Department of Environmental Sciences and Engineering, Gillings School
of Global Public Health,
The University of North Carolina at Chapel Hill, Chapel Hill, NC 27599-7431, USA
Department of Environmental Sciences and Engineering, Gillings School
of Global Public Health,
The University of North Carolina at Chapel Hill, Chapel Hill, NC 27599-7431, USA
Department of Chemistry, College of Arts and Sciences, The University
of North Carolina at Chapel Hill, Chapel Hill, NC 27599-3290, USA
Zhenfa Zhang
Department of Environmental Sciences and Engineering, Gillings School
of Global Public Health,
The University of North Carolina at Chapel Hill, Chapel Hill, NC 27599-7431, USA
Department of Environmental Sciences and Engineering, Gillings School
of Global Public Health,
The University of North Carolina at Chapel Hill, Chapel Hill, NC 27599-7431, USA
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We report synthesis of the isoprene-derived photochemical oxidation products trans- and cis-β-epoxydiols in high overall yields from inexpensive, readily available starting compounds. Protection/deprotection steps or time-consuming purification is not required, and the reactions can be scaled up to gram quantities. The procedures provide accessibility of these important compounds to atmospheric chemistry laboratories with only basic capabilities in organic synthesis.
We report synthesis of the isoprene-derived photochemical oxidation products trans- and...