A combined gas- and particle-phase analysis  of highly oxygenated organic molecules  (HOMs) from <i>α</i>-pinene ozonolysis

Zhao, Jian; Häkkinen, Ella; Graeffe, Frans; Krechmer, Jordan E.; Canagaratna, Manjula R.; Worsnop, Douglas R.; Kangasluoma, Juha; Ehn, Mikael

doi:https://doi.org/10.5194/acp-23-3707-2023

Articles | Volume 23, issue 6

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Articles | Volume 23, issue 6

https://doi.org/10.5194/acp-23-3707-2023

Articles | Volume 23, issue 6

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Research article

28 Mar 2023

Research article |

| 28 Mar 2023

A combined gas- and particle-phase analysis of highly oxygenated organic molecules (HOMs) from α-pinene ozonolysis

Jian Zhao, Ella Häkkinen, Frans Graeffe, Jordan E. Krechmer, Manjula R. Canagaratna, Douglas R. Worsnop, Juha Kangasluoma, and Mikael Ehn

Jian Zhao

CORRESPONDING AUTHOR

jian.zhao@helsinki.fi

https://orcid.org/0000-0002-4894-9587

Institute for Atmospheric and Earth System Research/Physics, Faculty of Science, University of Helsinki, Helsinki, 00014, Finland

Ella Häkkinen

https://orcid.org/0000-0002-9571-8925

Institute for Atmospheric and Earth System Research/Physics, Faculty of Science, University of Helsinki, Helsinki, 00014, Finland

Frans Graeffe

https://orcid.org/0000-0001-7304-4651

Institute for Atmospheric and Earth System Research/Physics, Faculty of Science, University of Helsinki, Helsinki, 00014, Finland

Jordan E. Krechmer

https://orcid.org/0000-0003-3642-0659

Aerodyne Research Inc., Billerica, Massachusetts 01821, United States

now at: Bruker Daltonics Inc., Billerica, Massachusetts 01821, United States

Manjula R. Canagaratna

https://orcid.org/0000-0002-8803-4007

Aerodyne Research Inc., Billerica, Massachusetts 01821, United States

Douglas R. Worsnop

Institute for Atmospheric and Earth System Research/Physics, Faculty of Science, University of Helsinki, Helsinki, 00014, Finland

Aerodyne Research Inc., Billerica, Massachusetts 01821, United States

Juha Kangasluoma

https://orcid.org/0000-0002-1639-1187

Institute for Atmospheric and Earth System Research/Physics, Faculty of Science, University of Helsinki, Helsinki, 00014, Finland

Mikael Ehn

CORRESPONDING AUTHOR

mikael.ehn@helsinki.fi

https://orcid.org/0000-0002-0215-4893

Institute for Atmospheric and Earth System Research/Physics, Faculty of Science, University of Helsinki, Helsinki, 00014, Finland

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PDF: 769
XML: 45
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BibTeX: 76
EndNote: 86

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Cumulative views and downloads (calculated since 28 Nov 2022)

Total article views: 2,901 (including HTML, PDF, and XML)

HTML	PDF	XML	Total	Supplement	BibTeX	EndNote
2,309	564	28	2,901	146	68	66

HTML: 2,309
PDF: 564
XML: 28
Total: 2,901
Supplement: 146
BibTeX: 68
EndNote: 66

Views and downloads (calculated since 28 Mar 2023)

Month	HTML	PDF	XML	Total
Mar 2023	457	72	4	533
Apr 2023	411	75	1	487
May 2023	128	34	0	162
Jun 2023	96	23	1	120
Jul 2023	111	36	1	148
Aug 2023	137	44	0	181
Sep 2023	85	34	1	120
Oct 2023	112	13	4	129
Nov 2023	58	11	0	69
Dec 2023	53	23	0	76
Jan 2024	34	14	0	48
Feb 2024	31	9	0	40
Mar 2024	46	13	1	60
Apr 2024	28	18	3	49
May 2024	45	14	1	60
Jun 2024	69	19	2	90
Jul 2024	52	16	2	70
Aug 2024	54	7	6	67
Sep 2024	34	8	0	42
Oct 2024	42	9	0	51
Nov 2024	36	11	1	48
Dec 2024	32	15	0	47
Jan 2025	42	12	0	54
Feb 2025	72	22	0	94
Mar 2025	44	12	0	56

Cumulative views and downloads (calculated since 28 Mar 2023)

