Articles | Volume 23, issue 4
https://doi.org/10.5194/acp-23-2859-2023
© Author(s) 2023. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-23-2859-2023
© Author(s) 2023. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
02 Mar 2023
Research article |
| 02 Mar 2023
| 02 Mar 2023
Comparison of aqueous secondary organic aerosol (aqSOA) product distributions from guaiacol oxidation by non-phenolic and phenolic methoxybenzaldehydes as photosensitizers in the absence and presence of ammonium nitrate
Brix Raphael Go
School of Energy and Environment, City University of Hong Kong, Kowloon, Hong Kong SAR, China
City University of Hong Kong Shenzhen Research Institute, Shenzhen 518057, China
Yong Jie Li
Department of Civil and Environmental Engineering, and Centre for Regional Oceans, Faculty of Science and Technology, University of Macau, Taipa, Macau SAR 999078, China
Dan Dan Huang
State Environmental Protection Key Laboratory of Formation and Prevention of the Urban Air Pollution Complex, Shanghai Academy of Environmental Sciences, Shanghai 200233, China
Yalin Wang
Department of Civil and Environmental Engineering, and Centre for Regional Oceans, Faculty of Science and Technology, University of Macau, Taipa, Macau SAR 999078, China
School of Energy and Environment, City University of Hong Kong, Kowloon, Hong Kong SAR, China
City University of Hong Kong Shenzhen Research Institute, Shenzhen 518057, China
Low-Carbon and Climate Impact Research Centre of School of Energy and Environment, City University of Hong Kong, Hong Kong SAR, China
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Cited
17 citations as recorded by crossref.
- Unsaturated Fatty Acids Enhance Aqueous Atmospheric Oxidation Ability by Producing Oxygen‐Containing Radicals in Fog Droplets N. Yang et al. 10.1029/2022JD038069
- Seasonal variations in the production of singlet oxygen and organic triplet excited states in aqueous PM2.5 in Hong Kong SAR, South China Y. Lyu et al. 10.5194/acp-23-9245-2023
- Photoinduced Reactions of Nitrate in Aqueous Microdroplets by Triplet Energy Transfer P. Kim et al. 10.1021/acs.jpclett.3c02178
- Deciphering the key drivers of oxidative potential during ammonium nitrate-mediated aqueous-phase photoreaction of methoxyphenols R. Lai et al. 10.1016/j.atmosenv.2024.120895
- Multiphase Guaiacol Photooxidation: Fenton Reactions, Brown Carbon, and Secondary Organic Aerosol Formation in Suspended Aerosol Particles D. De Haan et al. 10.1021/acsestair.3c00057
- Complexities of Photosensitization in Atmospheric Particles Z. Liang et al. 10.1021/acsestair.4c00112
- Enhanced HONO Formation from Aqueous Nitrate Photochemistry in the Presence of Marine Relevant Organics: Impact of Marine-Dissolved Organic Matter (m-DOM) Concentration on HONO Yields and Potential Synergistic Effects of Compounds within m-DOM S. Mora García et al. 10.1021/acsestair.4c00006
- Aqueous Photosensitization of Syringaldehyde: Reactivity, Effects of Environmental Factors, and Formation of Brown Carbon Products F. Li et al. 10.1021/acsearthspacechem.4c00004
- Sulfate formation via aerosol-phase SO2 oxidation by model biomass burning photosensitizers: 3,4-dimethoxybenzaldehyde, vanillin and syringaldehyde using single-particle mixing-state analysis L. Zhou et al. 10.5194/acp-23-5251-2023
- Aqueous-Phase Photooxidation of Vanillin in the Presence of Nitrite: Characteristics, Products, and Mechanism M. Cai et al. 10.1021/acsestair.4c00013
- Liquid phase transformation mechanism of β-caryophyllonic acid initiated by hydroxyl radicals and ozone in atmosphere C. Sun et al. 10.1016/j.chemosphere.2024.143257
- Contribution of Carbonyl Chromophores in Secondary Brown Carbon from Nighttime Oxidation of Unsaturated Heterocyclic Volatile Organic Compounds K. Chen et al. 10.1021/acs.est.3c08872
- Photoaging of phenolic secondary organic aerosol in the aqueous phase: evolution of chemical and optical properties and effects of oxidants W. Jiang et al. 10.5194/acp-23-7103-2023
- Aqueous photochemical aging of water-soluble smoke particles from crop straws burning Z. Ye et al. 10.1016/j.atmosenv.2024.120897
- Aqueous-Phase Photoreactions of Mixed Aromatic Carbonyl Photosensitizers Yield More Oxygenated, Oxidized, and less Light-Absorbing Secondary Organic Aerosol (SOA) than Single Systems B. Go et al. 10.1021/acs.est.3c10199
- Effects of copper on chemical kinetics and brown carbon formation in the aqueous ˙OH oxidation of phenolic compounds J. Yang et al. 10.1039/D4EM00191E
- The High Pressure Inside Aerosol Particles Enhances Photochemical Reactions of Biomass Burning Compounds C. Dubois et al. 10.1021/acsearthspacechem.4c00011
16 citations as recorded by crossref.
