Atmospheric Chemistry and Physics
Atmospheric Chemistry and Physics
ACP
Articles | Volume 24, issue 11
Articles | Volume 24, issue 11
https://doi.org/10.5194/acp-24-6567-2024
© Author(s) 2024. This work is distributed under
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-24-6567-2024
© Author(s) 2024. This work is distributed under
the Creative Commons Attribution 4.0 License.
Articles | Volume 24, issue 11
Research article
 | 
05 Jun 2024
Research article |  | 05 Jun 2024

Dual roles of the inorganic aqueous phase on secondary organic aerosol growth from benzene and phenol

Jiwon Choi, Myoseon Jang, and Spencer Blau

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Short summary
Persistent phenoxy radical (PPR), formed by phenol gas oxidation and its aqueous reaction, catalytically destroys O3 and retards secondary organic aerosol (SOA) growth. Explicit gas mechanisms including the formation of PPR and low-volatility products from the oxidation of phenol or benzene are applied to the UNIPAR model to predict SOA mass via multiphase reactions of precursors. Aqueous reactions of reactive organics increase SOA mass but retard SOA growth via heterogeneously formed PPR.
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