Gas–particle partitioning of toluene oxidation products: an experimental and modeling study

Lannuque, Victor; D'Anna, Barbara; Kostenidou, Evangelia; Couvidat, Florian; Martinez-Valiente, Alvaro; Eichler, Philipp; Wisthaler, Armin; Müller, Markus; Temime-Roussel, Brice; Valorso, Richard; Sartelet, Karine

doi:https://doi.org/10.5194/acp-23-15537-2023

Articles | Volume 23, issue 24

Article
Peer review
Metrics
Related articles

Articles | Volume 23, issue 24

https://doi.org/10.5194/acp-23-15537-2023

Articles | Volume 23, issue 24

Article
Peer review
Metrics
Related articles

Research article

20 Dec 2023

Research article |

| 20 Dec 2023

Gas–particle partitioning of toluene oxidation products: an experimental and modeling study

Victor Lannuque, Barbara D'Anna, Evangelia Kostenidou, Florian Couvidat, Alvaro Martinez-Valiente, Philipp Eichler, Armin Wisthaler, Markus Müller, Brice Temime-Roussel, Richard Valorso, and Karine Sartelet

Victor Lannuque

CORRESPONDING AUTHOR

victor.lannuque@enpc.fr

https://orcid.org/0000-0001-9373-0712

CEREA, École des Ponts ParisTech, EDF R&D, IPSL, 77455 Marne-la-Vallée, France

Barbara D'Anna

CORRESPONDING AUTHOR

barbara.danna@univ-amu.fr

https://orcid.org/0000-0001-8915-4097

Aix Marseille Univ, CNRS, LCE, Marseille, France

Evangelia Kostenidou

Aix Marseille Univ, CNRS, LCE, Marseille, France

now at: Department of Environmental Engineering, Democritus University of Thrace, 67100 Xanthi, Greece

Florian Couvidat

National Institute for Industrial Environment and Risks (INERIS), 60 550 Verneuil-en-Halatte, France

Alvaro Martinez-Valiente

Aix Marseille Univ, CNRS, LCE, Marseille, France

Philipp Eichler

Institute for Ion and Applied Physics, University of Innsbruck, 6020 Innsbruck, Austria

now at: German Environment Agency, Dessau, Germany

Armin Wisthaler

Institute for Ion and Applied Physics, University of Innsbruck, 6020 Innsbruck, Austria

Department of Chemistry, University of Oslo, 0315 Oslo, Norway

Markus Müller

https://orcid.org/0000-0003-4110-8950

Ionicon Analytik GmbH, 6020 Innsbruck, Austria

Brice Temime-Roussel

Aix Marseille Univ, CNRS, LCE, Marseille, France

Richard Valorso

Univ Paris Est Creteil and Université Paris Cité, CNRS, LISA, 94010 Créteil, France

Karine Sartelet

https://orcid.org/0000-0002-8165-2128

CEREA, École des Ponts ParisTech, EDF R&D, IPSL, 77455 Marne-la-Vallée, France

Viewed

Show all Final revised paper only Preprint only

Total article views: 2,003 (including HTML, PDF, and XML)

HTML	PDF	XML	Total	Supplement	BibTeX	EndNote
1,565	373	65	2,003	179	51	68

HTML: 1,565
PDF: 373
XML: 65
Total: 2,003
Supplement: 179
BibTeX: 51
EndNote: 68

Views and downloads (calculated since 20 Jun 2023)

Cumulative views and downloads (calculated since 20 Jun 2023)

Total article views: 1,438 (including HTML, PDF, and XML)

HTML	PDF	XML	Total	Supplement	BibTeX	EndNote
1,170	228	40	1,438	113	38	50

HTML: 1,170
PDF: 228
XML: 40
Total: 1,438
Supplement: 113
BibTeX: 38
EndNote: 50

Views and downloads (calculated since 20 Dec 2023)

Month	HTML	PDF	XML	Total
Dec 2023	262	46	10	318
Jan 2024	163	34	4	201
Feb 2024	57	14	0	71
Mar 2024	72	24	5	101
Apr 2024	44	15	5	64
May 2024	52	11	2	65
Jun 2024	94	12	3	109
Jul 2024	85	10	4	99
Aug 2024	49	5	2	56
Sep 2024	35	10	0	45
Oct 2024	69	4	1	74
Nov 2024	28	5	1	34
Dec 2024	43	8	1	52
Jan 2025	33	7	0	40
Feb 2025	32	13	0	45
Mar 2025	41	7	2	50
Apr 2025	11	3	0	14

Cumulative views and downloads (calculated since 20 Dec 2023)

Month	HTML	PDF	XML	Total
Dec 2023	262	46	10	318
Jan 2024	163	34	4	201
Feb 2024	57	14	0	71
Mar 2024	72	24	5	101
Apr 2024	44	15	5	64
May 2024	52	11	2	65
Jun 2024	94	12	3	109
Jul 2024	85	10	4	99
Aug 2024	49	5	2	56
Sep 2024	35	10	0	45
Oct 2024	69	4	1	74
Nov 2024	28	5	1	34
Dec 2024	43	8	1	52
Jan 2025	33	7	0	40
Feb 2025	32	13	0	45
Mar 2025	41	7	2	50
Apr 2025	11	3	0	14

Total article views: 565 (including HTML, PDF, and XML)

HTML	PDF	XML	Total	Supplement	BibTeX	EndNote
395	145	25	565	66	13	18

HTML: 395
PDF: 145
XML: 25
Total: 565
Supplement: 66
BibTeX: 13
EndNote: 18

Views and downloads (calculated since 20 Jun 2023)

