Articles | Volume 23, issue 6
https://doi.org/10.5194/acp-23-3707-2023
© Author(s) 2023. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-23-3707-2023
© Author(s) 2023. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
28 Mar 2023
Research article |
| 28 Mar 2023
| 28 Mar 2023
A combined gas- and particle-phase analysis of highly oxygenated organic molecules (HOMs) from α-pinene ozonolysis
Institute for Atmospheric and Earth System Research/Physics, Faculty of Science, University of Helsinki, Helsinki, 00014, Finland
Ella Häkkinen
Institute for Atmospheric and Earth System Research/Physics, Faculty of Science, University of Helsinki, Helsinki, 00014, Finland
Frans Graeffe
Institute for Atmospheric and Earth System Research/Physics, Faculty of Science, University of Helsinki, Helsinki, 00014, Finland
Jordan E. Krechmer
Aerodyne Research Inc., Billerica, Massachusetts 01821, United States
now at: Bruker Daltonics Inc., Billerica, Massachusetts 01821, United States
Manjula R. Canagaratna
Aerodyne Research Inc., Billerica, Massachusetts 01821, United States
Douglas R. Worsnop
Institute for Atmospheric and Earth System Research/Physics, Faculty of Science, University of Helsinki, Helsinki, 00014, Finland
Aerodyne Research Inc., Billerica, Massachusetts 01821, United States
Juha Kangasluoma
Institute for Atmospheric and Earth System Research/Physics, Faculty of Science, University of Helsinki, Helsinki, 00014, Finland
Institute for Atmospheric and Earth System Research/Physics, Faculty of Science, University of Helsinki, Helsinki, 00014, Finland
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Cited
27 citations as recorded by crossref.
- Atmospheric nanoparticle growth D. Stolzenburg et al. https://doi.org/10.1103/RevModPhys.95.045002
- The effects of photochemical aging and interactions with secondary organic aerosols on cellular toxicity of combustion particles R. Attah et al. https://doi.org/10.1016/j.jaerosci.2024.106473
- Unveiling the Role of Chirality in the Oxidation of Monoterpenes L. Gao et al. https://doi.org/10.1021/jacs.5c06118
- Rapid Nucleation and Growth of Indoor Atmospheric Nanocluster Aerosol during the Use of Scented Volatile Chemical Products in Residential Buildings S. Patra et al. https://doi.org/10.1021/acsestair.4c00118
- Positive matrix factorization reveals volatility-resolved composition from new particle formation during α-pinene ozonolysis J. Wakeen et al. https://doi.org/10.1080/02786826.2026.2649824
- Extending the Range of Detectable Trace Species with the Fast Polarity Switching of Chemical Ionization Orbitrap Mass Spectrometry R. Cai et al. https://doi.org/10.1021/acs.analchem.4c00650
- On the potential use of highly oxygenated organic molecules (HOMs) as indicators for ozone formation sensitivity J. Zhang et al. https://doi.org/10.5194/acp-24-2885-2024
- Differences in Secondary Organic Aerosol Formation from α-Pinene Photooxidation in a Chamber with Purified Air and Ambient Air as Matrices: Preliminary Results X. Li et al. https://doi.org/10.3390/atmos15020204
- New mechanism for the participation of aromatic oxidation products in atmospheric nucleation H. Zhang et al. https://doi.org/10.1016/j.scitotenv.2024.170487
- When Size Matters: Size-Selective Chemistry in the Heterogeneous Processing of Organic Aerosols M. Douverne & T. Hoffmann https://doi.org/10.1021/acsestair.5c00189
- Comparison of Gaseous and Particulate Highly Oxygenated Organic Molecules from the Ozonolysis of Terpenes J. Zhao et al. https://doi.org/10.1021/acsestair.4c00121
- Incomplete mass closure in atmospheric nanoparticle growth D. Stolzenburg et al. https://doi.org/10.1038/s41612-025-00893-5
- Atmospheric organic aerosols: online molecular characterization and environmental impacts Y. Sun et al. https://doi.org/10.1038/s41612-025-01199-2
