Atmospheric Chemistry and Physics
Atmospheric Chemistry and Physics
ACP
Articles | Volume 25, issue 6
Articles | Volume 25, issue 6
https://doi.org/10.5194/acp-25-3481-2025
© Author(s) 2025. This work is distributed under
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-25-3481-2025
© Author(s) 2025. This work is distributed under
the Creative Commons Attribution 4.0 License.
Articles | Volume 25, issue 6
Research article
 | 
25 Mar 2025
Research article |  | 25 Mar 2025

Kinetics of the reactions of OH with CO, NO, and NO2 and of HO2 with NO2 in air at 1 atm pressure, room temperature, and tropospheric water vapour concentrations

Michael Rolletter, Andreas Hofzumahaus, Anna Novelli, Andreas Wahner, and Hendrik Fuchs

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Short summary
Highly accurate rate coefficients of termolecular reactions between OH and HO2 radicals and reactive nitrogen oxides were measured for conditions in the lower troposphere, providing improved constraints on recommended values. No dependence on water vapour was found except for the HO2+NO2 reaction, which can be explained by an enhanced rate coefficient of the NO2 reaction with the water complex of the HO2 radical.
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