Month	HTML	PDF	XML	Total
Mar 2023	457	72	4	533
Apr 2023	411	75	1	487
May 2023	128	34	0	162
Jun 2023	96	23	1	120
Jul 2023	111	36	1	148
Aug 2023	137	44	0	181
Sep 2023	85	34	1	120
Oct 2023	112	13	4	129
Nov 2023	58	11	0	69
Dec 2023	53	23	0	76
Jan 2024	34	14	0	48
Feb 2024	31	9	0	40
Mar 2024	46	13	1	60
Apr 2024	28	18	3	49
May 2024	45	14	1	60
Jun 2024	69	19	2	90
Jul 2024	52	16	2	70
Aug 2024	54	7	6	67
Sep 2024	34	8	0	42
Oct 2024	42	9	0	51
Nov 2024	36	11	1	48
Dec 2024	32	15	0	47
Jan 2025	42	12	0	54
Feb 2025	72	22	0	94
Mar 2025	44	12	0	56

Total article views: 694 (including HTML, PDF, and XML)

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472	205	17	694	63	8	20

HTML: 472
PDF: 205
XML: 17
Total: 694
Supplement: 63
BibTeX: 8
EndNote: 20

Views and downloads (calculated since 28 Nov 2022)

Month	HTML	PDF	XML	Total
Mar 2023	457	72	4	533
Apr 2023	411	75	1	487
May 2023	128	34	0	162
Jun 2023	96	23	1	120
Jul 2023	111	36	1	148
Aug 2023	137	44	0	181
Sep 2023	85	34	1	120
Oct 2023	112	13	4	129
Nov 2023	58	11	0	69
Dec 2023	53	23	0	76
Jan 2024	34	14	0	48
Feb 2024	31	9	0	40
Mar 2024	46	13	1	60
Apr 2024	28	18	3	49
May 2024	45	14	1	60
Jun 2024	69	19	2	90
Jul 2024	52	16	2	70
Aug 2024	54	7	6	67
Sep 2024	34	8	0	42
Oct 2024	42	9	0	51
Nov 2024	36	11	1	48
Dec 2024	32	15	0	47
Jan 2025	42	12	0	54
Feb 2025	72	22	0	94
Mar 2025	44	12	0	56

Cumulative views and downloads (calculated since 28 Nov 2022)

Month	HTML	PDF	XML	Total
Mar 2023	457	72	4	533
Apr 2023	411	75	1	487
May 2023	128	34	0	162
Jun 2023	96	23	1	120
Jul 2023	111	36	1	148
Aug 2023	137	44	0	181
Sep 2023	85	34	1	120
Oct 2023	112	13	4	129
Nov 2023	58	11	0	69
Dec 2023	53	23	0	76
Jan 2024	34	14	0	48
Feb 2024	31	9	0	40
Mar 2024	46	13	1	60
Apr 2024	28	18	3	49
May 2024	45	14	1	60
Jun 2024	69	19	2	90
Jul 2024	52	16	2	70
Aug 2024	54	7	6	67
Sep 2024	34	8	0	42
Oct 2024	42	9	0	51
Nov 2024	36	11	1	48
Dec 2024	32	15	0	47
Jan 2025	42	12	0	54
Feb 2025	72	22	0	94
Mar 2025	44	12	0	56

Viewed (geographical distribution)

Show all Final revised paper only Preprint only

Total article views: 3,595 (including HTML, PDF, and XML) Thereof 3,582 with geography defined and 13 with unknown origin.

Total article views: 2,901 (including HTML, PDF, and XML) Thereof 2,901 with geography defined and 0 with unknown origin.

Total article views: 694 (including HTML, PDF, and XML) Thereof 639 with geography defined and 55 with unknown origin.

Country	#	Views	%
United States of America	1	1335	37
China	2	810	22
Finland	3	265	7
United Kingdom	4	203	5
Germany	5	166	4

Country	#	Views	%
United States of America	1	1152	39
China	2	673	23
Finland	3	181	6
United Kingdom	4	169	5
Germany	5	117	4

Country	#	Views	%
United States of America	1	183	26
China	2	137	19
Finland	3	84	12
Germany	4	49	7
United Kingdom	5	34	4


Total:	0
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1335


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183

Cited

Show all Final revised paper only Preprint only

13 citations as recorded by crossref.

