Articles | Volume 22, issue 2
https://doi.org/10.5194/acp-22-917-2022
© Author(s) 2022. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-22-917-2022
© Author(s) 2022. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
19 Jan 2022
Research article |
| 19 Jan 2022
| 19 Jan 2022
Secondary organic aerosol formation from the oxidation of decamethylcyclopentasiloxane at atmospherically relevant OH concentrations
Sophia M. Charan
Division of Chemistry and Chemical Engineering, California Institute of Technology, Pasadena, California 91125, USA
Yuanlong Huang
Division of Geological and Planetary Sciences, California Institute of Technology, Pasadena, California 91125, USA
Reina S. Buenconsejo
Division of Chemistry and Chemical Engineering, California Institute of Technology, Pasadena, California 91125, USA
Qi Li
Department of Chemical and Environmental Engineering, University of California – Riverside, Riverside, California 92521, USA
David R. Cocker III
Department of Chemical and Environmental Engineering, University of California – Riverside, Riverside, California 92521, USA
Division of Chemistry and Chemical Engineering, California Institute of Technology, Pasadena, California 91125, USA
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Cited
14 citations as recorded by crossref.
- Volatile oxidation products and secondary organosiloxane aerosol from D5 + OH at varying OH exposures H. Kang et al. 10.5194/acp-23-14307-2023
- Secondary organic aerosols from OH oxidation of cyclic volatile methyl siloxanes as an important Si source in the atmosphere C. Han et al. 10.5194/acp-22-10827-2022
- Chemical characterization and formation of secondary organosiloxane aerosol (SOSiA) from OH oxidation of decamethylcyclopentasiloxane Y. Chen et al. 10.1039/D2EA00161F
- Indoor Emission, Oxidation, and New Particle Formation of Personal Care Product Related Volatile Organic Compounds T. Wu et al. 10.1021/acs.estlett.4c00353
- Molecular composition and gas-particle partitioning of indoor cooking aerosol: Insights from a FIGAERO-CIMS and kinetic aerosol modeling C. Masoud et al. 10.1080/02786826.2022.2133593
- Comparison of the Yield and Chemical Composition of Secondary Organic Aerosol Generated from the OH and Cl Oxidation of Decamethylcyclopentasiloxane A. Avery et al. 10.1021/acsearthspacechem.2c00304
- Insights Into Formation and Aging of Secondary Organic Aerosol From Oxidation Flow Reactors: A Review Z. Zhang et al. 10.1007/s40726-024-00309-7
- Yields and molecular composition of gas-phase and secondary organic aerosol from the photooxidation of the volatile consumer product benzyl alcohol: formation of highly oxygenated and hydroxy nitro-aromatic compounds M. Jaoui et al. 10.5194/acp-23-4637-2023
- Methylsiloxanes from Vehicle Emissions Detected in Aerosol Particles P. Yao et al. 10.1021/acs.est.3c03797
- Rate coefficients for the gas‐phase reaction of OH radicals with the L4, L5, D5, and D6 permethylsiloxanes F. Bernard & J. Burkholder 10.1002/kin.21769
- Concentrations of Volatile Methyl Siloxanes in New York City Reflect Emissions from Personal Care and Industrial Use C. Brunet et al. 10.1021/acs.est.3c10752
- Secondary Organic Aerosol Formation from Volatile Chemical Product Emissions: Model Parameters and Contributions to Anthropogenic Aerosol S. Sasidharan et al. 10.1021/acs.est.3c00683
- Evaporation-Induced Transformations in Volatile Chemical Product-Derived Secondary Organic Aerosols: Browning Effects and Alterations in Oxidative Reactivity L. Zhou et al. 10.1021/acs.est.4c02316
- Atmospheric Degradation of Cyclic Volatile Methyl Siloxanes: Radical Chemistry and Oxidation Products M. Alton & E. Browne 10.1021/acsenvironau.1c00043
13 citations as recorded by crossref.
- Volatile oxidation products and secondary organosiloxane aerosol from D5 + OH at varying OH exposures H. Kang et al. 10.5194/acp-23-14307-2023
- Secondary organic aerosols from OH oxidation of cyclic volatile methyl siloxanes as an important Si source in the atmosphere C. Han et al. 10.5194/acp-22-10827-2022
- Chemical characterization and formation of secondary organosiloxane aerosol (SOSiA) from OH oxidation of decamethylcyclopentasiloxane Y. Chen et al. 10.1039/D2EA00161F
- Indoor Emission, Oxidation, and New Particle Formation of Personal Care Product Related Volatile Organic Compounds T. Wu et al. 10.1021/acs.estlett.4c00353
- Molecular composition and gas-particle partitioning of indoor cooking aerosol: Insights from a FIGAERO-CIMS and kinetic aerosol modeling C. Masoud et al. 10.1080/02786826.2022.2133593
- Comparison of the Yield and Chemical Composition of Secondary Organic Aerosol Generated from the OH and Cl Oxidation of Decamethylcyclopentasiloxane A. Avery et al. 10.1021/acsearthspacechem.2c00304
- Insights Into Formation and Aging of Secondary Organic Aerosol From Oxidation Flow Reactors: A Review Z. Zhang et al. 10.1007/s40726-024-00309-7
- Yields and molecular composition of gas-phase and secondary organic aerosol from the photooxidation of the volatile consumer product benzyl alcohol: formation of highly oxygenated and hydroxy nitro-aromatic compounds M. Jaoui et al. 10.5194/acp-23-4637-2023
- Methylsiloxanes from Vehicle Emissions Detected in Aerosol Particles P. Yao et al. 10.1021/acs.est.3c03797
- Rate coefficients for the gas‐phase reaction of OH radicals with the L4, L5, D5, and D6 permethylsiloxanes F. Bernard & J. Burkholder 10.1002/kin.21769
- Concentrations of Volatile Methyl Siloxanes in New York City Reflect Emissions from Personal Care and Industrial Use C. Brunet et al. 10.1021/acs.est.3c10752
- Secondary Organic Aerosol Formation from Volatile Chemical Product Emissions: Model Parameters and Contributions to Anthropogenic Aerosol S. Sasidharan et al. 10.1021/acs.est.3c00683
- Evaporation-Induced Transformations in Volatile Chemical Product-Derived Secondary Organic Aerosols: Browning Effects and Alterations in Oxidative Reactivity L. Zhou et al. 10.1021/acs.est.4c02316
Latest update: 25 Dec 2024
Short summary
In this study, we investigate the secondary organic aerosol formation potential of decamethylcyclopentasiloxane (D5), which is used as a tracer for volatile chemical products and measured in high concentrations both outdoors and indoors. By performing experiments in different types of reactors, we find that D5’s aerosol formation is highly dependent on OH, and, at low OH concentrations or exposures, D5 forms little aerosol. We also reconcile results from other studies.
In this study, we investigate the secondary organic aerosol formation potential of...
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