Volatility of aerosol particles from NO<sub>3</sub> oxidation of various biogenic organic precursors

Graham, Emelie L.; Wu, Cheng; Bell, David M.; Bertrand, Amelie; Haslett, Sophie L.; Baltensperger, Urs; El Haddad, Imad; Krejci, Radovan; Riipinen, Ilona; Mohr, Claudia

doi:https://doi.org/10.5194/acp-23-7347-2023

Articles | Volume 23, issue 13

Article
Assets
Peer review
Metrics
Related articles

Articles | Volume 23, issue 13

https://doi.org/10.5194/acp-23-7347-2023

Articles | Volume 23, issue 13

Article
Assets
Peer review
Metrics
Related articles

Research article

05 Jul 2023

Research article |

| 05 Jul 2023

Volatility of aerosol particles from NO₃ oxidation of various biogenic organic precursors

Emelie L. Graham, Cheng Wu, David M. Bell, Amelie Bertrand, Sophie L. Haslett, Urs Baltensperger, Imad El Haddad, Radovan Krejci, Ilona Riipinen, and Claudia Mohr

Emelie L. Graham

Department of Environmental Science (ACES) and Bolin Centre for Climate Research, Stockholm University, Stockholm, Sweden

Cheng Wu

Department of Environmental Science (ACES) and Bolin Centre for Climate Research, Stockholm University, Stockholm, Sweden

now at: Department of Chemistry and Molecular Biology, University of Gothenburg, Gothenburg, Sweden

David M. Bell

https://orcid.org/0000-0002-3958-2138

Paul Scherrer Institute, Laboratory of Atmospheric Chemistry, 5232 Villigen, Switzerland

Amelie Bertrand

Paul Scherrer Institute, Laboratory of Atmospheric Chemistry, 5232 Villigen, Switzerland

Sophie L. Haslett

https://orcid.org/0000-0003-2985-4846

Department of Environmental Science (ACES) and Bolin Centre for Climate Research, Stockholm University, Stockholm, Sweden

Urs Baltensperger

https://orcid.org/0000-0003-0079-8713

Paul Scherrer Institute, Laboratory of Atmospheric Chemistry, 5232 Villigen, Switzerland

Imad El Haddad

https://orcid.org/0000-0002-2461-7238

Paul Scherrer Institute, Laboratory of Atmospheric Chemistry, 5232 Villigen, Switzerland

Radovan Krejci

https://orcid.org/0000-0002-9384-9702

Department of Environmental Science (ACES) and Bolin Centre for Climate Research, Stockholm University, Stockholm, Sweden

Ilona Riipinen

CORRESPONDING AUTHOR

ilona.riipinen@aces.su.se

Department of Environmental Science (ACES) and Bolin Centre for Climate Research, Stockholm University, Stockholm, Sweden

Claudia Mohr

CORRESPONDING AUTHOR

claudia.mohr@psi.ch

https://orcid.org/0000-0002-3291-9295

Department of Environmental Science (ACES) and Bolin Centre for Climate Research, Stockholm University, Stockholm, Sweden

now at: Paul Scherrer Institute, Laboratory of Atmospheric Chemistry, 5232 Villigen, Switzerland

Viewed

Show all Final revised paper only Preprint only

Total article views: 2,346 (including HTML, PDF, and XML)

HTML	PDF	XML	Total	Supplement	BibTeX	EndNote
1,783	505	58	2,346	140	42	70

HTML: 1,783
PDF: 505
XML: 58
Total: 2,346
Supplement: 140
BibTeX: 42
EndNote: 70

Views and downloads (calculated since 10 Oct 2022)

Cumulative views and downloads (calculated since 10 Oct 2022)

Total article views: 1,764 (including HTML, PDF, and XML)

HTML	PDF	XML	Total	Supplement	BibTeX	EndNote
1,389	333	42	1,764	79	38	51

HTML: 1,389
PDF: 333
XML: 42
Total: 1,764
Supplement: 79
BibTeX: 38
EndNote: 51

Views and downloads (calculated since 05 Jul 2023)

