Articles | Volume 24, issue 9
https://doi.org/10.5194/acp-24-5585-2024
https://doi.org/10.5194/acp-24-5585-2024
Research article
 | 
15 May 2024
Research article |  | 15 May 2024

Modeling the influence of carbon branching structure on secondary organic aerosol formation via multiphase reactions of alkanes

Azad Madhu, Myoseon Jang, and Yujin Jo

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Latest update: 29 Jun 2024
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Short summary
Secondary organic aerosol (SOA) formation from branched alkanes (BAs) was simulated using the UNIPAR model, which predicted SOA growth via multiphase reactions of hydrocarbons, and compared with chamber data. Product distributions (PDs) of BAs were created by extrapolating PDs of linear alkanes (LAs). To account for methyl branching, an autoxidation reduction factor was applied to PDs. BAs in diesel fuel were shown to produce a higher proportion of SOA compared with LAs.
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