- Uncertainties and Gaps in Comprehensive Kinetic Modeling of Secondary Organic Aerosol Formation from α-Pinene Ozonolysis C. Shen et al. https://doi.org/10.1021/acsestair.5c00360
- Process-level simulation of chemical composition, size distribution and cloud condensation nuclei of secondary organic aerosol from α-pinene ozonolysis Z. Song et al. https://doi.org/10.5194/acp-26-2769-2026
- Peroxides on the Surface of Organic Aerosol Particles Using Matrix-Assisted Ionization in Vacuum (MAIV) Mass Spectrometry Y. Qin et al. https://doi.org/10.1021/acs.est.3c02895
- Characterization of the newly designed wall-free particle evaporator (WALL-E) for online measurements of atmospheric particles L. Gao et al. https://doi.org/10.5194/amt-18-5087-2025
- Types of regional and localised new aerosol particle formation and growth processes: Atmospheric Banana Atlas I. Salma et al. https://doi.org/10.1038/s41612-025-01149-y
- Source-resolved volatility and oxidation state decoupling in wintertime organic aerosols in Seoul H. Kim et al. https://doi.org/10.5194/acp-26-1145-2026
- Characterization of the Vaporization Inlet for Aerosols (VIA) for online measurements of particulate highly oxygenated organic molecules (HOMs) J. Zhao et al. https://doi.org/10.5194/amt-17-1527-2024
- Explaining apparent particle shrinkage related to new particle formation events in western Saudi Arabia does not require evaporation S. Hakala et al. https://doi.org/10.5194/acp-23-9287-2023
- Probing the Fate of Highly Oxygenated Molecules in Atmospheric Aerosols P. Hao et al. https://doi.org/10.1021/acs.est.4c07748
- Chemical Evolution of Monoterpene-Derived Secondary Organic Aerosols during Dark Aging F. Sari Doré et al. https://doi.org/10.1021/acsestair.5c00196
- A simple, versatile approach for coupling a liquid chromatograph and chemical ionization mass spectrometer for offline analysis of organic aerosol A. Schaum et al. https://doi.org/10.5194/ar-3-557-2025
- Formation and temperature dependence of highly oxygenated organic molecules (HOMs) from Δ3-carene ozonolysis Y. Luo et al. https://doi.org/10.5194/acp-24-9459-2024
- A mechanistic understanding of the varying yields of highly oxygenated organic molecules L. Yang et al. https://doi.org/10.1038/s41467-025-67007-w
- Molecular characterization of polar organic aerosols and their behaviors under varied PM2.5 levels in a typical populous megacity: Beijing of China H. Wang et al. https://doi.org/10.1016/j.envres.2025.121971
27 citations as recorded by crossref.
- Atmospheric nanoparticle growth D. Stolzenburg et al. https://doi.org/10.1103/RevModPhys.95.045002
- The effects of photochemical aging and interactions with secondary organic aerosols on cellular toxicity of combustion particles R. Attah et al. https://doi.org/10.1016/j.jaerosci.2024.106473
- Unveiling the Role of Chirality in the Oxidation of Monoterpenes L. Gao et al. https://doi.org/10.1021/jacs.5c06118
- Rapid Nucleation and Growth of Indoor Atmospheric Nanocluster Aerosol during the Use of Scented Volatile Chemical Products in Residential Buildings S. Patra et al. https://doi.org/10.1021/acsestair.4c00118
- Positive matrix factorization reveals volatility-resolved composition from new particle formation during α-pinene ozonolysis J. Wakeen et al. https://doi.org/10.1080/02786826.2026.2649824
- Extending the Range of Detectable Trace Species with the Fast Polarity Switching of Chemical Ionization Orbitrap Mass Spectrometry R. Cai et al. https://doi.org/10.1021/acs.analchem.4c00650
- On the potential use of highly oxygenated organic molecules (HOMs) as indicators for ozone formation sensitivity J. Zhang et al. https://doi.org/10.5194/acp-24-2885-2024
- Differences in Secondary Organic Aerosol Formation from α-Pinene Photooxidation in a Chamber with Purified Air and Ambient Air as Matrices: Preliminary Results X. Li et al. https://doi.org/10.3390/atmos15020204
