Articles | Volume 25, issue 4
https://doi.org/10.5194/acp-25-2459-2025
© Author(s) 2025. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-25-2459-2025
© Author(s) 2025. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
26 Feb 2025
Research article |
| 26 Feb 2025
| 26 Feb 2025
Vertical changes in volatile organic compounds (VOCs) and impacts on photochemical ozone formation
Xiao-Bing Li
College of Environment and Climate, Institute for Environmental and Climate Research, Guangdong–Hong Kong–Macau Joint Laboratory of Collaborative Innovation for Environmental Quality, Jinan University, Guangzhou 511443, China
College of Environment and Climate, Institute for Environmental and Climate Research, Guangdong–Hong Kong–Macau Joint Laboratory of Collaborative Innovation for Environmental Quality, Jinan University, Guangzhou 511443, China
Yibo Huangfu
College of Environment and Climate, Institute for Environmental and Climate Research, Guangdong–Hong Kong–Macau Joint Laboratory of Collaborative Innovation for Environmental Quality, Jinan University, Guangzhou 511443, China
Suxia Yang
Guangzhou Research Institute of Environment Protection Co., Ltd., Guangzhou 510620, China
College of Environment and Climate, Institute for Environmental and Climate Research, Guangdong–Hong Kong–Macau Joint Laboratory of Collaborative Innovation for Environmental Quality, Jinan University, Guangzhou 511443, China
Jipeng Qi
College of Environment and Climate, Institute for Environmental and Climate Research, Guangdong–Hong Kong–Macau Joint Laboratory of Collaborative Innovation for Environmental Quality, Jinan University, Guangzhou 511443, China
Xianjun He
College of Environment and Climate, Institute for Environmental and Climate Research, Guangdong–Hong Kong–Macau Joint Laboratory of Collaborative Innovation for Environmental Quality, Jinan University, Guangzhou 511443, China
Sihang Wang
College of Environment and Climate, Institute for Environmental and Climate Research, Guangdong–Hong Kong–Macau Joint Laboratory of Collaborative Innovation for Environmental Quality, Jinan University, Guangzhou 511443, China
Yubin Chen
College of Environment and Climate, Institute for Environmental and Climate Research, Guangdong–Hong Kong–Macau Joint Laboratory of Collaborative Innovation for Environmental Quality, Jinan University, Guangzhou 511443, China
Qing Yang
College of Environment and Climate, Institute for Environmental and Climate Research, Guangdong–Hong Kong–Macau Joint Laboratory of Collaborative Innovation for Environmental Quality, Jinan University, Guangzhou 511443, China
Yongxin Song
College of Environment and Climate, Institute for Environmental and Climate Research, Guangdong–Hong Kong–Macau Joint Laboratory of Collaborative Innovation for Environmental Quality, Jinan University, Guangzhou 511443, China
Yuwen Peng
College of Environment and Climate, Institute for Environmental and Climate Research, Guangdong–Hong Kong–Macau Joint Laboratory of Collaborative Innovation for Environmental Quality, Jinan University, Guangzhou 511443, China
Guiqian Tang
State Key Laboratory of Atmospheric Environment and Extreme Meteorology, Institute of Atmospheric Physics, Chinese Academy of Sciences, Beijing 100029, China
University of Chinese Academy of Sciences, Beijing 100049, China
Jian Gao
State Key Laboratory of Environmental Criteria and Risk Assessment, Chinese Research Academy of Environmental Sciences, Beijing 100012, China
Guangdong-Hong Kong-Macau Joint Laboratory of Collaborative Innovation for Environmental Quality and Division of Environment and Sustainability, Hong Kong University of Science and Technology, Hong Kong SAR 999077, China
Min Shao
College of Environment and Climate, Institute for Environmental and Climate Research, Guangdong–Hong Kong–Macau Joint Laboratory of Collaborative Innovation for Environmental Quality, Jinan University, Guangzhou 511443, China
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Cited
20 citations as recorded by crossref.
