Articles | Volume 23, issue 13
https://doi.org/10.5194/acp-23-7767-2023
© Author(s) 2023. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-23-7767-2023
© Author(s) 2023. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Atmospheric oxidation of new “green” solvents – Part 2: methyl pivalate and pinacolone
Caterina Mapelli
Department of Chemistry, University of York, York, YO10 5DD, UK
now at: the Institute of Atmospheric Sciences and Climate, National
Research Council, Lecce, 73100, Italy
James K. Donnelly
Department of Chemistry, University of York, York, YO10 5DD, UK
Úna E. Hogan
Department of Chemistry, University of York, York, YO10 5DD, UK
now at: Department of Chemistry, University of Waterloo, Waterloo, ON
N2L 3G1, Canada
Andrew R. Rickard
Department of Chemistry, University of York, York, YO10 5DD, UK
National Centre for Atmospheric Science, Wolfson Atmospheric Chemistry
Laboratories, Department of Chemistry, University of York, York, YO10 5DD, UK
Abbie T. Robinson
Department of Chemistry, University of York, York, YO10 5DD, UK
Fergal Byrne
Department of Chemistry, University of York, York, YO10 5DD, UK
Department of Chemistry, Maynooth University, Maynooth, Co. Kildare,
W23 F2H6, Ireland
Con Rob McElroy
Department of Chemistry, University of York, York, YO10 5DD, UK
School of Chemistry, University of Lincoln, Lincoln, LN6 7TS, UK
Basile F. E. Curchod
School of Chemistry, University of Bristol, Bristol, BS8 1TS, UK
Daniel Hollas
School of Chemistry, University of Bristol, Bristol, BS8 1TS, UK
Department of Chemistry, University of York, York, YO10 5DD, UK
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Cited
9 citations as recorded by crossref.
- Atmospheric breakdown kinetics and air quality impact of potential “green” solvents, the oxymethylene ethers OME3 and OME4 J. D'Souza Metcalf et al. https://doi.org/10.5194/acp-25-9169-2025
- AtmoSpec–A Tool to Calculate Photoabsorption Cross-Sections for Atmospheric Volatile Organic Compounds D. Hollas & B. Curchod https://doi.org/10.1021/acs.jpca.4c05174
- Practical atmospheric photochemical kinetics for undergraduate teaching and research J. D'Souza Metcalf et al. https://doi.org/10.1039/D5SU00681C
- Reactivity study of 3,3-dimethylbutanal and 3,3-dimethylbutanone: kinetics, reaction products, mechanisms, and atmospheric implications I. Aranda et al. https://doi.org/10.5194/acp-25-5445-2025
- Vapor Phase Cross Ketonization of Pivalic Acid with Acetic Acid to Prepare Pinacolone Over Mg-Zr Mixed Oxide Catalysts P. Kumar et al. https://doi.org/10.1007/s10562-024-04752-5
- Gas-phase degradation of the aroma compound ethyl butyrate and its methylated derivatives: UV-C photolysis and reactions with the hydroxyl radical F. Löher et al. https://doi.org/10.5194/acp-26-9277-2026
- Reductive Cross-Coupling of Alkynes with Aryl Bromides via Zr/Pd Synergistic Catalysis M. Erzuah et al. https://doi.org/10.1021/acs.orglett.6c01949
- Assessing Air Quality Impacts of Greener Chemicals: Beyond Traditional Metrics J. D’Souza Metcalf et al. https://doi.org/10.1021/acssuschemeng.5c08649
- Accelerating discovery across scientific disciplines through reproducible workflows with AiiDAlab A. Yakutovich et al. https://doi.org/10.1039/D5DD00567A
9 citations as recorded by crossref.
- Atmospheric breakdown kinetics and air quality impact of potential “green” solvents, the oxymethylene ethers OME3 and OME4 J. D'Souza Metcalf et al. https://doi.org/10.5194/acp-25-9169-2025
- AtmoSpec–A Tool to Calculate Photoabsorption Cross-Sections for Atmospheric Volatile Organic Compounds D. Hollas & B. Curchod https://doi.org/10.1021/acs.jpca.4c05174
- Practical atmospheric photochemical kinetics for undergraduate teaching and research J. D'Souza Metcalf et al. https://doi.org/10.1039/D5SU00681C
- Reactivity study of 3,3-dimethylbutanal and 3,3-dimethylbutanone: kinetics, reaction products, mechanisms, and atmospheric implications I. Aranda et al. https://doi.org/10.5194/acp-25-5445-2025
- Vapor Phase Cross Ketonization of Pivalic Acid with Acetic Acid to Prepare Pinacolone Over Mg-Zr Mixed Oxide Catalysts P. Kumar et al. https://doi.org/10.1007/s10562-024-04752-5
- Gas-phase degradation of the aroma compound ethyl butyrate and its methylated derivatives: UV-C photolysis and reactions with the hydroxyl radical F. Löher et al. https://doi.org/10.5194/acp-26-9277-2026
- Reductive Cross-Coupling of Alkynes with Aryl Bromides via Zr/Pd Synergistic Catalysis M. Erzuah et al. https://doi.org/10.1021/acs.orglett.6c01949
- Assessing Air Quality Impacts of Greener Chemicals: Beyond Traditional Metrics J. D’Souza Metcalf et al. https://doi.org/10.1021/acssuschemeng.5c08649
- Accelerating discovery across scientific disciplines through reproducible workflows with AiiDAlab A. Yakutovich et al. https://doi.org/10.1039/D5DD00567A
Saved (final revised paper)
Latest update: 17 Jul 2026
Short summary
Solvents are chemical compounds with countless uses in the chemical industry, and they also represent one of the main sources of pollution in the chemical sector. Scientists are trying to develop new
greensafer solvents which present favourable advantages when compared to traditional solvents. Since the assessment of these green solvents often lacks air quality considerations, this study aims to understand the behaviour of these compounds, investigating their reactivity in the troposphere.
Solvents are chemical compounds with countless uses in the chemical industry, and they also...
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