- Unsaturated Fatty Acids Enhance Aqueous Atmospheric Oxidation Ability by Producing Oxygen‐Containing Radicals in Fog Droplets N. Yang et al. 10.1029/2022JD038069
- Seasonal variations in the production of singlet oxygen and organic triplet excited states in aqueous PM2.5 in Hong Kong SAR, South China Y. Lyu et al. 10.5194/acp-23-9245-2023
- Photoinduced Reactions of Nitrate in Aqueous Microdroplets by Triplet Energy Transfer P. Kim et al. 10.1021/acs.jpclett.3c02178
- Deciphering the key drivers of oxidative potential during ammonium nitrate-mediated aqueous-phase photoreaction of methoxyphenols R. Lai et al. 10.1016/j.atmosenv.2024.120895
- Multiphase Guaiacol Photooxidation: Fenton Reactions, Brown Carbon, and Secondary Organic Aerosol Formation in Suspended Aerosol Particles D. De Haan et al. 10.1021/acsestair.3c00057
- Complexities of Photosensitization in Atmospheric Particles Z. Liang et al. 10.1021/acsestair.4c00112
- Enhanced HONO Formation from Aqueous Nitrate Photochemistry in the Presence of Marine Relevant Organics: Impact of Marine-Dissolved Organic Matter (m-DOM) Concentration on HONO Yields and Potential Synergistic Effects of Compounds within m-DOM S. Mora García et al. 10.1021/acsestair.4c00006
- Aqueous Photosensitization of Syringaldehyde: Reactivity, Effects of Environmental Factors, and Formation of Brown Carbon Products F. Li et al. 10.1021/acsearthspacechem.4c00004
- Sulfate formation via aerosol-phase SO2 oxidation by model biomass burning photosensitizers: 3,4-dimethoxybenzaldehyde, vanillin and syringaldehyde using single-particle mixing-state analysis L. Zhou et al. 10.5194/acp-23-5251-2023
- Aqueous-Phase Photooxidation of Vanillin in the Presence of Nitrite: Characteristics, Products, and Mechanism M. Cai et al. 10.1021/acsestair.4c00013
- Liquid phase transformation mechanism of β-caryophyllonic acid initiated by hydroxyl radicals and ozone in atmosphere C. Sun et al. 10.1016/j.chemosphere.2024.143257
- Contribution of Carbonyl Chromophores in Secondary Brown Carbon from Nighttime Oxidation of Unsaturated Heterocyclic Volatile Organic Compounds K. Chen et al. 10.1021/acs.est.3c08872
- Photoaging of phenolic secondary organic aerosol in the aqueous phase: evolution of chemical and optical properties and effects of oxidants W. Jiang et al. 10.5194/acp-23-7103-2023
- Aqueous photochemical aging of water-soluble smoke particles from crop straws burning Z. Ye et al. 10.1016/j.atmosenv.2024.120897
- Aqueous-Phase Photoreactions of Mixed Aromatic Carbonyl Photosensitizers Yield More Oxygenated, Oxidized, and less Light-Absorbing Secondary Organic Aerosol (SOA) than Single Systems B. Go et al. 10.1021/acs.est.3c10199
- Effects of copper on chemical kinetics and brown carbon formation in the aqueous ˙OH oxidation of phenolic compounds J. Yang et al. 10.1039/D4EM00191E
Latest update: 12 Nov 2024
Short summary
We compared non-phenolic and phenolic methoxybenzaldehydes as photosensitizers for aqueous secondary organic aerosol (aqSOA) formation under cloud and fog conditions. We showed that the structural features of photosensitizers affect aqSOA formation. We also elucidated potential interactions between photosensitization and ammonium nitrate photolysis. Our findings are useful for evaluating the importance of photosensitized reactions on aqSOA formation, which could improve aqSOA predictive models.
We compared non-phenolic and phenolic methoxybenzaldehydes as photosensitizers for aqueous...
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