Articles | Volume 23, issue 24
https://doi.org/10.5194/acp-23-15537-2023
© Author(s) 2023. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-23-15537-2023
© Author(s) 2023. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
20 Dec 2023
Research article |
| 20 Dec 2023
| 20 Dec 2023
Gas–particle partitioning of toluene oxidation products: an experimental and modeling study
CEREA, École des Ponts ParisTech, EDF R&D, IPSL, 77455 Marne-la-Vallée, France
Aix Marseille Univ, CNRS, LCE, Marseille, France
Evangelia Kostenidou
Aix Marseille Univ, CNRS, LCE, Marseille, France
now at: Department of Environmental Engineering, Democritus University of Thrace, 67100 Xanthi, Greece
Florian Couvidat
National Institute for Industrial Environment and Risks (INERIS), 60 550 Verneuil-en-Halatte, France
Alvaro Martinez-Valiente
Aix Marseille Univ, CNRS, LCE, Marseille, France
Philipp Eichler
Institute for Ion and Applied Physics, University of Innsbruck, 6020 Innsbruck, Austria
now at: German Environment Agency, Dessau, Germany
Armin Wisthaler
Institute for Ion and Applied Physics, University of Innsbruck, 6020 Innsbruck, Austria
Department of Chemistry, University of Oslo, 0315 Oslo, Norway
Markus Müller
Ionicon Analytik GmbH, 6020 Innsbruck, Austria
Brice Temime-Roussel
Aix Marseille Univ, CNRS, LCE, Marseille, France
Richard Valorso
Univ Paris Est Creteil and Université Paris Cité, CNRS, LISA, 94010 Créteil, France
Karine Sartelet
CEREA, École des Ponts ParisTech, EDF R&D, IPSL, 77455 Marne-la-Vallée, France
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Cited
17 citations as recorded by crossref.
- Spatiotemporal Evolution, Secondary Transformation and Control of Cooking Oil Fumes in Open-Plan Kitchens Y. Cui et al. https://doi.org/10.1021/acs.est.5c10491
- Ship Emission Factors for Volatile Organic Compounds and PM1 from land-based observations in an Emission Control Area of France E. Volent et al. https://doi.org/10.1016/j.aeaoa.2026.100459
- In situ measurements of gas–particle partitioning of organic compounds in Fairbanks A. Ijaz et al. https://doi.org/10.1039/D4FD00175C
- The impact of CO on secondary organic aerosols formed from the mixture of α-pinene and n-dodecane G. Xie et al. https://doi.org/10.5194/acp-26-9679-2026
- Modeling the molecular composition of secondary organic aerosol under highly polluted conditions: A case study in the Yangtze River Delta Region in China Q. Huang et al. https://doi.org/10.1016/j.scitotenv.2024.173327
- Modelling molecular composition of SOA from toluene photo-oxidation at urban and street scales K. Sartelet et al. https://doi.org/10.1039/D4EA00049H
- Development of a detailed gaseous oxidation scheme of naphthalene for secondary organic aerosol (SOA) formation and speciation V. Lannuque & K. Sartelet https://doi.org/10.5194/acp-24-8589-2024
- A new approach to detection of highly oxidized products from ethylbenzene oxidation using matrix assisted ionization in vacuum-mass spectrometry L. Wingen et al. https://doi.org/10.1039/D6EA00043F
- Secondary organic aerosol formed by Euro 5 gasoline vehicle emissions: chemical composition and gas-to-particle phase partitioning E. Kostenidou et al. https://doi.org/10.5194/acp-24-2705-2024
- Characterization of biogenic volatile organic compounds and their oxidation products in a stressed spruce-dominated forest close to a biogas power plant J. Song et al. https://doi.org/10.5194/acp-24-13199-2024
- Process-level simulation of chemical composition, size distribution and cloud condensation nuclei of secondary organic aerosol from α-pinene ozonolysis Z. Song et al. https://doi.org/10.5194/acp-26-2769-2026
- Molecular Tracking the Formation and Aging of Secondary Organic Aerosol from Benzothiazole Photooxidation Y. Zhan et al. https://doi.org/10.1021/acs.est.5c17162
- Complementary aerosol mass spectrometry elucidates sources of wintertime submicron particle pollution in Fairbanks, Alaska, during ALPACA 2022 A. Ijaz et al. https://doi.org/10.5194/acp-25-11789-2025
- Gas–particle partitioning of m-xylene and naphthalene oxidation products: temperature and NOx influence M. Shahin et al. https://doi.org/10.5194/acp-25-10267-2025
- Sources, concentrations, and seasonal variations of VOC and aerosol particles in downtown Munich in 2023/2024 Y. Li et al. https://doi.org/10.5194/acp-26-5813-2026
- Advanced modeling of gas chemistry and aerosol dynamics with SSH-aerosol v2.0 K. Sartelet et al. https://doi.org/10.5194/gmd-19-389-2026
- Exploring biogenic secondary organic aerosol using a PTRMS-CHARON in laboratory experiments: characterization and fingerprint analysis C. Ramírez-Romero et al. https://doi.org/10.5194/amt-19-3049-2026
17 citations as recorded by crossref.