Comparison of Gaseous and Particulate Highly Oxygenated Organic Molecules from the Ozonolysis of Terpenes J. Zhao et al. 10.1021/acsestair.4c00121
Incomplete mass closure in atmospheric nanoparticle growth D. Stolzenburg et al. 10.1038/s41612-025-00893-5
Atmospheric nanoparticle growth D. Stolzenburg et al. 10.1103/RevModPhys.95.045002
The effects of photochemical aging and interactions with secondary organic aerosols on cellular toxicity of combustion particles R. Attah et al. 10.1016/j.jaerosci.2024.106473
Peroxides on the Surface of Organic Aerosol Particles Using Matrix-Assisted Ionization in Vacuum (MAIV) Mass Spectrometry Y. Qin et al. 10.1021/acs.est.3c02895
Characterization of the Vaporization Inlet for Aerosols (VIA) for online measurements of particulate highly oxygenated organic molecules (HOMs) J. Zhao et al. 10.5194/amt-17-1527-2024
Rapid Nucleation and Growth of Indoor Atmospheric Nanocluster Aerosol during the Use of Scented Volatile Chemical Products in Residential Buildings S. Patra et al. 10.1021/acsestair.4c00118
Explaining apparent particle shrinkage related to new particle formation events in western Saudi Arabia does not require evaporation S. Hakala et al. 10.5194/acp-23-9287-2023
Extending the Range of Detectable Trace Species with the Fast Polarity Switching of Chemical Ionization Orbitrap Mass Spectrometry R. Cai et al. 10.1021/acs.analchem.4c00650
On the potential use of highly oxygenated organic molecules (HOMs) as indicators for ozone formation sensitivity J. Zhang et al. 10.5194/acp-24-2885-2024
Differences in Secondary Organic Aerosol Formation from α-Pinene Photooxidation in a Chamber with Purified Air and Ambient Air as Matrices: Preliminary Results X. Li et al. 10.3390/atmos15020204
Formation and temperature dependence of highly oxygenated organic molecules (HOMs) from Δ3-carene ozonolysis Y. Luo et al. 10.5194/acp-24-9459-2024
New mechanism for the participation of aromatic oxidation products in atmospheric nucleation H. Zhang et al. 10.1016/j.scitotenv.2024.170487

13 citations as recorded by crossref.

Comparison of Gaseous and Particulate Highly Oxygenated Organic Molecules from the Ozonolysis of Terpenes J. Zhao et al. 10.1021/acsestair.4c00121
Incomplete mass closure in atmospheric nanoparticle growth D. Stolzenburg et al. 10.1038/s41612-025-00893-5
Atmospheric nanoparticle growth D. Stolzenburg et al. 10.1103/RevModPhys.95.045002
The effects of photochemical aging and interactions with secondary organic aerosols on cellular toxicity of combustion particles R. Attah et al. 10.1016/j.jaerosci.2024.106473
Peroxides on the Surface of Organic Aerosol Particles Using Matrix-Assisted Ionization in Vacuum (MAIV) Mass Spectrometry Y. Qin et al. 10.1021/acs.est.3c02895
Characterization of the Vaporization Inlet for Aerosols (VIA) for online measurements of particulate highly oxygenated organic molecules (HOMs) J. Zhao et al. 10.5194/amt-17-1527-2024
Rapid Nucleation and Growth of Indoor Atmospheric Nanocluster Aerosol during the Use of Scented Volatile Chemical Products in Residential Buildings S. Patra et al. 10.1021/acsestair.4c00118
Explaining apparent particle shrinkage related to new particle formation events in western Saudi Arabia does not require evaporation S. Hakala et al. 10.5194/acp-23-9287-2023
Extending the Range of Detectable Trace Species with the Fast Polarity Switching of Chemical Ionization Orbitrap Mass Spectrometry R. Cai et al. 10.1021/acs.analchem.4c00650
On the potential use of highly oxygenated organic molecules (HOMs) as indicators for ozone formation sensitivity J. Zhang et al. 10.5194/acp-24-2885-2024
Differences in Secondary Organic Aerosol Formation from α-Pinene Photooxidation in a Chamber with Purified Air and Ambient Air as Matrices: Preliminary Results X. Li et al. 10.3390/atmos15020204
Formation and temperature dependence of highly oxygenated organic molecules (HOMs) from Δ3-carene ozonolysis Y. Luo et al. 10.5194/acp-24-9459-2024
New mechanism for the participation of aromatic oxidation products in atmospheric nucleation H. Zhang et al. 10.1016/j.scitotenv.2024.170487

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Short summary

Based on the combined measurements of gas- and particle-phase highly oxygenated organic molecules (HOMs) from α-pinene ozonolysis, enhancement of dimers in particles was observed. We conducted experiments wherein the dimer to monomer (D / M) ratios of HOMs in the gas phase were modified (adding CO / NO) to investigate the effects of the corresponding D / M ratios in the particles. These results are important for a better understanding of secondary organic aerosol formation in the atmosphere.

Based on the combined measurements of gas- and particle-phase highly oxygenated organic...

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