Articles | Volume 23, issue 24
https://doi.org/10.5194/acp-23-15537-2023
https://doi.org/10.5194/acp-23-15537-2023
Research article
 | 
20 Dec 2023
Research article |  | 20 Dec 2023

Gas–particle partitioning of toluene oxidation products: an experimental and modeling study

Victor Lannuque, Barbara D'Anna, Evangelia Kostenidou, Florian Couvidat, Alvaro Martinez-Valiente, Philipp Eichler, Armin Wisthaler, Markus Müller, Brice Temime-Roussel, Richard Valorso, and Karine Sartelet

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Latest update: 13 Dec 2024
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Short summary
Large uncertainties remain in understanding secondary organic aerosol (SOA) formation from toluene oxidation. In this study, speciation measurements in gaseous and particulate phases were carried out, providing partitioning and volatility data on individual toluene SOA components at different temperatures. A new detailed oxidation mechanism was developed to improve modeled speciation, and effects of different processes involved in gas–particle partitioning at the molecular scale are explored.
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