- Spatiotemporal Evolution, Secondary Transformation and Control of Cooking Oil Fumes in Open-Plan Kitchens Y. Cui et al. https://doi.org/10.1021/acs.est.5c10491
- Ship Emission Factors for Volatile Organic Compounds and PM1 from land-based observations in an Emission Control Area of France E. Volent et al. https://doi.org/10.1016/j.aeaoa.2026.100459
- In situ measurements of gas–particle partitioning of organic compounds in Fairbanks A. Ijaz et al. https://doi.org/10.1039/D4FD00175C
- The impact of CO on secondary organic aerosols formed from the mixture of α-pinene and n-dodecane G. Xie et al. https://doi.org/10.5194/acp-26-9679-2026
- Modeling the molecular composition of secondary organic aerosol under highly polluted conditions: A case study in the Yangtze River Delta Region in China Q. Huang et al. https://doi.org/10.1016/j.scitotenv.2024.173327
- Modelling molecular composition of SOA from toluene photo-oxidation at urban and street scales K. Sartelet et al. https://doi.org/10.1039/D4EA00049H
- Development of a detailed gaseous oxidation scheme of naphthalene for secondary organic aerosol (SOA) formation and speciation V. Lannuque & K. Sartelet https://doi.org/10.5194/acp-24-8589-2024
- A new approach to detection of highly oxidized products from ethylbenzene oxidation using matrix assisted ionization in vacuum-mass spectrometry L. Wingen et al. https://doi.org/10.1039/D6EA00043F
- Secondary organic aerosol formed by Euro 5 gasoline vehicle emissions: chemical composition and gas-to-particle phase partitioning E. Kostenidou et al. https://doi.org/10.5194/acp-24-2705-2024
- Characterization of biogenic volatile organic compounds and their oxidation products in a stressed spruce-dominated forest close to a biogas power plant J. Song et al. https://doi.org/10.5194/acp-24-13199-2024
- Process-level simulation of chemical composition, size distribution and cloud condensation nuclei of secondary organic aerosol from α-pinene ozonolysis Z. Song et al. https://doi.org/10.5194/acp-26-2769-2026
- Molecular Tracking the Formation and Aging of Secondary Organic Aerosol from Benzothiazole Photooxidation Y. Zhan et al. https://doi.org/10.1021/acs.est.5c17162
- Complementary aerosol mass spectrometry elucidates sources of wintertime submicron particle pollution in Fairbanks, Alaska, during ALPACA 2022 A. Ijaz et al. https://doi.org/10.5194/acp-25-11789-2025
- Gas–particle partitioning of m-xylene and naphthalene oxidation products: temperature and NOx influence M. Shahin et al. https://doi.org/10.5194/acp-25-10267-2025
- Sources, concentrations, and seasonal variations of VOC and aerosol particles in downtown Munich in 2023/2024 Y. Li et al. https://doi.org/10.5194/acp-26-5813-2026
- Advanced modeling of gas chemistry and aerosol dynamics with SSH-aerosol v2.0 K. Sartelet et al. https://doi.org/10.5194/gmd-19-389-2026
- Exploring biogenic secondary organic aerosol using a PTRMS-CHARON in laboratory experiments: characterization and fingerprint analysis C. Ramírez-Romero et al. https://doi.org/10.5194/amt-19-3049-2026
Saved (final revised paper)
Latest update: 21 Jul 2026
Short summary
Large uncertainties remain in understanding secondary organic aerosol (SOA) formation from toluene oxidation. In this study, speciation measurements in gaseous and particulate phases were carried out, providing partitioning and volatility data on individual toluene SOA components at different temperatures. A new detailed oxidation mechanism was developed to improve modeled speciation, and effects of different processes involved in gas–particle partitioning at the molecular scale are explored.
Large uncertainties remain in understanding secondary organic aerosol (SOA) formation from...
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