Articles | Volume 24, issue 1
https://doi.org/10.5194/acp-24-663-2024
https://doi.org/10.5194/acp-24-663-2024
Research article
 | 
17 Jan 2024
Research article |  | 17 Jan 2024

Temperature-dependent aqueous OH kinetics of C2–C10 linear and terpenoid alcohols and diols: new rate coefficients, structure–activity relationship, and atmospheric lifetimes

Bartłomiej Witkowski, Priyanka Jain, Beata Wileńska, and Tomasz Gierczak

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Interactive discussion

Status: closed

Comment types: AC – author | RC – referee | CC – community | EC – editor | CEC – chief editor | : Report abuse
  • RC1: 'Review of ACP submission egusphere-2023-1381', Anonymous Referee #2, 02 Sep 2023
    • AC2: 'Reply on RC1', Bartlomiej Witkowski, 06 Nov 2023
  • RC2: 'Comment on egusphere-2023-1381', Anonymous Referee #1, 04 Sep 2023
    • AC1: 'Reply on RC2', Bartlomiej Witkowski, 06 Nov 2023

Peer review completion

AR: Author's response | RR: Referee report | ED: Editor decision | EF: Editorial file upload
AR by Bartlomiej Witkowski on behalf of the Authors (07 Nov 2023)  Author's response   Author's tracked changes   Manuscript 
ED: Referee Nomination & Report Request started (12 Nov 2023) by Allan Bertram
RR by Anonymous Referee #2 (21 Nov 2023)
ED: Publish as is (24 Nov 2023) by Allan Bertram
AR by Bartlomiej Witkowski on behalf of the Authors (29 Nov 2023)  Author's response   Manuscript 
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Short summary
This article reports the results of the kinetic measurements for the aqueous oxidation of the 29 aliphatic alcohols by hydroxyl radical (OH) at different temperatures. The data acquired and the literature data were used to optimize a model for predicting the aqueous OH reactivity of alcohols and carboxylic acids and to estimate the atmospheric lifetimes of five terpenoic alcohols. The kinetic data provided new insights into the mechanism of aqueous oxidation of aliphatic molecules by the OH.
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