NH3 converts Criegee intermediates to nitrogenous organics
Xiaoying Li,Long Jia,and Yongfu Xu
Xiaoying Li
State Key Laboratory of Atmospheric Environment and Extreme Meteorology, Institute of Atmospheric Physics, Chinese Academy of Sciences, Beijing, 100029, China
College of Earth and Planetary Sciences, University of Chinese Academy of Sciences, Beijing, 100049, China
State Key Laboratory of Atmospheric Environment and Extreme Meteorology, Institute of Atmospheric Physics, Chinese Academy of Sciences, Beijing, 100029, China
College of Earth and Planetary Sciences, University of Chinese Academy of Sciences, Beijing, 100049, China
Yongfu Xu
College of Earth and Planetary Sciences, University of Chinese Academy of Sciences, Beijing, 100049, China
State Key Laboratory of Atmospheric Boundary Layer Physics and Atmospheric Chemistry, Institute of Atmospheric Physics, Chinese Academy of Sciences, Beijing, 100029, China
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Nitrogen-containing organic aerosols can affect health, environment, and climate; however, their formation mechanism is still poorly understood. Based on Orbitrap-MS (mass spectrometer), our study reveals a previously unrecognized atmospheric reaction pathway in which ammonia can efficiently scavenge stable Criegee intermediates. This new reaction produces nitrogen-containing organic compounds with a reactive peroxide bond, which may pose health risks and alter the optical properties of aerosols.
Nitrogen-containing organic aerosols can affect health, environment, and climate; however, their...