Articles | Volume 23, issue 6
https://doi.org/10.5194/acp-23-3707-2023
© Author(s) 2023. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-23-3707-2023
© Author(s) 2023. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
A combined gas- and particle-phase analysis of highly oxygenated organic molecules (HOMs) from α-pinene ozonolysis
Institute for Atmospheric and Earth System Research/Physics, Faculty of Science, University of Helsinki, Helsinki, 00014, Finland
Ella Häkkinen
Institute for Atmospheric and Earth System Research/Physics, Faculty of Science, University of Helsinki, Helsinki, 00014, Finland
Frans Graeffe
Institute for Atmospheric and Earth System Research/Physics, Faculty of Science, University of Helsinki, Helsinki, 00014, Finland
Jordan E. Krechmer
Aerodyne Research Inc., Billerica, Massachusetts 01821, United States
now at: Bruker Daltonics Inc., Billerica, Massachusetts 01821, United States
Manjula R. Canagaratna
Aerodyne Research Inc., Billerica, Massachusetts 01821, United States
Douglas R. Worsnop
Institute for Atmospheric and Earth System Research/Physics, Faculty of Science, University of Helsinki, Helsinki, 00014, Finland
Aerodyne Research Inc., Billerica, Massachusetts 01821, United States
Juha Kangasluoma
Institute for Atmospheric and Earth System Research/Physics, Faculty of Science, University of Helsinki, Helsinki, 00014, Finland
Institute for Atmospheric and Earth System Research/Physics, Faculty of Science, University of Helsinki, Helsinki, 00014, Finland
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Cited
27 citations as recorded by crossref.
- Atmospheric nanoparticle growth D. Stolzenburg et al.
- The effects of photochemical aging and interactions with secondary organic aerosols on cellular toxicity of combustion particles R. Attah et al.
- Unveiling the Role of Chirality in the Oxidation of Monoterpenes L. Gao et al.
- Rapid Nucleation and Growth of Indoor Atmospheric Nanocluster Aerosol during the Use of Scented Volatile Chemical Products in Residential Buildings S. Patra et al.
- Positive matrix factorization reveals volatility-resolved composition from new particle formation during α-pinene ozonolysis J. Wakeen et al.
- Extending the Range of Detectable Trace Species with the Fast Polarity Switching of Chemical Ionization Orbitrap Mass Spectrometry R. Cai et al.
- On the potential use of highly oxygenated organic molecules (HOMs) as indicators for ozone formation sensitivity J. Zhang et al.
- Differences in Secondary Organic Aerosol Formation from α-Pinene Photooxidation in a Chamber with Purified Air and Ambient Air as Matrices: Preliminary Results X. Li et al.
- New mechanism for the participation of aromatic oxidation products in atmospheric nucleation H. Zhang et al.
- When Size Matters: Size-Selective Chemistry in the Heterogeneous Processing of Organic Aerosols M. Douverne & T. Hoffmann
- Comparison of Gaseous and Particulate Highly Oxygenated Organic Molecules from the Ozonolysis of Terpenes J. Zhao et al.
- Incomplete mass closure in atmospheric nanoparticle growth D. Stolzenburg et al.
- Atmospheric organic aerosols: online molecular characterization and environmental impacts Y. Sun et al.
- Uncertainties and Gaps in Comprehensive Kinetic Modeling of Secondary Organic Aerosol Formation from α-Pinene Ozonolysis C. Shen et al.
- Process-level simulation of chemical composition, size distribution and cloud condensation nuclei of secondary organic aerosol from α-pinene ozonolysis Z. Song et al.
- Peroxides on the Surface of Organic Aerosol Particles Using Matrix-Assisted Ionization in Vacuum (MAIV) Mass Spectrometry Y. Qin et al.
- Characterization of the newly designed wall-free particle evaporator (WALL-E) for online measurements of atmospheric particles L. Gao et al.
- Types of regional and localised new aerosol particle formation and growth processes: Atmospheric Banana Atlas I. Salma et al.
- Source-resolved volatility and oxidation state decoupling in wintertime organic aerosols in Seoul H. Kim et al.
- Characterization of the Vaporization Inlet for Aerosols (VIA) for online measurements of particulate highly oxygenated organic molecules (HOMs) J. Zhao et al.
- Explaining apparent particle shrinkage related to new particle formation events in western Saudi Arabia does not require evaporation S. Hakala et al.
- Probing the Fate of Highly Oxygenated Molecules in Atmospheric Aerosols P. Hao et al.
- Chemical Evolution of Monoterpene-Derived Secondary Organic Aerosols during Dark Aging F. Sari Doré et al.