- Contrasting boundary-layer energy budgets during daytime, nighttime, and compound heatwaves in eastern China Z. Duan et al. https://doi.org/10.1016/j.isci.2026.114892
- Demonstration of an Automated System for Vertical Profiles of Volatile Organic Compounds G. Vandergrift et al. https://doi.org/10.1021/acsearthspacechem.5c00181
- Vertical Distribution of Volatile Organic Compounds and Their Potential Impact on Ozone Formation in Coal Chemical Industry Clusters of Northern Shaanxi S. SHI et al. https://doi.org/10.3724/EE.1672-9250.2026.54.008
- Production and loss pathways of tropospheric ozone under different ambient conditions R. Lehmann et al. https://doi.org/10.1007/s10874-025-09488-z
- Three-dimensional electrical impedance tomography for characterizing effects of particle agglomerates on adsorption efficiency in a gas–solid fluidized bed C. Pang et al. https://doi.org/10.1088/1361-6501/ae6093
- Ozone pollution: a persistent challenge in large cities like Mexico City, Los Angeles and Beijing E. Velasco et al. https://doi.org/10.14324/111.444/ucloe.3448
- MOF-Derived Catalytic Interfaces for Low-Temperature Chemiresistive VOC Sensing in Complex Backgrounds L. Zhang et al. https://doi.org/10.3390/chemosensors13110386
- A new parameterization of photolysis rates for oxygenated volatile organic compounds (OVOCs) Y. Peng et al. https://doi.org/10.5194/acp-25-7037-2025
- Aircraft-based observation of volatile organic compounds (VOCs) over the North China Plain Y. Huangfu et al. https://doi.org/10.5194/acp-25-17613-2025
- Effect of the Antibiotic Norfloxacin on Volatile Organic Compound Emissions From the Cyanobacteria Microcystis aeruginosa J. Wang et al. https://doi.org/10.1111/ppl.70910
- Unraveling the Formation and Evolution of Winter Haze in Beijing: Insights from Vertical Measurements of Particle Size Distributions and Aerosol Composition Y. Sun et al. https://doi.org/10.1021/acsestair.5c00264
- Drone-based needle trap device array coupled with portable mass spectrometry for onsite analysis of hazardous air pollutants J. Zhang et al. https://doi.org/10.1016/j.aca.2026.345218
- Uncovering Benzene Pollution Patterns Using an Interpretable, Setting-Aware Artificial Intelligence Approach I. Bešlić et al. https://doi.org/10.3390/toxics14020181
- Demand-Driven Ozone-Assisted Oxidation in a Recirculating Domestic Kitchen Hood: Experimental Evaluation and RSM Optimization E. Özçetin et al. https://doi.org/10.3390/app16084022
- Room-temperature VOC detection using light-driven metal oxide heterojunctions: principles, challenges, and prospects P. Shangpliang et al. https://doi.org/10.1039/D6NA00239K
- Characterization of atmospheric volatile phenolic compounds in china: based on long-term observations - Possibly seriously underestimated OVOCs Z. Chen et al. https://doi.org/10.1016/j.atmosres.2025.108586
- What Drives the Spatiotemporal Characteristics and Evolution of Near-Surface Ozone Across Multiple Scales? Implications for Sustainable Air Quality Management in Coastal Southeast China Y. Wu et al. https://doi.org/10.3390/su18136842
- Volatile organic compounds in bangu, Rio de janeiro: an exploratory study of source apportionment in the neighborhood with integrated assessment of toxicity and reactivity over a Two-Month monitoring period V. Maciel et al. https://doi.org/10.1007/s43153-025-00594-9
- Air pollution in the shadow of global crises: lessons from a small city in the Western Balkans A. Nuredini et al. https://doi.org/10.1039/D5EA00116A
- The differentiated VOC species vertical profiles and regional source contributions induced by transport and their reactivities over Nanjing Y. Wang et al. https://doi.org/10.1016/j.atmosenv.2026.122217
20 citations as recorded by crossref.
