Articles | Volume 23, issue 6
https://doi.org/10.5194/acp-23-3707-2023
© Author(s) 2023. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-23-3707-2023
© Author(s) 2023. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
28 Mar 2023
Research article |
| 28 Mar 2023
| 28 Mar 2023
A combined gas- and particle-phase analysis of highly oxygenated organic molecules (HOMs) from α-pinene ozonolysis
Institute for Atmospheric and Earth System Research/Physics, Faculty of Science, University of Helsinki, Helsinki, 00014, Finland
Ella Häkkinen
Institute for Atmospheric and Earth System Research/Physics, Faculty of Science, University of Helsinki, Helsinki, 00014, Finland
Frans Graeffe
Institute for Atmospheric and Earth System Research/Physics, Faculty of Science, University of Helsinki, Helsinki, 00014, Finland
Jordan E. Krechmer
Aerodyne Research Inc., Billerica, Massachusetts 01821, United States
now at: Bruker Daltonics Inc., Billerica, Massachusetts 01821, United States
Manjula R. Canagaratna
Aerodyne Research Inc., Billerica, Massachusetts 01821, United States
Douglas R. Worsnop
Institute for Atmospheric and Earth System Research/Physics, Faculty of Science, University of Helsinki, Helsinki, 00014, Finland
Aerodyne Research Inc., Billerica, Massachusetts 01821, United States
Juha Kangasluoma
Institute for Atmospheric and Earth System Research/Physics, Faculty of Science, University of Helsinki, Helsinki, 00014, Finland
Institute for Atmospheric and Earth System Research/Physics, Faculty of Science, University of Helsinki, Helsinki, 00014, Finland
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Cited
13 citations as recorded by crossref.
- Comparison of Gaseous and Particulate Highly Oxygenated Organic Molecules from the Ozonolysis of Terpenes J. Zhao et al. 10.1021/acsestair.4c00121
- Incomplete mass closure in atmospheric nanoparticle growth D. Stolzenburg et al. 10.1038/s41612-025-00893-5
- Atmospheric nanoparticle growth D. Stolzenburg et al. 10.1103/RevModPhys.95.045002
- The effects of photochemical aging and interactions with secondary organic aerosols on cellular toxicity of combustion particles R. Attah et al. 10.1016/j.jaerosci.2024.106473
- Peroxides on the Surface of Organic Aerosol Particles Using Matrix-Assisted Ionization in Vacuum (MAIV) Mass Spectrometry Y. Qin et al. 10.1021/acs.est.3c02895
- Characterization of the Vaporization Inlet for Aerosols (VIA) for online measurements of particulate highly oxygenated organic molecules (HOMs) J. Zhao et al. 10.5194/amt-17-1527-2024
- Rapid Nucleation and Growth of Indoor Atmospheric Nanocluster Aerosol during the Use of Scented Volatile Chemical Products in Residential Buildings S. Patra et al. 10.1021/acsestair.4c00118
- Explaining apparent particle shrinkage related to new particle formation events in western Saudi Arabia does not require evaporation S. Hakala et al. 10.5194/acp-23-9287-2023
- Extending the Range of Detectable Trace Species with the Fast Polarity Switching of Chemical Ionization Orbitrap Mass Spectrometry R. Cai et al. 10.1021/acs.analchem.4c00650
- On the potential use of highly oxygenated organic molecules (HOMs) as indicators for ozone formation sensitivity J. Zhang et al. 10.5194/acp-24-2885-2024
- Differences in Secondary Organic Aerosol Formation from α-Pinene Photooxidation in a Chamber with Purified Air and Ambient Air as Matrices: Preliminary Results X. Li et al. 10.3390/atmos15020204
- Formation and temperature dependence of highly oxygenated organic molecules (HOMs) from Δ3-carene ozonolysis Y. Luo et al. 10.5194/acp-24-9459-2024
- New mechanism for the participation of aromatic oxidation products in atmospheric nucleation H. Zhang et al. 10.1016/j.scitotenv.2024.170487
13 citations as recorded by crossref.
- Comparison of Gaseous and Particulate Highly Oxygenated Organic Molecules from the Ozonolysis of Terpenes J. Zhao et al. 10.1021/acsestair.4c00121
- Incomplete mass closure in atmospheric nanoparticle growth D. Stolzenburg et al. 10.1038/s41612-025-00893-5
- Atmospheric nanoparticle growth D. Stolzenburg et al. 10.1103/RevModPhys.95.045002
- The effects of photochemical aging and interactions with secondary organic aerosols on cellular toxicity of combustion particles R. Attah et al. 10.1016/j.jaerosci.2024.106473
- Peroxides on the Surface of Organic Aerosol Particles Using Matrix-Assisted Ionization in Vacuum (MAIV) Mass Spectrometry Y. Qin et al. 10.1021/acs.est.3c02895
- Characterization of the Vaporization Inlet for Aerosols (VIA) for online measurements of particulate highly oxygenated organic molecules (HOMs) J. Zhao et al. 10.5194/amt-17-1527-2024
- Rapid Nucleation and Growth of Indoor Atmospheric Nanocluster Aerosol during the Use of Scented Volatile Chemical Products in Residential Buildings S. Patra et al. 10.1021/acsestair.4c00118
- Explaining apparent particle shrinkage related to new particle formation events in western Saudi Arabia does not require evaporation S. Hakala et al. 10.5194/acp-23-9287-2023
- Extending the Range of Detectable Trace Species with the Fast Polarity Switching of Chemical Ionization Orbitrap Mass Spectrometry R. Cai et al. 10.1021/acs.analchem.4c00650
- On the potential use of highly oxygenated organic molecules (HOMs) as indicators for ozone formation sensitivity J. Zhang et al. 10.5194/acp-24-2885-2024
- Differences in Secondary Organic Aerosol Formation from α-Pinene Photooxidation in a Chamber with Purified Air and Ambient Air as Matrices: Preliminary Results X. Li et al. 10.3390/atmos15020204
- Formation and temperature dependence of highly oxygenated organic molecules (HOMs) from Δ3-carene ozonolysis Y. Luo et al. 10.5194/acp-24-9459-2024
- New mechanism for the participation of aromatic oxidation products in atmospheric nucleation H. Zhang et al. 10.1016/j.scitotenv.2024.170487
Latest update: 23 Apr 2025
Short summary
Based on the combined measurements of gas- and particle-phase highly oxygenated organic molecules (HOMs) from α-pinene ozonolysis, enhancement of dimers in particles was observed. We conducted experiments wherein the dimer to monomer (D / M) ratios of HOMs in the gas phase were modified (adding CO / NO) to investigate the effects of the corresponding D / M ratios in the particles. These results are important for a better understanding of secondary organic aerosol formation in the atmosphere.
Based on the combined measurements of gas- and particle-phase highly oxygenated organic...
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