- A simple, versatile approach for coupling a liquid chromatograph and chemical ionization mass spectrometer for offline analysis of organic aerosol A. Schaum et al.
- Formation and temperature dependence of highly oxygenated organic molecules (HOMs) from Δ3-carene ozonolysis Y. Luo et al.
- A mechanistic understanding of the varying yields of highly oxygenated organic molecules L. Yang et al.
- Molecular characterization of polar organic aerosols and their behaviors under varied PM2.5 levels in a typical populous megacity: Beijing of China H. Wang et al.
27 citations as recorded by crossref.
- Atmospheric nanoparticle growth D. Stolzenburg et al.
- The effects of photochemical aging and interactions with secondary organic aerosols on cellular toxicity of combustion particles R. Attah et al.
- Unveiling the Role of Chirality in the Oxidation of Monoterpenes L. Gao et al.
- Rapid Nucleation and Growth of Indoor Atmospheric Nanocluster Aerosol during the Use of Scented Volatile Chemical Products in Residential Buildings S. Patra et al.
- Positive matrix factorization reveals volatility-resolved composition from new particle formation during α-pinene ozonolysis J. Wakeen et al.
- Extending the Range of Detectable Trace Species with the Fast Polarity Switching of Chemical Ionization Orbitrap Mass Spectrometry R. Cai et al.
- On the potential use of highly oxygenated organic molecules (HOMs) as indicators for ozone formation sensitivity J. Zhang et al.
- Differences in Secondary Organic Aerosol Formation from α-Pinene Photooxidation in a Chamber with Purified Air and Ambient Air as Matrices: Preliminary Results X. Li et al.
- New mechanism for the participation of aromatic oxidation products in atmospheric nucleation H. Zhang et al.
- When Size Matters: Size-Selective Chemistry in the Heterogeneous Processing of Organic Aerosols M. Douverne & T. Hoffmann
- Comparison of Gaseous and Particulate Highly Oxygenated Organic Molecules from the Ozonolysis of Terpenes J. Zhao et al.
- Incomplete mass closure in atmospheric nanoparticle growth D. Stolzenburg et al.
- Atmospheric organic aerosols: online molecular characterization and environmental impacts Y. Sun et al.
- Uncertainties and Gaps in Comprehensive Kinetic Modeling of Secondary Organic Aerosol Formation from α-Pinene Ozonolysis C. Shen et al.
- Process-level simulation of chemical composition, size distribution and cloud condensation nuclei of secondary organic aerosol from α-pinene ozonolysis Z. Song et al.
- Peroxides on the Surface of Organic Aerosol Particles Using Matrix-Assisted Ionization in Vacuum (MAIV) Mass Spectrometry Y. Qin et al.
- Characterization of the newly designed wall-free particle evaporator (WALL-E) for online measurements of atmospheric particles L. Gao et al.
- Types of regional and localised new aerosol particle formation and growth processes: Atmospheric Banana Atlas I. Salma et al.
- Source-resolved volatility and oxidation state decoupling in wintertime organic aerosols in Seoul H. Kim et al.
- Characterization of the Vaporization Inlet for Aerosols (VIA) for online measurements of particulate highly oxygenated organic molecules (HOMs) J. Zhao et al.
- Explaining apparent particle shrinkage related to new particle formation events in western Saudi Arabia does not require evaporation S. Hakala et al.
- Probing the Fate of Highly Oxygenated Molecules in Atmospheric Aerosols P. Hao et al.
- Chemical Evolution of Monoterpene-Derived Secondary Organic Aerosols during Dark Aging F. Sari Doré et al.
- A simple, versatile approach for coupling a liquid chromatograph and chemical ionization mass spectrometer for offline analysis of organic aerosol A. Schaum et al.
- Formation and temperature dependence of highly oxygenated organic molecules (HOMs) from Δ3-carene ozonolysis Y. Luo et al.
- A mechanistic understanding of the varying yields of highly oxygenated organic molecules L. Yang et al.
- Molecular characterization of polar organic aerosols and their behaviors under varied PM2.5 levels in a typical populous megacity: Beijing of China H. Wang et al.
Saved (final revised paper)
Latest update: 28 Apr 2026
Short summary
Based on the combined measurements of gas- and particle-phase highly oxygenated organic molecules (HOMs) from α-pinene ozonolysis, enhancement of dimers in particles was observed. We conducted experiments wherein the dimer to monomer (D / M) ratios of HOMs in the gas phase were modified (adding CO / NO) to investigate the effects of the corresponding D / M ratios in the particles. These results are important for a better understanding of secondary organic aerosol formation in the atmosphere.
Based on the combined measurements of gas- and particle-phase highly oxygenated organic...
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