- New mechanism for the participation of aromatic oxidation products in atmospheric nucleation H. Zhang et al. https://doi.org/10.1016/j.scitotenv.2024.170487
- When Size Matters: Size-Selective Chemistry in the Heterogeneous Processing of Organic Aerosols M. Douverne & T. Hoffmann https://doi.org/10.1021/acsestair.5c00189
- Comparison of Gaseous and Particulate Highly Oxygenated Organic Molecules from the Ozonolysis of Terpenes J. Zhao et al. https://doi.org/10.1021/acsestair.4c00121
- Incomplete mass closure in atmospheric nanoparticle growth D. Stolzenburg et al. https://doi.org/10.1038/s41612-025-00893-5
- Atmospheric organic aerosols: online molecular characterization and environmental impacts Y. Sun et al. https://doi.org/10.1038/s41612-025-01199-2
- Uncertainties and Gaps in Comprehensive Kinetic Modeling of Secondary Organic Aerosol Formation from α-Pinene Ozonolysis C. Shen et al. https://doi.org/10.1021/acsestair.5c00360
- Process-level simulation of chemical composition, size distribution and cloud condensation nuclei of secondary organic aerosol from α-pinene ozonolysis Z. Song et al. https://doi.org/10.5194/acp-26-2769-2026
- Peroxides on the Surface of Organic Aerosol Particles Using Matrix-Assisted Ionization in Vacuum (MAIV) Mass Spectrometry Y. Qin et al. https://doi.org/10.1021/acs.est.3c02895
- Characterization of the newly designed wall-free particle evaporator (WALL-E) for online measurements of atmospheric particles L. Gao et al. https://doi.org/10.5194/amt-18-5087-2025
- Types of regional and localised new aerosol particle formation and growth processes: Atmospheric Banana Atlas I. Salma et al. https://doi.org/10.1038/s41612-025-01149-y
- Source-resolved volatility and oxidation state decoupling in wintertime organic aerosols in Seoul H. Kim et al. https://doi.org/10.5194/acp-26-1145-2026
- Characterization of the Vaporization Inlet for Aerosols (VIA) for online measurements of particulate highly oxygenated organic molecules (HOMs) J. Zhao et al. https://doi.org/10.5194/amt-17-1527-2024
- Explaining apparent particle shrinkage related to new particle formation events in western Saudi Arabia does not require evaporation S. Hakala et al. https://doi.org/10.5194/acp-23-9287-2023
- Probing the Fate of Highly Oxygenated Molecules in Atmospheric Aerosols P. Hao et al. https://doi.org/10.1021/acs.est.4c07748
- Chemical Evolution of Monoterpene-Derived Secondary Organic Aerosols during Dark Aging F. Sari Doré et al. https://doi.org/10.1021/acsestair.5c00196
- A simple, versatile approach for coupling a liquid chromatograph and chemical ionization mass spectrometer for offline analysis of organic aerosol A. Schaum et al. https://doi.org/10.5194/ar-3-557-2025
- Formation and temperature dependence of highly oxygenated organic molecules (HOMs) from Δ3-carene ozonolysis Y. Luo et al. https://doi.org/10.5194/acp-24-9459-2024
- A mechanistic understanding of the varying yields of highly oxygenated organic molecules L. Yang et al. https://doi.org/10.1038/s41467-025-67007-w
- Molecular characterization of polar organic aerosols and their behaviors under varied PM2.5 levels in a typical populous megacity: Beijing of China H. Wang et al. https://doi.org/10.1016/j.envres.2025.121971
Saved (final revised paper)
Latest update: 07 Jun 2026
Short summary
Based on the combined measurements of gas- and particle-phase highly oxygenated organic molecules (HOMs) from α-pinene ozonolysis, enhancement of dimers in particles was observed. We conducted experiments wherein the dimer to monomer (D / M) ratios of HOMs in the gas phase were modified (adding CO / NO) to investigate the effects of the corresponding D / M ratios in the particles. These results are important for a better understanding of secondary organic aerosol formation in the atmosphere.
Based on the combined measurements of gas- and particle-phase highly oxygenated organic...
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