Summary

This manuscript (“Upward transport and segregation of ice-nucleating particles in deep convective clouds”) by Schaefer et al. investigates the transport of particles in deep convective clouds, with a focus upon ice nucleating particles. They utilize the HALO research aircraft to collect measurements of particle number and composition above Europe. They sampled aerosol and cloud residual composition using a single particle mass spectrometer, and collected filters for offline analysis. They primarily present results from a case study sampling a deep convective system, where they sampled the inflow the convective system, in-cloud, and the outflow of the convective system. The convective inflow had high INP concentrations at very warm temperatures (>-15 °C), while the in-cloud had INPs at warm temperatures, but particularly from -14 to -17 °C, and the convective outflow had virtually no INPs at temperatures warmer than 17 °C. They observed that DCC outflow INPs were much higher than would have been expected from the background INP concentrations in the free troposphere/lower stratosphere, indicating that the INPs were transported from the BL. They also observed that the composition of free tropospheric air, in-cloud residuals, and convective outflow varied systematically, though this aspect of the paper is under-developed.

I like this study, think it is interesting, and that it warrants publication in ACP after some revisions. My suggestions are below.

General comments

First, this paper is primarily about a single case study, with a handful of supporting measurements from complementary flights. The authors make some strong statements about their results, from a single case study and I think that they need to temper them. For instance, in the summary and conclusions, they state that “deep convective clouds act as a major mechanism for lifting INPs from the boundary layer into the free troposphere.” I am not disputing that they DCC can transport INPs from the BL into the FT, but calling it a major mechanism is too strong, based upon the results from one research flight. I would also say that they did not find that INP outflow from DCC “can influence ice formation in cirrus clouds, and after sedimentation downstream, in mid-level mixed-phase clouds.” I agree that this may happen, but don’t think the authors demonstrated that happening in this study. Wording here and throughout the manuscript should be revised where appropriate.

Second, it appears to me that there is no significant difference between the activated fraction of warm INPs in the inflow vs in-cloud residuals (Fig. 5a). At the very warmest temperatures (-10 °C) the in-cloud sampling has higher INP concentrations than the inflow, and when the inflow is higher than the in-cloud, it appears to be within the measurement uncertainty.

Finally, the single particle composition aspect of this paper is under-developed. For instance, dust particles are observed in-cloud and also at the DCC outflow. Is the mixing state of the dust particles that make it to the outflow systematically different from those found in-cloud? It would be interesting to know whether the authors considered this in their analysis.

Specific comments

Line 51: HALO needs to be parenthesized.

Line 63: Cziczo et al. (2004) also measured composition of INPs in the free troposphere.

Line 81: I think it would be worthwhile to change the name of HASI to not include sub-micrometer. If it has been modified to also measure supermicron particles, it seems like a potential source of unnecessary confusion.

Line 124: The sentence starting “A lower size…” is awkwardly constructed, rewrite for clarity.

Line 133: Vali formula given in SI, worthwhile to reference this fact.

Line 163: What does S2 refer to? Is it figure or table?

Line 221: No closing parentheses.

Line 234: This whole paragraph has a number of missing parantheses. I am going to stop noting these, but please go through and carefully check the rest of the manuscript.

Line 248: I thought that the

Line 287: Figure 5d title is ‘outflow’ not ‘inflow’, and there is no red line. Do you mean 5c?

Line 387: I think that the authors showed that DCC can act as a lifting mechanism for INPs, but they did not find a clear indication that “they can influence ice formation in cirrus clouds, and after sedimentation downstream, in mid-level mixed-phase clouds.” I agree that the this is likely to happen, but don’t think the authors demonstrated that happening in this study. Would recommend rewording this point to clarify the distinction.

Figure 4: Panel (a) altitude is in hPa, could you add a scale showing it in m as well. There is also a blue line that looks like an isotherm in this panel, what is it?

Supplement: It would be more reader-friendly to add the list of abbreviations to the main text.

References

 Cziczo, D. J., Murphy, D. M., Hudson, P. K., & Thomson, D. S. (2004). Single particle measurements of the chemical composition of cirrus ice residue during CRYSTAL-FACE. Journal of Geophysical Research, 109(D4), 1–13. https://doi.org/10.1029/2003JD004032

see attached