Articles | Volume 22, issue 13
https://doi.org/10.5194/acp-22-8497-2022
© Author(s) 2022. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-22-8497-2022
© Author(s) 2022. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
04 Jul 2022
Research article |
| 04 Jul 2022
| 04 Jul 2022
Investigation of the limonene photooxidation by OH at different NO concentrations in the atmospheric simulation chamber SAPHIR (Simulation of Atmospheric PHotochemistry In a large Reaction Chamber)
Jacky Yat Sing Pang
Institute of Energy and Climate Research, IEK-8: Troposphere,
Forschungszentrum Jülich GmbH, Jülich, Germany
Anna Novelli
Institute of Energy and Climate Research, IEK-8: Troposphere,
Forschungszentrum Jülich GmbH, Jülich, Germany
Martin Kaminski
Institute of Energy and Climate Research, IEK-8: Troposphere,
Forschungszentrum Jülich GmbH, Jülich, Germany
now at: Federal Office of Consumer Protection and Food Safety,
Department 5: Method Standardisation, Reference Laboratories, Resistance to
Antibiotics, Berlin, Germany
Ismail-Hakki Acir
Institute of Energy and Climate Research, IEK-8: Troposphere,
Forschungszentrum Jülich GmbH, Jülich, Germany
now at: Institute of Nutrition and Food Sciences, Food Science,
University of Bonn, Bonn, Germany
Birger Bohn
Institute of Energy and Climate Research, IEK-8: Troposphere,
Forschungszentrum Jülich GmbH, Jülich, Germany
Philip T. M. Carlsson
Institute of Energy and Climate Research, IEK-8: Troposphere,
Forschungszentrum Jülich GmbH, Jülich, Germany
Changmin Cho
Institute of Energy and Climate Research, IEK-8: Troposphere,
Forschungszentrum Jülich GmbH, Jülich, Germany
now at: Atmospheric Trace Molecule Sensing Laboratory, School of Earth
Sciences and Environmental Engineering, Gwangju Institute of Science and
Technology, Gwangju, Republic of Korea
Hans-Peter Dorn
Institute of Energy and Climate Research, IEK-8: Troposphere,
Forschungszentrum Jülich GmbH, Jülich, Germany
Andreas Hofzumahaus
Institute of Energy and Climate Research, IEK-8: Troposphere,
Forschungszentrum Jülich GmbH, Jülich, Germany
Institute of Energy and Climate Research, IEK-8: Troposphere,
Forschungszentrum Jülich GmbH, Jülich, Germany
now at: State Key Joint Laboratory of Environmental Simulation and
Pollution Control, College of Environmental Sciences and Engineering, Peking
University, Beijing, China
Anna Lutz
Department of Chemistry and Molecular Biology, University of
Gothenburg, Gothenburg, Sweden
Sascha Nehr
Institute of Energy and Climate Research, IEK-8: Troposphere,
Forschungszentrum Jülich GmbH, Jülich, Germany
now at: CBS International Business School, Brühl, Germany
David Reimer
Institute of Energy and Climate Research, IEK-8: Troposphere,
Forschungszentrum Jülich GmbH, Jülich, Germany
Franz Rohrer
Institute of Energy and Climate Research, IEK-8: Troposphere,
Forschungszentrum Jülich GmbH, Jülich, Germany
Ralf Tillmann
Institute of Energy and Climate Research, IEK-8: Troposphere,
Forschungszentrum Jülich GmbH, Jülich, Germany
Robert Wegener
Institute of Energy and Climate Research, IEK-8: Troposphere,
Forschungszentrum Jülich GmbH, Jülich, Germany
Astrid Kiendler-Scharr
Institute of Energy and Climate Research, IEK-8: Troposphere,
Forschungszentrum Jülich GmbH, Jülich, Germany
I. Physikalisches Institut, Universität zu Köln, Köln,
Germany
Andreas Wahner
Institute of Energy and Climate Research, IEK-8: Troposphere,
Forschungszentrum Jülich GmbH, Jülich, Germany
Institute of Energy and Climate Research, IEK-8: Troposphere,
Forschungszentrum Jülich GmbH, Jülich, Germany
I. Physikalisches Institut, Universität zu Köln, Köln,
Germany
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Cited
5 citations as recorded by crossref.
- Development of a multiphase chemical mechanism to improve secondary organic aerosol formation in CAABA/MECCA (version 4.7.0) F. Wieser et al. 10.5194/gmd-17-4311-2024
- Limonene: A scented and versatile tropospheric free radical deactivator M. Francisco‐Márquez & A. Galano 10.1002/qua.27103
- Atmospheric photooxidation and ozonolysis of sabinene: reaction rate coefficients, product yields, and chemical budget of radicals J. Pang et al. 10.5194/acp-23-12631-2023
- Formation of highly oxygenated organic molecules from the oxidation of limonene by OH radical: significant contribution of H-abstraction pathway H. Luo et al. 10.5194/acp-23-7297-2023
- Comparison of Isoprene Chemical Mechanisms with Chamber and Field Observations W. Brune et al. 10.1021/acsearthspacechem.4c00196
5 citations as recorded by crossref.
- Development of a multiphase chemical mechanism to improve secondary organic aerosol formation in CAABA/MECCA (version 4.7.0) F. Wieser et al. 10.5194/gmd-17-4311-2024
- Limonene: A scented and versatile tropospheric free radical deactivator M. Francisco‐Márquez & A. Galano 10.1002/qua.27103
- Atmospheric photooxidation and ozonolysis of sabinene: reaction rate coefficients, product yields, and chemical budget of radicals J. Pang et al. 10.5194/acp-23-12631-2023
- Formation of highly oxygenated organic molecules from the oxidation of limonene by OH radical: significant contribution of H-abstraction pathway H. Luo et al. 10.5194/acp-23-7297-2023
- Comparison of Isoprene Chemical Mechanisms with Chamber and Field Observations W. Brune et al. 10.1021/acsearthspacechem.4c00196
Latest update: 13 Dec 2024
Short summary
This study investigates the radical chemical budget during the limonene oxidation at different atmospheric-relevant NO concentrations in chamber experiments under atmospheric conditions. It is found that the model–measurement discrepancies of HO2 and RO2 are very large at low NO concentrations that are typical for forested environments. Possible additional processes impacting HO2 and RO2 concentrations are discussed.
This study investigates the radical chemical budget during the limonene oxidation at different...
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