Articles | Volume 23, issue 20 
            
                
                    
            
            
            https://doi.org/10.5194/acp-23-12965-2023
                    © Author(s) 2023. This work is distributed under 
the Creative Commons Attribution 4.0 License.
                the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-23-12965-2023
                    © Author(s) 2023. This work is distributed under 
the Creative Commons Attribution 4.0 License.
                the Creative Commons Attribution 4.0 License.
Influence of anthropogenic emissions on the composition of highly oxygenated organic molecules in Helsinki: a street canyon and urban background station comparison
Magdalena Okuljar
CORRESPONDING AUTHOR
                                            
                                    
                                            Institute of Atmospheric and Earth System Science/Physics, University of Helsinki, 00014, Helsinki,
Finland
                                        
                                    Olga Garmash
                                            Aerosol Physics Laboratory, Physics Unit, Tampere University, P.O. Box
692, 33014, Tampere, Finland
                                        
                                    
                                            Department of Atmospheric Sciences, University of Washington, Seattle,
WA, United States
                                        
                                    Miska Olin
                                            Aerosol Physics Laboratory, Physics Unit, Tampere University, P.O. Box
692, 33014, Tampere, Finland
                                        
                                    Joni Kalliokoski
                                            Aerosol Physics Laboratory, Physics Unit, Tampere University, P.O. Box
692, 33014, Tampere, Finland
                                        
                                    Hilkka Timonen
                                            Atmospheric Composition Research, Finnish Meteorological Institute,
00101, Helsinki, Finland
                                        
                                    Jarkko V. Niemi
                                            Helsinki Region Environmental Services Authority, HSY, P.O. Box 100,
00066, Helsinki, Finland
                                        
                                    Pauli Paasonen
                                            Institute of Atmospheric and Earth System Science/Physics, University of Helsinki, 00014, Helsinki,
Finland
                                        
                                    Jenni Kontkanen
                                            Institute of Atmospheric and Earth System Science/Physics, University of Helsinki, 00014, Helsinki,
Finland
                                        
                                    
                                            CSC – IT Center for Science Ltd., 02101, Espoo, Finland
                                        
                                    Yanjun Zhang
                                            Institute of Atmospheric and Earth System Science/Physics, University of Helsinki, 00014, Helsinki,
Finland
                                        
                                    
                                            IRCELYON, University of Lyon, Université Claude Bernard Lyon 1, CNRS,69626 Villeurbanne, France
                                        
                                    Heidi Hellén
                                            Atmospheric Composition Research, Finnish Meteorological Institute,
00101, Helsinki, Finland
                                        
                                    Heino Kuuluvainen
                                            Aerosol Physics Laboratory, Physics Unit, Tampere University, P.O. Box
692, 33014, Tampere, Finland
                                        
                                    Minna Aurela
                                            Atmospheric Composition Research, Finnish Meteorological Institute,
00101, Helsinki, Finland
                                        
                                    Hanna E. Manninen
                                            Helsinki Region Environmental Services Authority, HSY, P.O. Box 100,
00066, Helsinki, Finland
                                        
                                    Mikko Sipilä
                                            Institute of Atmospheric and Earth System Science/Physics, University of Helsinki, 00014, Helsinki,
Finland
                                        
                                    Topi Rönkkö
                                            Aerosol Physics Laboratory, Physics Unit, Tampere University, P.O. Box
692, 33014, Tampere, Finland
                                        
                                    Tuukka Petäjä
                                            Institute of Atmospheric and Earth System Science/Physics, University of Helsinki, 00014, Helsinki,
Finland
                                        
                                    Markku Kulmala
                                            Institute of Atmospheric and Earth System Science/Physics, University of Helsinki, 00014, Helsinki,
Finland
                                        
                                    Miikka Dal Maso
                                            Aerosol Physics Laboratory, Physics Unit, Tampere University, P.O. Box
692, 33014, Tampere, Finland
                                        
                                    Mikael Ehn
                                            Institute of Atmospheric and Earth System Science/Physics, University of Helsinki, 00014, Helsinki,
Finland
                                        
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                            Cited
5 citations as recorded by crossref.
- The Characteristics of the Chemical Composition of PM2.5 during a Severe Haze Episode in Suzhou, China X. Huang et al. 10.3390/atmos15101204
 - Long-term evolution of carbonaceous aerosols in PM2.5 during over a decade of atmospheric pollution outbreaks and control in polluted central China Z. Dong et al. 10.1016/j.scitotenv.2024.173089
 - Comparison of Gaseous and Particulate Highly Oxygenated Organic Molecules from the Ozonolysis of Terpenes J. Zhao et al. 10.1021/acsestair.4c00121
 - Characterization of brown carbon absorption in different European environments through source contribution analysis H. Navarro-Barboza et al. 10.5194/acp-25-2667-2025
 - Influence of anthropogenic emissions on the composition of highly oxygenated organic molecules in Helsinki: a street canyon and urban background station comparison M. Okuljar et al. 10.5194/acp-23-12965-2023
 
4 citations as recorded by crossref.
- The Characteristics of the Chemical Composition of PM2.5 during a Severe Haze Episode in Suzhou, China X. Huang et al. 10.3390/atmos15101204
 - Long-term evolution of carbonaceous aerosols in PM2.5 during over a decade of atmospheric pollution outbreaks and control in polluted central China Z. Dong et al. 10.1016/j.scitotenv.2024.173089
 - Comparison of Gaseous and Particulate Highly Oxygenated Organic Molecules from the Ozonolysis of Terpenes J. Zhao et al. 10.1021/acsestair.4c00121
 - Characterization of brown carbon absorption in different European environments through source contribution analysis H. Navarro-Barboza et al. 10.5194/acp-25-2667-2025
 
Latest update: 03 Nov 2025
Short summary
                    Highly oxygenated organic molecules (HOMs) form secondary organic aerosol that affects air quality and health. In this study, we demonstrate that in a moderately polluted city with abundant vegetation, the composition of HOMs is largely controlled by the effect of NOx on the biogenic volatile organic compound oxidation. Comparing the results from two nearby stations, we show that HOM composition and formation pathways can change considerably within small distances in urban environments.
                    Highly oxygenated organic molecules (HOMs) form secondary organic aerosol that affects air...
                    
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