Month	HTML	PDF	XML	Total
Jul 2023	449	92	7	548
Aug 2023	128	21	3	152
Sep 2023	96	24	1	121
Oct 2023	103	22	1	126
Nov 2023	51	9	4	64
Dec 2023	39	14	2	55
Jan 2024	37	9	2	48
Feb 2024	35	13	1	49
Mar 2024	34	19	0	53
Apr 2024	35	17	4	56
May 2024	31	12	5	48
Jun 2024	64	13	1	78
Jul 2024	42	9	3	54
Aug 2024	33	10	2	45
Sep 2024	29	6	1	36
Oct 2024	36	8	0	44
Nov 2024	24	5	1	30
Dec 2024	23	7	0	30
Jan 2025	27	8	1	36
Feb 2025	38	9	1	48
Mar 2025	35	6	2	43

Cumulative views and downloads (calculated since 05 Jul 2023)

Month	HTML	PDF	XML	Total
Jul 2023	449	92	7	548
Aug 2023	128	21	3	152
Sep 2023	96	24	1	121
Oct 2023	103	22	1	126
Nov 2023	51	9	4	64
Dec 2023	39	14	2	55
Jan 2024	37	9	2	48
Feb 2024	35	13	1	49
Mar 2024	34	19	0	53
Apr 2024	35	17	4	56
May 2024	31	12	5	48
Jun 2024	64	13	1	78
Jul 2024	42	9	3	54
Aug 2024	33	10	2	45
Sep 2024	29	6	1	36
Oct 2024	36	8	0	44
Nov 2024	24	5	1	30
Dec 2024	23	7	0	30
Jan 2025	27	8	1	36
Feb 2025	38	9	1	48
Mar 2025	35	6	2	43

Total article views: 582 (including HTML, PDF, and XML)

HTML	PDF	XML	Total	Supplement	BibTeX	EndNote
394	172	16	582	61	4	19

HTML: 394
PDF: 172
XML: 16
Total: 582
Supplement: 61
BibTeX: 4
EndNote: 19

Views and downloads (calculated since 10 Oct 2022)

Month	HTML	PDF	XML	Total
Jul 2023	449	92	7	548
Aug 2023	128	21	3	152
Sep 2023	96	24	1	121
Oct 2023	103	22	1	126
Nov 2023	51	9	4	64
Dec 2023	39	14	2	55
Jan 2024	37	9	2	48
Feb 2024	35	13	1	49
Mar 2024	34	19	0	53
Apr 2024	35	17	4	56
May 2024	31	12	5	48
Jun 2024	64	13	1	78
Jul 2024	42	9	3	54
Aug 2024	33	10	2	45
Sep 2024	29	6	1	36
Oct 2024	36	8	0	44
Nov 2024	24	5	1	30
Dec 2024	23	7	0	30
Jan 2025	27	8	1	36
Feb 2025	38	9	1	48
Mar 2025	35	6	2	43

Cumulative views and downloads (calculated since 10 Oct 2022)

Month	HTML	PDF	XML	Total
Jul 2023	449	92	7	548
Aug 2023	128	21	3	152
Sep 2023	96	24	1	121
Oct 2023	103	22	1	126
Nov 2023	51	9	4	64
Dec 2023	39	14	2	55
Jan 2024	37	9	2	48
Feb 2024	35	13	1	49
Mar 2024	34	19	0	53
Apr 2024	35	17	4	56
May 2024	31	12	5	48
Jun 2024	64	13	1	78
Jul 2024	42	9	3	54
Aug 2024	33	10	2	45
Sep 2024	29	6	1	36
Oct 2024	36	8	0	44
Nov 2024	24	5	1	30
Dec 2024	23	7	0	30
Jan 2025	27	8	1	36
Feb 2025	38	9	1	48
Mar 2025	35	6	2	43

Viewed (geographical distribution)

Show all Final revised paper only Preprint only

Total article views: 2,346 (including HTML, PDF, and XML) Thereof 2,248 with geography defined and 98 with unknown origin.

Total article views: 1,764 (including HTML, PDF, and XML) Thereof 1,682 with geography defined and 82 with unknown origin.

Total article views: 582 (including HTML, PDF, and XML) Thereof 566 with geography defined and 16 with unknown origin.

