Articles | Volume 23, issue 13
https://doi.org/10.5194/acp-23-7347-2023
© Author(s) 2023. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-23-7347-2023
© Author(s) 2023. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
05 Jul 2023
Research article |
| 05 Jul 2023
| 05 Jul 2023
Volatility of aerosol particles from NO3 oxidation of various biogenic organic precursors
Emelie L. Graham
Department of Environmental Science (ACES) and Bolin Centre for
Climate Research, Stockholm University, Stockholm, Sweden
Cheng Wu
Department of Environmental Science (ACES) and Bolin Centre for
Climate Research, Stockholm University, Stockholm, Sweden
now at: Department of Chemistry and Molecular Biology, University of Gothenburg, Gothenburg, Sweden
David M. Bell
Paul Scherrer Institute, Laboratory of Atmospheric Chemistry, 5232
Villigen, Switzerland
Amelie Bertrand
Paul Scherrer Institute, Laboratory of Atmospheric Chemistry, 5232
Villigen, Switzerland
Sophie L. Haslett
Department of Environmental Science (ACES) and Bolin Centre for
Climate Research, Stockholm University, Stockholm, Sweden
Urs Baltensperger
Paul Scherrer Institute, Laboratory of Atmospheric Chemistry, 5232
Villigen, Switzerland
Imad El Haddad
Paul Scherrer Institute, Laboratory of Atmospheric Chemistry, 5232
Villigen, Switzerland
Radovan Krejci
Department of Environmental Science (ACES) and Bolin Centre for
Climate Research, Stockholm University, Stockholm, Sweden
Ilona Riipinen
CORRESPONDING AUTHOR
Department of Environmental Science (ACES) and Bolin Centre for
Climate Research, Stockholm University, Stockholm, Sweden
Department of Environmental Science (ACES) and Bolin Centre for
Climate Research, Stockholm University, Stockholm, Sweden
now at: Paul Scherrer Institute, Laboratory of Atmospheric Chemistry, 5232 Villigen, Switzerland
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Cited
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- Unraveling secondary organic aerosol formation from isoprene and toluene mixture S. Han et al. 10.1038/s41612-025-01189-4
- Observation-constrained kinetic modeling of isoprene SOA formation in the atmosphere C. Shen et al. 10.5194/acp-24-6153-2024
- Molecular characterization of aerosols from photochemical interactions of toluene and α-pinene using Orbitrap-MS J. Wang et al. 10.1016/j.atmosenv.2025.121452
- Development, Demonstration, and Evaluation of Routine Monitoring of Aerosol Carbon, Oxygen, and Sulfur Content P. Kumar et al. 10.1021/acsestair.3c00059
- Tower-based profiles of wintertime secondary organic aerosols in the urban boundary layer over Guangzhou Y. Li et al. 10.1016/j.scitotenv.2024.175326
- Molecular-Level Insights into the Relationship between Volatility of Organic Aerosol Constituents and PM2.5 Air Pollution Levels: A Study with Ultrahigh-Resolution Mass Spectrometry K. Wang et al. 10.1021/acs.est.3c10662
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- Cloud response to co-condensation of water and organic vapors over the boreal forest L. Heikkinen et al. 10.5194/acp-24-5117-2024
- Characterization of offline analysis of particulate matter with FIGAERO-CIMS J. Cai et al. 10.5194/amt-16-1147-2023
10 citations as recorded by crossref.
- Simultaneously Characterizing the Volatility Distribution and Phase State of Submicron Secondary Organic Aerosols Using a Vocus Vaporization Inlet for Aerosols with a Chemical Ionization Mass Spectrometer S. Niu et al. 10.1021/acsestair.5c00155
- Unraveling secondary organic aerosol formation from isoprene and toluene mixture S. Han et al. 10.1038/s41612-025-01189-4
- Observation-constrained kinetic modeling of isoprene SOA formation in the atmosphere C. Shen et al. 10.5194/acp-24-6153-2024
- Molecular characterization of aerosols from photochemical interactions of toluene and α-pinene using Orbitrap-MS J. Wang et al. 10.1016/j.atmosenv.2025.121452
- Development, Demonstration, and Evaluation of Routine Monitoring of Aerosol Carbon, Oxygen, and Sulfur Content P. Kumar et al. 10.1021/acsestair.3c00059
- Tower-based profiles of wintertime secondary organic aerosols in the urban boundary layer over Guangzhou Y. Li et al. 10.1016/j.scitotenv.2024.175326
- Molecular-Level Insights into the Relationship between Volatility of Organic Aerosol Constituents and PM2.5 Air Pollution Levels: A Study with Ultrahigh-Resolution Mass Spectrometry K. Wang et al. 10.1021/acs.est.3c10662
- Variation in chemical composition and volatility of oxygenated organic aerosol in different rural, urban, and mountain environments W. Huang et al. 10.5194/acp-24-2607-2024
- Hygroscopicity and Volatility of Biomass Burning Aromatic and Nitroaromatic Compounds M. Amugoda et al. 10.1021/acsestair.3c00071
- Cloud response to co-condensation of water and organic vapors over the boreal forest L. Heikkinen et al. 10.5194/acp-24-5117-2024
1 citations as recorded by crossref.
Latest update: 30 Oct 2025
Short summary
The volatility of an aerosol particle is an important parameter for describing its atmospheric lifetime. We studied the volatility of secondary organic aerosols from nitrate-initiated oxidation of three biogenic precursors with experimental methods and model simulations. We saw higher volatility than for the corresponding ozone system, and our simulations produced variable results with different parameterizations which warrant a re-evaluation of the treatment of the nitrate functional group.
The volatility of an aerosol particle is an important parameter for describing its atmospheric...
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