Articles | Volume 25, issue 23
https://doi.org/10.5194/acp-25-17779-2025
© Author(s) 2025. This work is distributed under the Creative Commons Attribution 4.0 License.
Emission characteristics of greenhouse gases and air pollutants in a Qinghai-Tibetan Plateau city using a portable Fourier transform spectrometer and TROPOMI observations
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- Final revised paper (published on 05 Dec 2025)
- Preprint (discussion started on 01 Apr 2025)
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Status: closed
Comment types: AC – author | RC – referee | CC – community | EC – editor | CEC – chief editor
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RC1: 'Comment on egusphere-2025-966', Anonymous Referee #1, 11 May 2025
- AC1: 'Reply on RC1', Qiansi Tu, 24 Oct 2025
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RC2: 'Comment on egusphere-2025-966', Anonymous Referee #2, 29 Jul 2025
- AC2: 'Reply on RC2', Qiansi Tu, 24 Oct 2025
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AR – Author's response | RR – Referee report | ED – Editor decision | EF – Editorial file upload
AR by Qiansi Tu on behalf of the Authors (24 Oct 2025)
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ED: Referee Nomination & Report Request started (04 Nov 2025) by Chris Wilson
RR by Anonymous Referee #2 (23 Nov 2025)
ED: Publish subject to minor revisions (review by editor) (28 Nov 2025) by Chris Wilson
AR by Qiansi Tu on behalf of the Authors (28 Nov 2025)
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ED: Publish as is (29 Nov 2025) by Chris Wilson
AR by Qiansi Tu on behalf of the Authors (30 Nov 2025)
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This manuscript presents a short-term measurement campaign in Xining, a city located on the eastern edge of the Qinghai-Tibetan Plateau (QTP), using a portable FTIR instrument (EM27/SUN) to retrieve column-averaged concentrations of CO₂, CH₄, and CO. The study touches on several topics, including satellite validation for CH₄ and CO, CAMS product evaluation, combustion efficiency derived from the CO:CO₂ ratio, and CO₂ emissions estimation. However, the manuscript lacks a cohesive narrative and frequently shifts between topics without adequately developing or concluding each one. As a result, it reads more like a collection of loosely connected sub-studies rather than a focused, hypothesis-driven investigation.
And the study does not offer significant methodological innovation or new scientific insights and lacks discussion part. The only potentially unique aspect is the absence of previous atmospheric column observations in the suburban area of Xining city. However, this alone does not justify publication unless the authors can thoroughly address the concerns outlined above through major revisions.
Major Comments:
1. The observational period was very short, only 8 days in early June 2024, but the rationale for selecting this specific timeframe is unclear. Was there a particular emission event or atmospheric condition of interest during this period? The motivation for the campaign is not well explained. Additionally, the measurements were conducted in a suburban area, but it is not clear whether this site is representative, whether the data can inform future carbon cycle studies, or what the broader scientific significance is. Summer conditions are typically associated with various interfering factors, yet these are neither acknowledged nor discussed in the manuscript.
2. The manuscript aims to evaluate satellite retrievals using ground-based observations. In Section 2.2, a detailed description of the general COCCON product is provided, but there is almost no information about the specific EM27/SUN instrument used in this campaign. Key details such as the instrument’s stability before and after the measurement period, the configuration of retrieval parameters, and whether any calibration was performed using TCCON, AirCore, or aircraft measurements are missing. Additionally, the measurement uncertainty is not discussed. As the ground-based observations serve as the reference for satellite validation, it is essential to present their accuracy and reliability clearly, rather than focusing only on general background information.
3. The manuscript also attempts to evaluate CAMS simulation results using ground-based observations. However, the approach raises several questions. A 20 km radius was used for CAMS product validation—but why? Since CAMS provides data at specific grid points, the rationale for selecting a 20 km averaging radius is unclear. Large-area averaging is typically applied in satellite validation to reduce observational noise and improve sampling statistics, but it is not obvious why a 20 km radius was appropriate or necessary in this case.
Moreover, the analysis in this section is not sufficiently developed. The authors conclude that CAMS performs well in simulating CH₄ in this region, while its performance for CO and CO₂ is poor. But what are the broader implications of this result? Does this indicate that CAMS is better suited for CH₄ studies over the Qinghai-Tibetan Plateau? Could this support the case for establishing long-term observation sites in the area?
In addition, satellite retrievals usually offer a higher number of soundings than ground-based instruments. How does the CAMS product compare with satellite observations in terms of coverage and consistency? Do the conclusions drawn from CAMS agree with those from the COCCON dataset? These questions are not clearly addressed in the manuscript.
4. The manuscript estimates CO₂ emissions using CO fluxes derived from TROPOMI and EM27/SUN observations. However, several points need clarification. First, the emission estimation appears to be based on multiplying values observed by wind speed. If so, does this method account for transport processes and particle dilution along the plume? A brief explanation of this approach in the Methods section would be helpful. In addition, how does the CO:CO₂ ratio used in this study compare with values reported in emission inventories? This could be further discussed, especially in relation to combustion efficiency and source attribution.
Moreover, there appears to be an inconsistency in logic. In the CAMS evaluation, CO and CO₂ simulations were shown to perform poorly, while CH₄ agreed well with observations. However, in this section, the calculated CO emissions match CAMS values, and CO₂ emissions align closely with inventory estimates. Given the earlier performance issues with CO and CO₂ in CAMS, this raises questions about the reliability of the derived fluxes. What about CH₄ emissions in this context? Without addressing this discrepancy, the conclusions are difficult to reconcile.
Minor Comments:
Line 53–55: I still do not fully understand the claim that surface observations are influenced by surface exchange but limit the ability to estimate sources and sinks. Given that surface measurements are sensitive to near-surface fluxes, wouldn’t they actually be more effective for detecting local sources and sinks? This statement needs clarification.
Line 161: This point raises concerns. The measurement period spans only 8 days, while coal mining activity is often highly episodic. As shown in the study by [Author] (https://doi.org/10.1016/j.ecolind.2023.110454), regions similar to the study area in Qinghai are known to have significant coal mining emissions. Therefore, concluding that there is no such influence based solely on this short observational window appears premature.