- Contrasting boundary-layer energy budgets during daytime, nighttime, and compound heatwaves in eastern China Z. Duan et al. https://doi.org/10.1016/j.isci.2026.114892
- Demonstration of an Automated System for Vertical Profiles of Volatile Organic Compounds G. Vandergrift et al. https://doi.org/10.1021/acsearthspacechem.5c00181
- Vertical Distribution of Volatile Organic Compounds and Their Potential Impact on Ozone Formation in Coal Chemical Industry Clusters of Northern Shaanxi S. SHI et al. https://doi.org/10.3724/EE.1672-9250.2026.54.008
- Production and loss pathways of tropospheric ozone under different ambient conditions R. Lehmann et al. https://doi.org/10.1007/s10874-025-09488-z
- Three-dimensional electrical impedance tomography for characterizing effects of particle agglomerates on adsorption efficiency in a gas–solid fluidized bed C. Pang et al. https://doi.org/10.1088/1361-6501/ae6093
- Ozone pollution: a persistent challenge in large cities like Mexico City, Los Angeles and Beijing E. Velasco et al. https://doi.org/10.14324/111.444/ucloe.3448
- MOF-Derived Catalytic Interfaces for Low-Temperature Chemiresistive VOC Sensing in Complex Backgrounds L. Zhang et al. https://doi.org/10.3390/chemosensors13110386
- A new parameterization of photolysis rates for oxygenated volatile organic compounds (OVOCs) Y. Peng et al. https://doi.org/10.5194/acp-25-7037-2025
- Aircraft-based observation of volatile organic compounds (VOCs) over the North China Plain Y. Huangfu et al. https://doi.org/10.5194/acp-25-17613-2025
- Effect of the Antibiotic Norfloxacin on Volatile Organic Compound Emissions From the Cyanobacteria Microcystis aeruginosa J. Wang et al. https://doi.org/10.1111/ppl.70910
- Unraveling the Formation and Evolution of Winter Haze in Beijing: Insights from Vertical Measurements of Particle Size Distributions and Aerosol Composition Y. Sun et al. https://doi.org/10.1021/acsestair.5c00264
- Drone-based needle trap device array coupled with portable mass spectrometry for onsite analysis of hazardous air pollutants J. Zhang et al. https://doi.org/10.1016/j.aca.2026.345218
- Uncovering Benzene Pollution Patterns Using an Interpretable, Setting-Aware Artificial Intelligence Approach I. Bešlić et al. https://doi.org/10.3390/toxics14020181
- Demand-Driven Ozone-Assisted Oxidation in a Recirculating Domestic Kitchen Hood: Experimental Evaluation and RSM Optimization E. Özçetin et al. https://doi.org/10.3390/app16084022
- Room-temperature VOC detection using light-driven metal oxide heterojunctions: principles, challenges, and prospects P. Shangpliang et al. https://doi.org/10.1039/D6NA00239K
- Characterization of atmospheric volatile phenolic compounds in china: based on long-term observations - Possibly seriously underestimated OVOCs Z. Chen et al. https://doi.org/10.1016/j.atmosres.2025.108586
- What Drives the Spatiotemporal Characteristics and Evolution of Near-Surface Ozone Across Multiple Scales? Implications for Sustainable Air Quality Management in Coastal Southeast China Y. Wu et al. https://doi.org/10.3390/su18136842
- Volatile organic compounds in bangu, Rio de janeiro: an exploratory study of source apportionment in the neighborhood with integrated assessment of toxicity and reactivity over a Two-Month monitoring period V. Maciel et al. https://doi.org/10.1007/s43153-025-00594-9
- Air pollution in the shadow of global crises: lessons from a small city in the Western Balkans A. Nuredini et al. https://doi.org/10.1039/D5EA00116A
- The differentiated VOC species vertical profiles and regional source contributions induced by transport and their reactivities over Nanjing Y. Wang et al. https://doi.org/10.1016/j.atmosenv.2026.122217
Saved (final revised paper)
Latest update: 14 Jul 2026
Short summary
Online vertical gradient measurements of volatile organic compounds (VOCs), ozone, and NOx were conducted based on a 325 m tall tower in urban Beijing. Vertical changes in the concentrations, compositions, key drivers, and environmental impacts of VOCs were analyzed in this study. We find that VOC species display differentiated vertical variation patterns and distinct roles in contributing to photochemical ozone formation with increasing height in the urban planetary boundary layer.
Online vertical gradient measurements of volatile organic compounds (VOCs), ozone, and NOx were...
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