Articles | Volume 23, issue 18
https://doi.org/10.5194/acp-23-10287-2023
https://doi.org/10.5194/acp-23-10287-2023
Research article
 | 
15 Sep 2023
Research article |  | 15 Sep 2023

OH, HO2, and RO2 radical chemistry in a rural forest environment: measurements, model comparisons, and evidence of a missing radical sink

Brandon Bottorff, Michelle M. Lew, Youngjun Woo, Pamela Rickly, Matthew D. Rollings, Benjamin Deming, Daniel C. Anderson, Ezra Wood, Hariprasad D. Alwe, Dylan B. Millet, Andrew Weinheimer, Geoff Tyndall, John Ortega, Sebastien Dusanter, Thierry Leonardis, James Flynn, Matt Erickson, Sergio Alvarez, Jean C. Rivera-Rios, Joshua D. Shutter, Frank Keutsch, Detlev Helmig, Wei Wang, Hannah M. Allen, Johnathan H. Slade, Paul B. Shepson, Steven Bertman, and Philip S. Stevens

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Interactive discussion

Status: closed

Comment types: AC – author | RC – referee | CC – community | EC – editor | CEC – chief editor | : Report abuse
  • RC1: 'Comment on egusphere-2023-790', Anonymous Referee #1, 16 May 2023
  • RC2: 'Comment on egusphere-2023-790', Anonymous Referee #2, 10 Jun 2023

Peer review completion

AR: Author's response | RR: Referee report | ED: Editor decision | EF: Editorial file upload
AR by Brandon Bottorff on behalf of the Authors (27 Jul 2023)  Author's response   Author's tracked changes   Manuscript 
ED: Publish subject to minor revisions (review by editor) (31 Jul 2023) by Lisa Whalley
AR by Brandon Bottorff on behalf of the Authors (09 Aug 2023)  Author's response   Author's tracked changes   Manuscript 
ED: Publish as is (11 Aug 2023) by Lisa Whalley
AR by Brandon Bottorff on behalf of the Authors (16 Aug 2023)  Manuscript 
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Short summary
The hydroxyl (OH), hydroperoxy (HO2), and organic peroxy (RO2) radicals play important roles in atmospheric chemistry and have significant air quality implications. Here, we compare measurements of OH, HO2, and total peroxy radicals (XO2) made in a remote forest in Michigan, USA, to predictions from a series of chemical models. Lower measured radical concentrations suggest that the models may be missing an important radical sink and overestimating the rate of ozone production in this forest.
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