Atmospheric Chemistry and Physics
Atmospheric Chemistry and Physics
ACP
Articles | Volume 26, issue 6
Articles | Volume 26, issue 6
https://doi.org/10.5194/acp-26-3933-2026
© Author(s) 2026. This work is distributed under
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-26-3933-2026
© Author(s) 2026. This work is distributed under
the Creative Commons Attribution 4.0 License.
Articles | Volume 26, issue 6
Research article
 | 
20 Mar 2026
Research article |  | 20 Mar 2026

Gas-phase products from nitrate radical oxidation of five monoterpenes: insights from free-jet flow-tube experiments

Jiangyi Zhang, Yi Zhang, Hannu Koskenvaara, Jian Zhao, and Mikael Ehn

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Short summary
Using a free-jet flow-tube system, we observed a wide range of radicals and closed-shell products from NO3 oxidation of five monoterpenes (α-pinene, Δ-3-carene, limonene, β-pinene, and β-myrcene). Results highlight that the product formation is highly structure-dependent. Our study provides individual product yields, radical distributions, and HOM (highly oxygenated organic molecule) yields, which are all essential for correctly implementing monoterpene + NO3 oxidation mechanisms into models.
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