Country	#	Views	%
United States of America	1	793	33
China	2	437	18
Sweden	3	159	6
Germany	4	144	6
India	5	83	3

Country	#	Views	%
United States of America	1	651	36
China	2	347	19
Germany	3	95	5
Sweden	4	80	4
India	5	76	4

Country	#	Views	%
United States of America	1	142	24
China	2	90	15
Sweden	3	79	13
Germany	4	49	8
Finland	5	39	6


Total:	0
HTML:	0
PDF:	0
XML:	0

793


Total:	0
HTML:	0
PDF:	0
XML:	0

651


Total:	0
HTML:	0
PDF:	0
XML:	0

142

Cited

Show all Final revised paper only Preprint only

8 citations as recorded by crossref.

Observation-constrained kinetic modeling of isoprene SOA formation in the atmosphere C. Shen et al. 10.5194/acp-24-6153-2024
Development, Demonstration, and Evaluation of Routine Monitoring of Aerosol Carbon, Oxygen, and Sulfur Content P. Kumar et al. 10.1021/acsestair.3c00059
Tower-based profiles of wintertime secondary organic aerosols in the urban boundary layer over Guangzhou Y. Li et al. 10.1016/j.scitotenv.2024.175326
Molecular-Level Insights into the Relationship between Volatility of Organic Aerosol Constituents and PM2.5 Air Pollution Levels: A Study with Ultrahigh-Resolution Mass Spectrometry K. Wang et al. 10.1021/acs.est.3c10662
Variation in chemical composition and volatility of oxygenated organic aerosol in different rural, urban, and mountain environments W. Huang et al. 10.5194/acp-24-2607-2024
Hygroscopicity and Volatility of Biomass Burning Aromatic and Nitroaromatic Compounds M. Amugoda et al. 10.1021/acsestair.3c00071
Cloud response to co-condensation of water and organic vapors over the boreal forest L. Heikkinen et al. 10.5194/acp-24-5117-2024
Characterization of offline analysis of particulate matter with FIGAERO-CIMS J. Cai et al. 10.5194/amt-16-1147-2023

7 citations as recorded by crossref.

Observation-constrained kinetic modeling of isoprene SOA formation in the atmosphere C. Shen et al. 10.5194/acp-24-6153-2024
Development, Demonstration, and Evaluation of Routine Monitoring of Aerosol Carbon, Oxygen, and Sulfur Content P. Kumar et al. 10.1021/acsestair.3c00059
Tower-based profiles of wintertime secondary organic aerosols in the urban boundary layer over Guangzhou Y. Li et al. 10.1016/j.scitotenv.2024.175326
Molecular-Level Insights into the Relationship between Volatility of Organic Aerosol Constituents and PM2.5 Air Pollution Levels: A Study with Ultrahigh-Resolution Mass Spectrometry K. Wang et al. 10.1021/acs.est.3c10662
Variation in chemical composition and volatility of oxygenated organic aerosol in different rural, urban, and mountain environments W. Huang et al. 10.5194/acp-24-2607-2024
Hygroscopicity and Volatility of Biomass Burning Aromatic and Nitroaromatic Compounds M. Amugoda et al. 10.1021/acsestair.3c00071
Cloud response to co-condensation of water and organic vapors over the boreal forest L. Heikkinen et al. 10.5194/acp-24-5117-2024

1 citations as recorded by crossref.

Characterization of offline analysis of particulate matter with FIGAERO-CIMS J. Cai et al. 10.5194/amt-16-1147-2023

Latest update: 29 Mar 2025

Download

Article (3271 KB)
Full-text XML

Supplement (1584 KB)
BibTeX
EndNote

Short summary

The volatility of an aerosol particle is an important parameter for describing its atmospheric lifetime. We studied the volatility of secondary organic aerosols from nitrate-initiated oxidation of three biogenic precursors with experimental methods and model simulations. We saw higher volatility than for the corresponding ozone system, and our simulations produced variable results with different parameterizations which warrant a re-evaluation of the treatment of the nitrate functional group.

The volatility of an aerosol particle is an important parameter for describing its atmospheric...