Month	HTML	PDF	XML	Total
Dec 2023	262	46	10	318
Jan 2024	163	34	4	201
Feb 2024	57	14	0	71
Mar 2024	72	24	5	101
Apr 2024	44	15	5	64
May 2024	52	11	2	65
Jun 2024	94	12	3	109
Jul 2024	85	10	4	99
Aug 2024	49	5	2	56
Sep 2024	35	10	0	45
Oct 2024	69	4	1	74
Nov 2024	28	5	1	34
Dec 2024	43	8	1	52
Jan 2025	33	7	0	40
Feb 2025	32	13	0	45
Mar 2025	41	7	2	50
Apr 2025	11	3	0	14

Cumulative views and downloads (calculated since 20 Jun 2023)

Month	HTML	PDF	XML	Total
Dec 2023	262	46	10	318
Jan 2024	163	34	4	201
Feb 2024	57	14	0	71
Mar 2024	72	24	5	101
Apr 2024	44	15	5	64
May 2024	52	11	2	65
Jun 2024	94	12	3	109
Jul 2024	85	10	4	99
Aug 2024	49	5	2	56
Sep 2024	35	10	0	45
Oct 2024	69	4	1	74
Nov 2024	28	5	1	34
Dec 2024	43	8	1	52
Jan 2025	33	7	0	40
Feb 2025	32	13	0	45
Mar 2025	41	7	2	50
Apr 2025	11	3	0	14

Viewed (geographical distribution)

Show all Final revised paper only Preprint only

Total article views: 2,003 (including HTML, PDF, and XML) Thereof 1,974 with geography defined and 29 with unknown origin.

Total article views: 1,438 (including HTML, PDF, and XML) Thereof 1,420 with geography defined and 18 with unknown origin.

Total article views: 565 (including HTML, PDF, and XML) Thereof 554 with geography defined and 11 with unknown origin.

Country	#	Views	%
United States of America	1	506	25
China	2	421	21
France	3	288	14
Germany	4	125	6
Italy	5	106	5

Country	#	Views	%
United States of America	1	398	27
China	2	305	21
France	3	145	10
Italy	4	101	7
Germany	5	82	5

Country	#	Views	%
France	1	143	25
China	2	116	20
United States of America	3	108	19
Germany	4	43	7
India	5	21	3


Total:	0
HTML:	0
PDF:	0
XML:	0

506


Total:	0
HTML:	0
PDF:	0
XML:	0

398


Total:	0
HTML:	0
PDF:	0
XML:	0

143

Cited

Show all Final revised paper only Preprint only

6 citations as recorded by crossref.

Secondary organic aerosol formed by Euro 5 gasoline vehicle emissions: chemical composition and gas-to-particle phase partitioning E. Kostenidou et al. 10.5194/acp-24-2705-2024
Characterization of biogenic volatile organic compounds and their oxidation products in a stressed spruce-dominated forest close to a biogas power plant J. Song et al. 10.5194/acp-24-13199-2024
In situ measurements of gas–particle partitioning of organic compounds in Fairbanks A. Ijaz et al. 10.1039/D4FD00175C
Modeling the molecular composition of secondary organic aerosol under highly polluted conditions: A case study in the Yangtze River Delta Region in China Q. Huang et al. 10.1016/j.scitotenv.2024.173327
Modelling molecular composition of SOA from toluene photo-oxidation at urban and street scales K. Sartelet et al. 10.1039/D4EA00049H
Development of a detailed gaseous oxidation scheme of naphthalene for secondary organic aerosol (SOA) formation and speciation V. Lannuque & K. Sartelet 10.5194/acp-24-8589-2024

6 citations as recorded by crossref.

Secondary organic aerosol formed by Euro 5 gasoline vehicle emissions: chemical composition and gas-to-particle phase partitioning E. Kostenidou et al. 10.5194/acp-24-2705-2024
Characterization of biogenic volatile organic compounds and their oxidation products in a stressed spruce-dominated forest close to a biogas power plant J. Song et al. 10.5194/acp-24-13199-2024
In situ measurements of gas–particle partitioning of organic compounds in Fairbanks A. Ijaz et al. 10.1039/D4FD00175C
Modeling the molecular composition of secondary organic aerosol under highly polluted conditions: A case study in the Yangtze River Delta Region in China Q. Huang et al. 10.1016/j.scitotenv.2024.173327
Modelling molecular composition of SOA from toluene photo-oxidation at urban and street scales K. Sartelet et al. 10.1039/D4EA00049H
Development of a detailed gaseous oxidation scheme of naphthalene for secondary organic aerosol (SOA) formation and speciation V. Lannuque & K. Sartelet 10.5194/acp-24-8589-2024

Latest update: 04 Apr 2025

Download

Article (2331 KB)
Full-text XML

Supplement (3393 KB)
BibTeX
EndNote

Short summary

Large uncertainties remain in understanding secondary organic aerosol (SOA) formation from toluene oxidation. In this study, speciation measurements in gaseous and particulate phases were carried out, providing partitioning and volatility data on individual toluene SOA components at different temperatures. A new detailed oxidation mechanism was developed to improve modeled speciation, and effects of different processes involved in gas–particle partitioning at the molecular scale are explored.

Large uncertainties remain in understanding secondary organic aerosol (SOA) formation from...

Altmetrics

Final-revised paper

Preprint