pathway for Chloromethane in Methylobacterium Strains Highlights Different Limitations for Growth with Chloromethane or with Dichloromethane J. Michener et al. 10.3389/fmicb.2016.01116
- Probing the diversity of chloromethane-degrading bacteria by comparative genomics and isotopic fractionation T. Nadalig et al. 10.3389/fmicb.2014.00523
- Uncertainties of fluxes and <sup>13</sup>C ∕ <sup>12</sup>C ratios of atmospheric reactive-gas emissions S. Gromov et al. 10.5194/acp-17-8525-2017
- Methane emissions from terrestrial plants under aerobic conditions F. Keppler et al. 10.1038/nature04420
- Fast determination of methyl chloride and methyl bromide emissions from dried plant matter and soil samples using HS-SPME and GC-MS: method and first results N. Yassaa et al. 10.1071/EN09034
- Thermolytic degradation of methylmethionine and implications for its role in DMS and MeCl formation in hypersaline environments I. Mulder et al. 10.1071/EN14207
- Methyl chloride and C2–C5 hydrocarbon emissions from dry leaf litter and their dependence on temperature L. Derendorp et al. 10.1016/j.atmosenv.2011.03.016
- A High-Volume Cryosampler and Sample Purification System for Bromine Isotope Studies of Methyl Bromide* B. Thornton et al. 10.1175/JTECH-D-12-00228.1
- Protostellar and cometary detections of organohalogens E. Fayolle et al. 10.1038/s41550-017-0237-7
- Sensitivity of biomarkers to changes in chemical emissions in the Earth’s Proterozoic atmosphere J. Grenfell et al. 10.1016/j.icarus.2010.09.015
- Hydrologic regulation of gross methyl chloride and methyl bromide uptake from Alaskan Arctic tundra Y. TEH et al. 10.1111/j.1365-2486.2008.01749.x
- Release and uptake of volatile inorganic and organic gases through the snowpack at Niwot Ridge, Colorado D. Helmig et al. 10.1007/s10533-009-9326-8
- Stable Carbon Isotope Analysis of Anthropogenic Volatile Halogenated C1 and C2 Organic Compounds N. Auer & D. Schulz-Bull 10.1071/EN06027
- A high volume sampling system for isotope determination of volatile halocarbons and hydrocarbons E. Bahlmann et al. 10.5194/amt-4-2073-2011
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